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531.
532.
David F. Miller Wm. E. Wilson Jr. Robert G. Kling 《Journal of the Air & Waste Management Association (1995)》2013,63(7):414-417
An electrochemical instrument of the type commonly used to monitor total oxidants was adapted to measure acid gases such as SO2, HCI, and HCO2H. By using chemical methods of treating the air sample prior to absorption, it is possible to monitor for specific oxidants and acids. Measurements of NO, NOx, and SO2 during smog-chamber experiments were found to be in good agreement with measurements made by other methods. 相似文献
533.
Richard D. Wilson David W. Minnotte 《Journal of the Air & Waste Management Association (1995)》2013,63(10):761-766
Several existing federal and state provisions act to reduce the cost to in dustry of controlling air pollution. Included are the federal corporate income tax, depreciation allowances, investment credits, small Business Administration loans, Economic Development Administration aid, and state tax laws. These provisions give government assistance to industry amounting to as much as 59 percent of the cost of air pollution control. Numerous bills have been introduced in Congress that would give additional government aid to industry in the form of special across-the-board tax allowances for air pollution control equipment. A typical bill of this type would result in the government bearing an additional 11 percent of these costs. There are several possible objectives for this kind of additional aid; however, none of these seem valid when the amount of present assistance is recognized. From this analysis, it would seem that additional across-the-board tax subsidies for air pollution control equipment are neither required nor advisable. Future studies and/or experience may show certain firms or industries for which air pollution control will be too great a burden and for which additional government assistance is advisable. When such cases are found, legislation should be enacted only after the pros and cons of the various assistance methods are considered. 相似文献
534.
Wm. E. Wilson Jr Arthur Levy 《Journal of the Air & Waste Management Association (1995)》2013,63(6):385-390
There is an appreciable chemical interaction between SO2 and photochemical smog which depends on the concentration of SO2 and water vapor. The rate of decay of SO2 concentration is greatly increased in the presence of photochemical smog. With 0.75 ppm SO2, a light-scattering aerosol is produced in dry systems and systems at 22 and 55% relative humidity (RH). Aerosol is not observed until after the NO2 peak has been reached and the NO concentration has fallen to a very low value. The formation of aerosol corresponds in time to the region of most rapid decrease in the SO2 profile. In systems at 65% RH or with smaller amounts of SO2, no light scattering is observed, but the percentage of SO2 disappearing is greater. In relatively dry systems the presence of SO2 results in a general slowing down of the photochemical smog reactions. In systems containing water vapor concentrations comparable to those found in the atmosphere, the inhibiting influence of SO2 on the smog reaction is less pronounced. However, the maximum concentration of oxidant produced by the photochemical smog reactions is significantly lower when SO2 is present. 相似文献
535.
Robert B. Snyder W. Ira Wilson Irving Johnson Albert A. Jonke 《Journal of the Air & Waste Management Association (1995)》2013,63(10):975-981
The information presented in this paper is directed to engineers who are involved with environmental emissions from coal conversion plants. Synthetic sorbents were investigated as an alternative to natural sorbents (limestone) for the removal of SO2 from the combustion gas in a fluidized-bed coal combustor. The sulfation rate of a synthetic sorbent, CaO in α-AI2O3, was determined as a function of gas composition, temperature, and calcium concentration in the sorbent. The reaction was found to be diffusion-controlled above 850°C and kinetically controlled at lower temperatures. The physical characteristics of the support material have a major effect oh the sulfation kinetics. Porosity measurements indicated that supports containing large pores (>0.2 µm) produced sorbents having high sulfation rates and that pores with diameters less than 0.2 µm did not contribute significantly to the capture of SO2. The sorbents SrO in α-AI2O3 and BaO in α-AI2O3 had lower SO2 capture rates than did CaO in α-AI2O3. The alkali metal oxide sorbents K2O and Na2O in α-AI2O3 captured SO2 much faster than did the alkaline earth metal oxides. 相似文献
536.
David Mage William Wilson Vic Hasselblad Lester Grant 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1280-1291
ABSTRACT Recent epidemiological studies have consistently shown that the acute mortality effects of high concentrations of ambient particulate matter (PM), documented in historic air pollution episodes, may also be occurring at the low to moderate concentrations of ambient PM found in modern urban areas. In London in December 1952, the unexpected deaths due to PM exposure could be identified and counted as integers by the coroners. In modern times, the PM-related deaths cannot be as readily identified, and they can only be inferred as fractional average daily increases in mortality rates using sophisticated statistical filtering and analyses of the air quality and mortality data. The causality of the relationship between exposure to ambient PM and acute mortality at these lower modern PM concentrations has been questioned because of a perception that there is little significant correlation in time between the ambient PM concentrations and measured personal exposure to PM from all sources (ambient PM plus indoor-generated PM). This article shows that the critical factor supporting the plausibility of a linear PM mortality relationship is the expected high correlation in time of people's exposure to PM of ambient origin with measured ambient PM concentrations, as used in the epidemiological time series studies. The presence of indoor and personal sources of PM masks this underlying relationship, leading to confusion in the scientific literature about the strong underlying temporal relationship between personal exposure to PM of ambient origin and ambient PM concentration. The authors show that the sources of PM of non-ambient origin operate independently of the ambient PM concentrations, so that the mortality effect of non-ambient PM, if any, must be independent of the effects of the ambient PM exposures. 相似文献
537.
Nima Afshar-Mohajer Christina Wilson Chang-Yu Wu James E. Stormer 《Journal of the Air & Waste Management Association (1995)》2016,66(4):377-386
Due to concerns about adverse health effects associated with inhalation of atmospheric polycyclic aromatic hydrocarbons (PAHs), 30 ambient air samples were obtained at an air quality monitoring station in Palm Beach County, Florida, from March 2013 to March 2014. The ambient PAH concentration measurements and fractional emission rates of known sources were incorporated into a chemical mass balance model, CMB8.2, developed by EPA, to apportion contributions of three major PAH sources including preharvest sugarcane burning, mobile vehicles, and wildland fires. Strong association between the number of benzene rings and source contribution was found, and mobile vehicles were identified to be the prevailing source (contribution ≥56%) for the observed PAHs concentration with lower molecular weights (four or fewer benzene rings) throughout the year. Preharvest sugarcane burning was the primary contributing source for PAHs with relatively higher molecular weights (five or more benzene rings) during the sugarcane burning season (from October to May of the next year). Source contribution of wildland fires varied among PAH compounds but was consistently lower than for sugarcane burning during the sugarcane harvest season. Determining the major sources responsible for ground-level PAHs serves as a tool to improving management strategies for PAH emitting sources and a step toward better protection of the health of residents in terms of exposure to PAHs. The results obtain insight into temporal dominance of PAH polluting sources for those residential areas located near sugarcane burning facilities and have implications beyond Palm Beach County, in areas with high concerns of PAHs and their linked sources.Implications: Source apportionment of atmospheric polycyclic hydrocarbons (PAHs) in Palm Beach County, Florida, meant to estimate contributions of major sources in PAH concentrations measured at Belle Glade City of Palm Beach County. Number of benzene rings was found to be the key parameter in determining the source with the prevailing contribution. Mobile vehicle sources showed a higher contribution for species with four or fewer benzene rings, whereas sugarcane burning contributed more for species with five or more benzene rings. Results from this study encourage more control for sugarcane burns and help to better manage authorization of the sugarcane burning incidents and more restrictive transportation plans to limit PAH emissions from mobile vehicles. 相似文献
538.
539.
Oliveira-Filho Eduardo C. Filho José Sousa Novais Luana A. Peternele Wilson S. Azevedo Ricardo B. Grisolia Cesar K. 《Environmental science and pollution research international》2016,23(18):18362-18368
Environmental Science and Pollution Research - This study aims to evaluate the effects of maghemite nanoparticles (γ-Fe2O3) coated with meso-2, 3-dimercaptosuccinic acid (DMSA) stabilizer on... 相似文献
540.
Geoff Wilson Giovanni Quaranta Claire Kelly Rosanna Salvia 《Journal of Environmental Planning and Management》2016,59(3):518-537
This study analyses social, economic and political “lock-ins” for understanding community resilience and land degradation. The study focuses on lock-ins from within communities, using four case study communities in Italy affected by land degradation. The analysis highlights the complex interrelationships between various lock-ins, and suggests that the communities are on declining resilience pathways that may lead to increasing difficulties in addressing land degradation issues in future. 相似文献