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61.
设计了一种循环式超声强化光催化反应器,以TiO2作为光催化剂,研究了超声功率、TiO2加入量、循环液流速和空气流量对双酚A(BPA)降解效果的影响。实验结果表明:超声与光催化过程在循环式超声强化光催化反应器中实现了较好的协同效应;在初始BPA质量浓度为20.0mg/L、超声功率为600W、TiO2加入量为7g/L、循环液流速为4.05×10-2m/s、空气流量为200mL/min的条件下,反应150min后,BPA降解率可达90.5%,溶液中剩余BPA质量浓度仅为1.8mg/L,反应240min后TOC去除率可达84.5%。 相似文献
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Sorption of nonpolar (phenanthrene and butylate) and polar (atrazine and diuron) organic chemicals to oil-contaminated soil was examined to investigate oil effects on sorption of organic chemicals and to derive oil–water distribution coefficients (Koil). The resulting oil-contaminated soil–water distribution coefficients (Kd) for phenanthrene demonstrated sorption-enhancing effects at both lower and higher oil concentrations (Coil) but sorption-reducing (competitive) effects at intermediate Coil (approximately 1 g kg−1). Rationalization of the different dominant effects was attempted in terms of the relative aliphatic carbon content which determines the accessibility of the aromatic cores to phenanthrene. Little or no competitive effect occurred for butylate because its sorption was dominated by partitioning. For atrazine and diuron, the changes in Kd at Coil above approximately 1 g kg−1 were negligible, indicating that the presently investigated oil has little or no effect on the two tested compounds even though the polarity of the oil is much less than soil organic matter (SOM). Therefore, specific interactions with the active groups (aromatic and polar domains) are dominantly responsible for the sorption of polar sorbates, and thus their sorption is controlled by available sorption sites. This study showed that the oil has the potential to be a dominant sorptive phase for nonpolar pollutants when compared to SOM, but hardly so for polar compounds. The results may aid in a better understanding of the role of the aliphatic and aromatic domains in sorption of nonpolar and polar organic pollutants. 相似文献
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Zhang Q Wang C Zhang X Jin D Huang C Zhao M 《Journal of environmental monitoring : JEM》2012,14(2):465-472
Chiral pesticides are ubiquitous in the aquatic environment, and their enantioselectivities in aquatic toxicity are known to be complicated. The difference in enantioselective effects between enantiomers may sometimes differ by approximately 100-fold or more, which makes it important to incorporate enantioselective effects into the risk assessment of chiral pesticides. In this paper, we reviewed relevant work on the aquatic toxicity of chiral pesticides with an emphasis on the enantioselective aquatic toxicity under both chronic and acute exposure conditions. We provided a personal account of the importance of studies on molecular mechanisms of developmental toxicity and specific endpoints such as vitellogenin, yolk sac edema and pericardial edema in future research. Given the widespread use of chiral pesticides, we suggest that a more comprehensive understanding of the significance of enantioselective aquatic toxicity will be very helpful in improving risk assessment and regulation of chiral pesticides. 相似文献
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Yan Yan Peng Shan Chenxing Wang Yuan Quan Di Wu Chunli Zhao Gang Wu Hongbing Deng 《Environmental monitoring and assessment》2017,189(4):191
Sustainable urban development focuses on enhancing urban well-being, while also balancing the demands of urban social and economic development, natural resource consumption, and environmental pollution. This work used general data envelopment analysis to assess the urban sustainability efficiency (USE) and sustainability potential (SP) in Lanzhou and Xiamen, two cities that are characteristic of urban areas in western and eastern China. The assessment indicator system included important natural and urban welfare factors as input and output indices, respectively. The results showed that overall urban sustainability efficiency increased in Lanzhou and Xiamen from 1985 to 2010, but that the sustainability of natural resources clearly decreased. The urban sustainability efficiency of Xiamen was higher than that of Lanzhou, and the sustainability potential of Xiamen was lower than that of Lanzhou; this indicates that Xiamen performed better in terms of urban sustainable development. The urban sustainability efficiency in Xiamen has increased with increasing urban population, and the rate and scale of economic development have been higher than in Lanzhou. The assessment and analysis performed in this study show that cities with different natural resources and development characteristics have different forms, patterns, and trajectories of sustainable development. 相似文献
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安全等级特征量及其计算方法 总被引:17,自引:2,他引:15
指出了目前用模糊评价法确定系统的安全等级所存在的问题和不足之处。分别运用模糊随机变量理论和模糊集理论而提出了安全等级模糊随机特征量和安全等级模糊特征量的概念及其计算方法。安全等级特征量及安全等级变量,均为安全等级取值论域上的模糊子集,而并非是一个确定的点。还给出了安全等级的绝对可能性和相对可能性的计算方法。实例表明,笔者所提出的安全等级特征量及可能性的计算方法是科学的、合理的 相似文献
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建筑施工企业事故频发,对建筑安全成本认识不足是导致事故发生的重要原因。建筑施工企业安全成本包括保证性安全成本和损失性安全成本。通过合理的保证性安全投入,提升安全水平,减少损失性成本,成为建筑安全领域的重要课题。对建筑施工企业安全成本研究成果进行梳理,从3个方面进行了综述:安全教育及培训投入,间接损失成本估算方法,建筑安全成本的影响因素。最后,从法律、政府、建筑施工企业自身等角度提出提升我国建筑施工企业安全成本管理的对策,并根据现有研究不足指明未来研究的方向。 相似文献
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为了更有效地开展空域安全风险管理工作,本文总结了目前国内外空域安全风险评估的研究成果,重点概述了空域安全风险因果模型、空域安全风险人因可靠性分析、空域安全风险雷达模拟机验证法和碰撞风险模型四类空域安全风险评估方法,并对这四类方法进行了对比分析,剖析了各模型的应用领域、解决的问题、优缺点、限制条件以及发展方向,以为空域安全风险评估研究与风险管理的深入开展和具体实施提供理论依据. 相似文献