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761.
762.
K. Pritsch D. Ernst F. Fleischmann S. Gayler T. E. E. Grams A. Göttlein W. Heller N. Koch H. Lang R. Matyssek J. C. Munch M. Olbrich H. Scherb S. Stich J. B. Winkler M. Schloter 《Water, Air, & Soil Pollution: Focus》2008,8(2):139-154
A lysimeter study was performed to monitor effects of elevated ozone on juvenile trees of Fagus sylvatica L. as well as on the plant–soil system. During a fumigation period over almost three growing seasons, parameters related
to plant growth, phenological development and physiology as well as soil functions were studied. The data analyses identified
elevated ozone to delay leaf phenology at early and to accelerate it at late developmental stages, to reduce growth, some
leaf nutrients (Ca, K) as well as some soluble phenolics (hydroxycinnamic acid derivatives, total flavonol glycosides). No
or very weak ozone effects were found in mobile carbon pools of leaves (starch, sucrose), and other phenolic compounds (flavans).
Altered gene expression related to stress and carbon cycling corresponded well with findings from leaf phenology and chemical
composition analyses indicating earlier senescence and oxidative stress in leaves under elevated ozone. Conversely in the
soil system, no effects of ozone were detected on soil enzyme activities, rates of litter degradation and lysimeter water
balances. Despite the fact that the three reported years 2003–2005 were climatically very contrasting including a hot and
dry as well as an extremely wet summer, and also mild as well as cold winters, the influence of ozone on a number of plant
parameters is remarkably consistent, further underlining the phytotoxic potential of elevated tropospheric ozone levels. 相似文献
763.
764.
Reiner Schroll Sabine Grundmann Ulrike Dörfler Bernhard Ruth Jean Charles Munch 《Water, Air, & Soil Pollution: Focus》2008,8(2):209-216
Several lysimeter scenarios and approaches exist to study the fate of agro-chemicals or contaminants from deposition in soil
columns. In many systems just transport and leaching of the parent compound is followed, in some systems the leaching and
transport of the metabolites is investigated as well. In more sophisticated lysimeter systems the volatilization and also
the mineralization of the applied chemicals can be additionally monitored. Depending on the lysimeter system used and on the
fact whether the applied chemicals are 14C-labeled or not, different results and various interpretations of the results might be achieved. Different lysimeter systems
are described in this paper and a real dataset of a specific lysimeter experiment was transferred and evaluated in a virtual
approach in the different lysimeter systems in order to show the advantages and disadvantages of the various systems. 相似文献
765.
Hang Seok Choi Seock Joon Kim Kwan Tae Kim 《Journal of Material Cycles and Waste Management》2008,10(1):1-6
The mixing characteristics of a passive scalar in the turbulent flow of a selective catalytic reduction process were numerically
and experimentally investigated, focusing especially on an injection nozzle with multiple holes for the reducing agent. The
multihole injection nozzle studied has six holes that are perpendicular to the ambient flue gas flow and are located near
the tip of the nozzle. Large eddy simulation was applied to the turbulent flow and mixing fields to elucidate the mixing mechanism
of the proposed nozzle compared with the single-hole nozzle that is commonly used in the conventional selective catalytic
reduction process. From the results, there exist broader regions of higher turbulent intensities for the multihole nozzle
than for the conventional single-hole nozzle. These regions are well matched with the positions of high vorticity in the near
upstream region of the jet flow issuing from the multiple holes of the nozzle. Consequently, the high turbulent intensities
and vorticity magnitudes lead to intensified mixing between the flue gas and the reducing agent. Hence, the most suitable
molar ratio between NOx and the reducing agent for the catalytic reaction can be easily obtained within a shorter physical
mixing length as a result of the enhanced scalar mixing. Finally, the numerical results were applied to a trial design version
of a multihole nozzle, and this nozzle was experimentally tested to confirm its mixing performance. 相似文献
766.
Leaching behavior of heavy metals from municipal solid waste incineration bottom ash and its geochemical modeling 总被引:1,自引:1,他引:0
Hua Zhang Pin-Jing He Li-Ming Shao Xin-Jie Li 《Journal of Material Cycles and Waste Management》2008,10(1):7-13
With the increase in the number of municipal solid waste incineration (MSWI) plants constructed in China recently, great attention
has been paid to the heavy metal leaching toxicity of MSWI residues. In this study, the effects of various parameters, including
extractant, leaching time, liquid-to-solid ratio, leachate pH, and heavy metal content, on the release properties of Cd, Cr,
Cu, Ni, Pb, and Zn from MSWI bottom ash were investigated. Partial least-squares analysis was employed to highlight the interrelationships
between the factors and response variables. Both experimental research and geochemical modeling using Visual MINTEQ software
were conducted to study the pH-dependent leaching behavior of these metals in fresh and weathered bottom ash, considering
precipitation/dissolution and surface complexation reactions (adsorption by hydrous ferric oxide and amorphous aluminum oxide/hydroxide).
The results showed that leachate pH was the predominant factor influencing heavy metal leachability. The leaching of Cu, Pb,
and Zn was mainly controlled by precipitation/dissolution reactions, whereas surface complexation had some effect on the leaching
of Cr, Cd, and Ni for certain pH ranges. The modeling results aggreed well with the experimental results.
Part of this work was presented at the Fourth International Conference on Combustion, Incineration/Pyrolysis and Emission
Control (i-CIPEC) 相似文献
767.
Bacterial pretreatment enhances removal of heavy metals during treatment of post-methanated distillery effluent by Typha angustata L 总被引:1,自引:1,他引:0
A combination of bacterial pretreatment followed by free water surface flow through wetland plants was investigated to determine its effect on removal of heavy metals in bioremediation of post-methanated distillery effluent (PMDE). The bacterial pretreatment was intended to transform the metal complexes and organic pollutants into simpler, biologically assimilable molecules. The 10% and 30% v/v concentrations of PMDE favored luxuriant bacterial growth; the 50% concentration supported less growth, whereas the undiluted effluent (i.e., 100%) supported very little bacterial growth. The use of bacterial pretreatment combined with the constructed wetland system greatly increase the overall bioaccumulation of all heavy metals by the plants compared with the control treatment. However, the integration of bacterial pretreatment of PMDE with the Typha angustata resulted in enhanced removal of Cd (34.02–61.50% increase), Cr (35.90–57.60% increase), Cu (32.88–54.22% increase), Fe (32.50–51.26% increase), Mn (35.99–82.85% increase), Ni (35.85–59.24% increase), Pb (33.45–59.51% increase) and Zn (31.95–53.70% increase) compared with a control that lacked this pretreatment. In addition to the bioaccumulation of these heavy metals, several physico-chemical parameters also improved at the 30% effluent concentration: color, BOD, COD, phenol and total nitrogen decreased by 98.33%, 98.89%, 98.50%, 93.75% and 82.39%, respectively, after 7 days of free water surface flow treatment. The results suggest that bacterial pretreatment of PMDE, integrated with phytoremediation will improve the treatment process of PMDE and promote safer disposal of this waste. 相似文献
768.
Multicriteria decision support systems are applied in natural resource management in order to clarify the planning process for the stakeholders, to make all available information usable and all objectives manageable. Especially when the public is involved in planning, the decision support system should be easy to comprehend, transparent and fair. Social choice theory has recently been applied to group decision-making in natural resources management to accomplish these objectives. Although voting forms the basis of democracy, and is usually taken as a fair method, the influence of voters over the outcome may vary. It is also possible to vote strategically to improve the results from each stakeholder's point of view. This study examines the use of social choice theory in revealing stakeholders' preferences in participatory forest planning, and the influence of different voters on the outcome. The positional voting rules examined were approval voting and Borda count, but both rules were slightly modified for the purposes of this study. The third rule examined, cumulative rule, resembles utilitarian voting rules. The voting rules were tested in a real participatory forest planning situation in eastern Lapland, Finland. All voting rules resulted in a different joint order of importance of the criteria. Yet, the preference orders produced had also a lot in common and the criteria could be divided into three quite distinct groups according to their importance. The influence of individual voters varied between the voting rules, and in each case different voter was the most influential. 相似文献
769.
Increased salinity in spawning and nursery grounds in the Savannah River estuary was cited as the primary cause of a 97% decrease
in adult striped bass (Morone saxatilis) and a concomitant 96% decrease in striped bass egg production. Restoration efforts focused on environmental remediation
and stock enhancement have resulted in restored salinity patterns and increased egg and adult abundances. However, future
water needs or harbor development may preclude further recovery by reducing freshwater inflow or increasing salinity intrusion.
To assess the effect of potential changes in the salinity regime, we developed models relating discharge, tidal phase, and
salinity to striped bass egg and early larval survival and re-cast these in a quantitative Bayesian belief network. The model
indicated that a small upstream shift (≤1.67 km) in the salinity regime would have the least impact on striped bass early
life history survival, whereas shifts >1.67 km would have progressively larger impacts, with a 8.33-km shift potentially reducing
our estimated survival probability by >28%. Such an impact could have cumulative and long-term detrimental effects on the
recovery of the Savannah River striped bass population. The available salinity data were collected during average and low
flows, so our model represents some typical and some extreme conditions during a striped bass spawning season. Our model is
a relatively simplistic, “first-order” attempt at evaluating potential effects of changes in the Savannah River estuarine
salinity regime and points to areas of concern and potential future research. 相似文献
770.
Lopez-Espinosa MJ Kiviranta H Araque P Ruokojärvi P Molina-Molina JM Fernandez MF Vartiainen T Olea N 《Chemosphere》2008,73(6):967-971
Seventeen polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were quantified in adipose tissue samples of non-occupationally exposed women living in Southern Spain. Geometric mean levels of sum of congeners and WHO(PCDD/F)-TEQ(2005) were 410 and 17.9pgg(-1) fat, respectively. Among PCDDs, octachlorodibenzo-p-dioxin (OCDD) showed the highest concentration with a mean value of 265pgg(-1) fat, followed by 1,2,3,6,7,8-HxCDD (49.3pgg(-1) fat) and 1,2,3,4,6,7,8-HpCDD (45.2pgg(-1) fat). These three congeners were responsible for around 90% of the sum of all PCDD/F congeners in adipose tissue. The geometric mean 2,3,7,8-TCDD value was 1.87pgg(-1) fat. 2,3,4,7,8-PeCDF (8.43pgg(-1) fat) showed the highest concentration among the PCDFs, followed by 1,2,3,4,7,8-HxCDF (4.17pgg(-1) fat) and 1,2,3,6,7,8-HxCDF (3.28pgg(-1) fat), and these three congeners were responsible for 4% of the sum of all studied PCDD/F congeners in adipose tissue and 76% of the sum of ten PCDFs. 1,2,3,7,8,9-HxCDF was the only congener not quantified in any sample, while 1,2,3,4,7,8,9-HpCDF, 1,2,3,7,8-PeCDF, OCDF and 2,3,7,8-TCDF were found in 5, 16, 16 and 19 samples, respectively. All other congeners were quantifiable in all 20 samples. Congeners contributing most to the WHO(PCDD/F)-TEQ(2005) were 1,2,3,7,8-PeCDD (31.6%), 1,2,3,6,7,8-HxCDD (28.3%) and 2,3,4,7,8-PeCDF (14.6%). The body burden of log-transformed WHO(PCDD/F)-TEQ(2005) levels increased with age (B=0.02; 95% CI=0.01, 0.03; p=0.02). Although these adipose tissue PCDD/F levels are similar to previously published findings in Spain and other European countries, further research is needed to determine trends in the exposure of women to these chemical residues. 相似文献