INDICATIONS OF GROUND WATER INFLUENCES ON NUTRIENT TRANSPORT THROUGH SCHWATKA LAKE,YUKON TERRITORY1

ABSTRACT: Samples were collected upstream and downstream of Schwatka Lake, Yukon Territory, to examine nutrient transport through a small northern impoundment. Annual loads were estimated for total phosphorus, nitrate plus nitrite, total dissolved nitrogen, silicate, total inorganic carbon, and total organic carbon. Transport of these materials out of the impoundment was greater than estimated for the upstream location. Results of a short term temporal study confirmed that the output exceeded the input to the lake. There are several processes which might be responsible for this occurrence, of these, ground water contributions appear to be the active process.     

QUALITY ASSURANCE TECHNIQUES FOR ELECTRONIC DATA ACQUISITION1

ABSTRACT: Electronic instruments are increasingly being used to gather water quality data. Quality assurance protocols are needed which provide adequate documentation of the procedures followed in calibration, collection, and validation of electronically acquired data. The level of precision of many data loggers exceeds the technology which is commonly used to make field measurements. Overcoming this problem involves using laboratory quality equipment in the field or enhanced quality control at the time of instrument servicing. Time control procedures for data loggers are needed to allow direct comparisons of data between instruments. Electronic instruments provide a mechanism to study transient events in great detail, but, without time controls, multiple loggers produce data which contain artifacts due to timing errors. Individual sensors deployed with data loggers are subject to different degrees of drift over time. Certain measurements can be measured with defined precision and accuracy for long periods of time, while other sensors are subject to loss of both precision and accuracy with increasing time of use. Adequate quality assurance requires the levels of precision and accuracy be documented, particularly those which vary with increasing time deployment.     

EVALUATION OF WATER QUALITY SAMPLING LOCATIONS ON THE YUKON RIVER1

ABSTRACT: This paper presents an approach to the evaluation of water quality sampling locations for their potential use for long term monitoring. This approach was applied to four sites on the Yukon River near the Canada-United States boundary. At three of these sites it was difficult to obtain representative samples due to the presence of extensive lateral heterogeneities. These heterogeneities occur because of a lack of mixing between the Yukon River and the major tributaries upstream from Dawson. Only one of the sampling locations is spatially homogeneous enough to provide representative samples. Concentration variations over the annual cycle are very large, often as much as two orders of magnitude. Estimates are made of the frequency and density with which samples must be collected to be able to detect a 10 percent different between annual mean concentrations. The estimated frequencies are so large that such an undertaking would be impractical. More importantly, the assumptions of this analysis are invalid, and time series analysis of fixed frequency samples is proposed as an alternative that is statistically rigorous and requires fewer samples.     

MONITORING STRATEGIES TO DETERMINE COMPLIANCE WITH WATER QUALITY OBJIECTIVES1

ABSTRACT: Two sampling strategies designed to test for compliance with water quality objectives are examined. For objectives based on long-term mean requirements, fixed frequency sampling at frequent intervals is most advantageous regardless of the underlying distribution of the data. For objectives that are based on maximum allowable concentrations, effective sampling strategies increase the likelihood of detecting noncompliance. If data are highly autocorrelated or sharply seasonal in distribution, an exceedance-driven sampling strategy is more effective and efficient for detecting violations than fixed frequency sampling. However, data generated by exceedance-driven sampling provide biased estimates of mean and standard deviation.     

The effects of pruning and nodal adventitious roots on polychlorinated biphenyl uptake by Cucurbita pepo grown in field conditions

Two cultivation techniques (i-pruning and ii-nodal adventitious root encouragement) were investigated for their ability to increase PCB phytoextraction by Cucurbita pepo ssp pepo cv. Howden (pumpkin) plants in situ at a contaminated industrial site in Ontario (Aroclor 1248, mean soil [PCB] = 5.6 μg g⁻¹). Pruning was implemented to increase plant biomass close to the root where PCB concentration is known to be highest. This treatment was found to have no effect on final shoot biomass or PCB concentration. However, material pruned from the plant is not included in the final shoot biomass. The encouragement of nodal adventitious roots at stem nodes did significantly increase the PCB concentration in the primary stem, while not affecting shoot biomass. Both techniques are easily applied cultivation practices that may be implemented to decrease phytoextraction treatment time.     

Changes in Extractable Metal Concentrations During Storage of Surface Water Samples Containing Sediments1

ABSTRACT: Changes in metal concentrations during storage of acidified water samples were studied. Water samples with high concentrations of suspended sediment were collected from the Fraser River, British Columbia. These samples were analyzed for “extractable” metals, which are defined to be the dissolved metals plus those metals extracted from suspended sediment by dilute mineral acid. Concentrations of extractable Cu, Fe, Pb, Zn, Ni, Co, Mn, and Cd were determined over time. Metal concentrations in these water samples were not stable and showed significant increases throughout the storage period. These results suggest that the extractable metal technique is inappropriate for the analysis of water samples containing suspended sediment.     

GOALS AND DATA COLLECTION DESIGNS FOR WATER QUALITY MONITORING1

ABSTRACT: Water quality monitoring cannot address every information need through one data collection procedure. This paper discusses the goals and related procedures for designing water quality monitoring programs. The discussion focuses on the broad information needs of those agencies operating water quality networks. These information needs include the ability to assess trends and environmental impacts, determine compliance with objectives or standards, estimate mass transport, and perform general surveillance. Each of these information needs has different data requirements. This paper outlines these goals and discusses factors to consider in developing a monitoring plan on a site by site basis.