沉淀物和生物中U,Th和226Ra的联合测定

用放射化学法对U,Th,~(226)Ra等核素进行联合测定,国外已有不少报道,只是所用的分离方法和所测的介质不同而已。我国学者也做过一些这方面的工作。本工作建立了用三正辛胺-二甲苯萃取分离法对沉积物和生物样中U,Th和~(226)Ra的联合测定方法。 二、主要仪器与试剂     

Study of prediction for groundwater contamination in wastewater land treatment system

This paper uses a prediction model of groundwater pollution based on the experiments in the laboratory and in field .The model, which was tested and calibrated by the field observated data ,satisfactorily simulated the field conditions in land treatment system of wastewater . Particularly , the model can provide the reliable pollution prediction of heavy metals , organisms and nitrogen . The model was used to predict the groundwater pollution caused by the land treatment system in the region of North China . The calibration of the model showed that correlation coefficients between the tested and predictive data of Cr6+. As3+, organism and NH4+ could reach 0.990, which proved that the model possessed the realistic instructive significance for design and use of wastewater land treatment systems .     

京津风沙源区防风固沙功能的时空变化及其区域差异

防风固沙功能是京津风沙源治理成效的关键监测指标。以往研究注重局地防风固沙功能的评估,对全区防风固沙功能的时空变化与内部差异揭示不足。基于京津风沙源区多期遥感数据,采用修正风蚀方程与GIS空间统计技术,评估分析了2000-2015年防风固沙功能的整体变化及其区域差异。结果表明:(1)京津风沙源区年均防风固沙量为28.98亿t,防风固沙能力为68.24 t/hm~2,且均随年份变化波动增加,年均增速分别为1.10%和0.71%;(2)京津风沙源区防风固沙能力呈西北高、东南低趋势,有49.06%的区域防风固沙能力高于70 t/hm~2,评估期内有54%的区域防风固沙能力明显提高;(3)浑善达克沙地亚区、典型草原亚区和荒漠草原亚区的防风固沙量累计为全区防风固沙总量的88%,燕山丘陵山地水源保护亚区和晋北山地丘陵亚区的防风固沙能力提升最显著;(4)锡林郭勒盟、赤峰市和乌兰察布市的防风固沙量合计占全区防风固沙量的77%,朔州市与包头市防风固沙能力较高,北京市与天津市防风固沙能力增速较高。因此,未来应重视分区施策治理与西部和北部防风固沙功能提升。     

不同生物接触氧化方法对藻类的去除效果比较及其途径分析

比较了3种生物接触氧化法对富营养化水源水中藻类的去除效果，探讨其去除藻类的途径。试验结果表明：淹没式曝气生物陶粒滤池（I型）在4-6m/h过滤速度条件下，对藻类总数的去除效率稳定，平均为70%左右；采用YDT弹性立体填料的中心导流筒曝气生物接触氧化法（Ⅱ型）与直接微孔曝气生物接触氧化法（Ⅲ型），在试验初期对藻类总数的去除率较低，平均去除率分别为60.2%、51.6%。但随着生物膜厚度的增加，试验后期对藻类的去除效果逐步得到提高，平均达70%以上。生物膜对藻类的生物絮凝、吸附、生物膜的脱落沉降等是生物接触氧化法去除藻类的主要途径。     

Combined effect of tributyltin and benzo[a] pyrene on the levels of sex hormone and vitellogenin in female Sebastiscus marmoratus

Tributyltin（TBT）, an organometal used as an antifouling biocide, has been reported to induce masculinization of fish. Benzo [a]pyrene （BaP）, a widespread carcinogenic polycyclic aromatic hydrocarbon, has been reported that its microsomal metabolites can produce an estrogenic response when tested in vitro. This study was therefore designed to examine the potential in vivo influence of TBT, BaP and their mixture on sex hormone levels in serum of Sebastiscus marmoratus, which were given 2 separate intraperitoneally （ip） injections（a single injection every 7 d） of TBT（0.5, 1, 5 and 10 mg/kg）, BaP（0.5, 1, 5 and 10 mg/kg）, or both in combination（0.5, 1, 5 and 10 mg/kg）; control fish received olive oil vehicle only. Six days after the 2nd injection, serum samples were collected and analyzed for sex hormone levels and alkali labile protein phosphorus （ALPP）, which is related to the yolk precursor protein vitellogenin. The pollutants at all doses significantly reduced serum testosterone, estradiol and ALPP content after 2 injections compared with the corresponding controls. The reduction of the estradiol levels should be response for the decrease of the vitellogenin levels. The results in the present study suggested that aromatase seems not the major target acted by TBT and BaP in fish. This study demonstrated that TBT or BaP exposure both inhibit the reproductive potential in female Sebastiscus marmoratus. Combined effect of TBT and BaP on the serum testosterone, estradiol and ALPP was not antagonism from the anticipation.     

论乌海及周边地区推广气烧石灰竖窑的可行性

本文介绍了使用焦炉煤气做气烧石灰竖窑清洁燃料国内发展概况，阐述了在乌海及周边地区利用丰富石灰石资源和焦炉剩余煤气开展清洁生产、减少环境污染、进行循环经济的必然选择，并从石灰石生产工艺选择，环境效益分析方面进行了讨论。     

气相色谱法测定二硫化碳和甲硫醚

利用气相色谱(配火焰光度检测器,采用3mxφ2mm玻璃填充柱分离)对CS2和甲硫醚(DMS)两种含硫化合物进行了分离检测。该方法具有较高的灵敏度和良好的线性关系。结果表明:该分析对含硫气体的最小检测浓度在mg/m3级,在柱温为70℃,检测器温度为180℃,气化室温度为150℃,氮气流速为50mL/min时,CS2的回收率为98.66%,变异系数为2.12%;甲硫醚的回收率为98.66%,变异系数为1.56%。     

水稻烤田期间N2O排放及其影响因素

水稻田间实验研究了烤田期间的土壤温度、Eh、含水量和裂缝基本性质,矿质态氮以及与氮有关的酶活性的演变规律,及其对N2O排放的影响.试验表明,在水稻分蘖期间烤田,N2O有一个排放高峰,其最高值可达75.6μg·m-2·h-1.在排放高峰后,即使继续烤田,N2O的排放值也将降低.N2O排放与尿素氮肥的施用量没有明显关系.裂缝的生成,改变了N2O的日排放规律.随着烤田时间的延长,脲酶和羟胺还原酶活性呈波动变化,硝酸还原酶活性递减,亚硝酸还原酶活性极低.硝酸还原酶活性与N2O排放之间没有显著相关性.土壤中的脲酶活性与N2O日排放通量呈显著的线性正相关.在烤田期间,NO-3含量呈增加趋势.土壤中的硝态氮含量与N2O排放通量之间呈显著正线性关系.土壤中的铵态氮含量与N2O排放通量之间呈显著负线性相关.     

国内氰化物测定法近况

阐述了近几年来国内氰化物的测定方法。方法包括:色谱法、光谱法、电化学法及其他方法。     

生活垃圾填埋污染控制标准比较研究

详细介绍了美国《城市生活垃圾填埋场标准》，德国《生活垃圾技术条例》．日本《废弃物最终处置场指南》和欧盟《废弃物填埋导则》等有关生活垃圾填埋污染控制的标准的主要内容以厦其主要特点．井与中国现行的《生活垃圾填埋污染控制标准》（GB16889—1997）相比较，主要从选址、入场垃圾要求、渗滤液排放标准、防渗结构和终场覆盖系统等5方面分析了GB16889中存在的一些问题，并对今后其修订、完善工作提出了具体的建议。