1952-2016年长江经济带天然与人为氮输入时空演变

过量氮输入是水体氮污染的关键驱动因子，解析氮输入的结构和时空变化模式成为氮素环境管理的重要基础和难点.基于1952—2016年长江经济带各地区氮活动数据，分别构建了天然氮输入和人为氮输入模型，评估了氮输入负荷的时空变化特征.结果表明：①长江经济带氮输入负荷总体越过EKC曲线拐点进入由增长向下降的发展阶段，拐点出现在人均GDP为35777~36299元·人^-1时，发生时间为"十二五"时期，主要原因是化肥和食物输入下降；②氮输入负荷存在显著的时空差异，东部地区表现为倒U型，中部为S型，西部为J型，表明氮负荷存在从东向西的空间转移，西部地区成为氮输入负荷增长的热点地区，这与东部地区化肥施用量下降有关；③人为输入是长江经济带氮输入的主要来源，输入量及其占总输入的比例均呈现显著的增长趋势，空间上表现为从西到东部逐步递增的变化规律，与氮驱动力分布一致；④植被的多年平均固氮量为1771 kg·km^-2·a^-1，其中，非农作物的固氮速率为763 kg·km^-2·a^-1，植被固氮量的年际波动较小，天然输入对长江经济带总体氮输入影响较小.     

Enhanced removal of high-As(Ⅲ) from Cl(-Ⅰ)-diluted SO4(-Ⅱ)-rich wastewater at pH 2.3 via mixed tooeleite and(Cl(-Ⅰ)-free) ferric arsenite hydroxychloride formation

An advanced cost-saving method of removal of high-As(Ⅲ) from SO₄(-Ⅱ)-rich metallurgi cal wastewater has been developed by diluting the SO₄(-Ⅱ) content with As(Ⅲ)-Cl(-Ⅰ)-rich metallurgical wastewater and then by the direct precipitation of As(Ⅲ) with Fe(Ⅲ) at pH2.3.As(Ⅲ) removal at various SO₄(-Ⅱ)/Cl(-Ⅰ) molar ratios and temperatures was investigated The results showed that 65.2–98.2%of As(III) immobilization into solids occurred at the SO₄(Ⅱ)/Cl(-Ⅰ) mo...     

Decomplexation of Cu-1-hydroxyethylidene-1,1-diphosphonic acid by a three-dimensional electrolysis system with activated biochar as particle electrodes

The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10⁻³ and 1.94 × 10⁻⁵ min⁻¹respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H₂O₂ and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed.     

事故出流时河流综合水质的计算机预测方法研究

河流上游的污水排放口或倒虹管等污水构筑因有可能发生事故出流而对下游的取水口存在着潜在的威胁，常规的单参数模型不能就事故出流对下游的影响作出公正评价。本文以QUAL－Ⅱ模型为骨架，以生动形象的动画形式演示出在整个排污过程中多个水质参数沿河道分布的变化全过程，并且，在模型中融入隶属度BP神经网络综合评价水质的模块，用它来对发生事故出流时下游取水口水域的水质变化进行综合评价，最后通过一个例子说明了该方法的优越性和合理性。     

于桥水库流域暴雨径流中锰的输送特征及其对水库水质的影响

对于桥水库流域内暴雨径流中锰含量形态的研究表明,锰主要以悬浮状态存在,其中易释放的、潜在释放的和非释放形态的锰所占比例分别为10％、60％和30％.以溶解态迁移的锰极少.流域内的锰矿-含锰页岩带提高了暴雨径流中总锰的浓度,对于桥水库水质造成了一定的影响.     

南方涝渍地区退田还渔的一个实例分析

以江汉平原四湖涝渍地区的一个经围湖造田形成的典型农业微域为研究对象,在对其土壤和作物生长状况进行调查的基础上,探讨了退田还渔的必要性与具体方案。结果表明,对小型湖泊通过围湖造田所形成的农业微域,在人工排水和土地平整不充分的情况下,其地貌和土壤还残留有原有湖泊的影响,处于原湖泊低处的土壤表现出明显的沼泽化和严重潜育化的特征。在该地区种植水稻产量比正常地区减产达16%～26.8%。利用数量化理论Ⅰ确定了该地区适宜退田还渔的具体位置和面积。按照这一方案实施的结果,该地区从1997～2001年的5年中精养鱼塘面积增加9倍,养鱼的效益比种植水稻高5～10倍,还减轻了该地区夏季和冬季的排水压力。     

废水中含磷表面活性剂的测定

应用非水电位滴定法测定了废水中各种烷基磷酸酯钾盐及其单、双酯盐。方法的变异系数分别为２．３％和７．８％（ｎ＝１２）。本法可有效地消除非离子表面活性剂的干扰，适用于化纤油剂的质量检验和上油槽中油剂浓度的测定。     

城郊道路交通污染个例分析

为建立和研究适合地面道路的宽路幅、高等级、支路多等特点的大城市城郊道路交通大气污染扩散模式,选取了受环境外来源影响较小的上海市沪青平公路的徐泾段,作交通大气污染实测和相关气象因子项目的观测。在获得详细实测结果的基础上,以NOx为例分析了大气稳定度、风向、风速、交通量对城郊地面道路交通污染扩散的影响。     

Maternal sex chromosome mosaicism diagnosed by amniocentesis and percutaneous umbilical cord sampling

We present a remarkable chain of events in which percutaneous umbilical cord sampling was performed in an attempt to clarify a situation of possible fetal sex chromosome mosaicism in an amniotic fluid culture and led to the discovery that the mother herself had a 45,X/46,XX/ 47.XXX chromosome constitution. This may have simply represented the chance concurrence of pseudo-mosaicism in the amniotic fluid culture of a woman with an abnormal sex chromosome constitution, but it is also possible that the 45,X colony was maternal in origin. Although clearly a most unusual circumstance, the possibility should be kept in mind when termination of a pregnancy is being considered because of apparent mosaicism in a prenatal diagnostic study.