Waste cooking oil (WCO) was experimentally examined to determine whether it can be used as an alternative fuel in a 3-cylinder, 4-stroke, direct injection, 48 kW power tractor engine. The test engine was operated under full load conditions using diesel fuel and waste vegetable oil from the 2400 to 1100 rpm and performance values were recorded. Tests were performed in two stages to evaluate the effect of the waste oils on the engine life cycle. When the test engine was operated with diesel fuel and waste cooking oil; engine torque decreased between at ratio of 0.09 % and 3% according to the engine speed. While no significant difference occurs in the diesel fuel tests at the end of 100 hours of operation, an important reduction was observed in the engine torque of the WCO engine between 4.21% and 14.48% according to the engine speed, and an increase in average smoke opacity ratio was also observed. In accordance with the results obtained from the studies, it was determined that the engine performance values of waste cooking oil show similar properties with diesel fuel, but in long-term usage, performance losses increased. In the SEM analysis performed on the fuel system, there were dark deposits at the nozzle tip and stem. According to an EDX analysis at the nozzle tips, the detected elements point to engine oil ash in the combustion chamber and show coking products (C and O). The other elements (Na, S, Ca, P, Cl, and K) point to used WCO. 相似文献
Agricultural wastewater that produces color are of environmental and health concern as colored effluent can produce toxic and carcinogenic by-products. From this study, batch culture optimization using response surface methods indicated that the fungus isolated from the pineapple solid waste, Curvularia clavata was able to decolorize sterile palm oil mill effluent (POME) which is mainly associated with polyphenol and lignin. Results showed successful decolorization of POME up to 80 % (initial ADMI [American Dye Manufacturing Index] of 3,793) with 54 % contributed by biosorption and 46 % by biodegradation after 5 days of treatment. Analysis using HPLC and GC-MS showed the degradation of color causing compound such as 3-methoxyphenyl isothiocynate and the production of new metabolites. Ecotoxicity test indicated that the decolorized effluent is safe for discharge. To determine the longevity of the fungus for a prolonged decolorization period, sequential batch decolorization studies were carried out. The results showed that lignin peroxidase and laccase were the main ligninolytic enzymes involved in the degradation of color. Carboxymethyl cellulase (CMCase) and xylanase activities were also detected suggesting possible roles of the enzymes in promoting growth of the fungus which consequently contributed to improved decolorization of POME. In conclusion, the ability of C. clavata in treating color of POME indicated that C. clavata is of potential use for decolorization and degradation of agricultural wastewater containing polyphenolic compounds. 相似文献
The use and utilization areas of geographic information system (GIS) increase every day due to both enabling easiness in storing, updating, grouping, analyzing, correlating, and mapping of data about evaluation factors in planning studies and having quite low error margin depending on the accuracy of data stored. In fact, GIS is also used both in visualization and in various analyses in planning tourism terrains. In this study, the effectiveness of GIS on holistic evaluation of natural and cultural resources in planning tourism terrains was analyzed. Natural and cultural resources in Kayseri Yahyal? were quantified by using ArcGIS 9.3 software from GIS software; data were analyzed and potential tourism and recreation terrains, level of suitability, and rate of coverage were determined. As a result of the analyses, it was determined that 11.847 ha area (6,53 %) was quite suitable for such kind of activities, 103.010 ha (56,77 %) was suitable, 39.278 ha (21,65 %) was less suitable, and 27.314 ha area (15,05 %) was not suitable. In the next stage, landscape properties which are suitable for tourism and recreation were evaluated and landscape types were classified in the sense of their tourist attraction. It was determined that the water resources and valley landscapes were the basic sources of the tourism and recreation activities of Yahyal?, and it was determined that the landscape of the forest and mountain was important for variety of the tourism and recreation activities of Yahyal?. 相似文献
The objective of this work was to determine some physical and mechanical properties of the high density polyethylene (HDPE)
composites reinforced with various mixtures of the paper sludge and the wood flour, and to evaluate the coupling agent performance.
The waste sludge materials originating from two different sources including paper making waste water treatment sludge (PS)
and ink-eliminated sludge (IES) were characterized in terms of physico-chemical properties. In the experiment, four levels
of paper sludge (20, 30, 40 and 60 wt%), three levels of wood flour (20, 40 and 60 wt%), and two levels of coupling agent
(MAPE) content (2 and 3 wt%) were used. The flexural properties of the composites were positively affected by the addition
of the sludge. Especially, tensile modulus improved with the increase of paper sludge content. With the addition of MAPE,
flexural properties improved considerably compared with control specimens (without any coupling agent). The results showed
that the water absorption (WA) and thickness swelling (TS) values of the samples decreased considerably with increasing sludge
content in the composite, while they increased with increasing wood flour content. It is to be noted that with incorporation
of MAPE in the composite formulation, the compatibility between the wood flour and HDPE was enhanced through esterification,
which reduced the WA and TS and improved the mechanical properties. Composites made with IES exhibited superior physico-mechanical
properties compared with the PS filled composites. Overall results suggest that the waste paper sludge materials were capable
of serving as feasible reinforcing fillers for thermoplastic polymer composites. 相似文献
The kinetic behavior of polyesterification of the alkyd resins synthesized using glycerol and phthalic anhydride modified
with oleic acid from the palm oil at temperatures between 120 and 240 °C was studied. Three alkyds having oleic acid contents
of 28, 40, and 65% were prepared by employing fatty acid method. The extent of the polyesterification reaction and average
degree of polymerization were monitored by determining the acid number of the aliquot of the reaction mixture at various intervals
of time and by measuring the volume of water evolved. Kinetic studies revealed that initial reaction rates followed a second-order
kinetics up to certain limit and thereafter deviations were observed. The extent of reaction varied from 77.4 to 86.3% before
deviation for all the three samples and exhibited a considerable degree of conversion. The second-order rate constants calculated
from the linear part were found to be of the order of 10−5 g (mg KOH)−1 min−1. Molecular weight of the alkyd samples was determined by GPC; number average molecular weight of the alkyds ranged from 980
to 2,070. 相似文献
The synthesis and characterization of poly (acrylic acid) grafted pectin hydrogel followed by biosorption and desorption characteristics of cadmium, as a model heavy metal, have been studied. The grafted eco-friendly pectin based interpenetrating hydrogel was prepared in the presence of gluteraldehyde crosslinker under N2 atmosphere and characterized using 1H-NMR, FTIR, TGA and SEM techniques. Gluteraldehyde was found to form one-arm and two-arm crosslinks in the copolymer. Upon grafting, two-dimensional sheet structures bounded to tubular and vascular cylindrical rods were observed. The biosorption and desorption data, determined experimentally, were fitted to pseudo-second order reaction kinetics. At higher ionic strength values, the maximum metal uptake value (qmax) was lowered and pseudo-second order rate constant (k2) was increased. Whereas, at higher pH values the maximum metal uptake value (qmax) was increased and Pseudo-second order rate constant (k2) was decreased. 0.1?M HCl solution was a suitable eluent to regenerate the hydrogel surface and recover the adsorbed cadmium metal ions. Pectin based copolymer could be used as an efficient candidature biosorbent for the recovery of cadmium metal ions from aqueous solutions. 相似文献
Environmental Economics and Policy Studies - Reducing the negative effects of vehicle emissions is one of the main priorities for governments worldwide. Comprehensive understanding of the costs and... 相似文献
Studies on the production of biogas of different organic materials in an anaerobic environment are being carried out all over the world. The most important parameters in these researches can be listed as raw material potential, production processes, economic analyses, and environmental effects. Chicken manure is one of the raw materials used in biogas production. In this study, in addition to the analysis of biogas and energy production potential from chicken manure, greenhouse gas emissions were analyzed to evaluate environmental effects. In Turkey, chicken manure is not adequately processed and causes environmental pollution. The model biogas plant and potential energy generation were researched in this field study. The pilot plant produces 8.58 million m3 of biogas per year by processing about 110 thousand tons of waste. It produces 17 GWh/year of electricity and 16 GWh/year of thermal energy, as well as reducing CO2 greenhouse gas emissions by 13.86 thousand tons/year.
Objectives. The aim of this study was to assess the relationship between occupational cognitive failures (OCFs) and unsafe behaviors, accidents and driving offences among municipal bus drivers in Tehran, Iran. Methods. Systematic random sampling was used to select 190 drivers from 3 transport and traffic Tehran districts. Data were collected with the occupational cognitive failure questionnaire (OCFQ), the driver behavior questionnaire and a data collection form. Results. The mean (SD) numbers of driving-related offences and road traffic accidents were 1.5 (2.6) and 0.37 (1.0), respectively. The mean (SD) numbers of deliberate driving violations, unintended violations, driving slips and mistakes were 6.97 (5.5), 1.61 (1.5), 13.6 (9.0) and 4.53 (3.28), respectively. The mean (SD) number of the OCFs was 28.9 (20.5). A significant correlation was found between occupational cognitive error and unsafe driving behavior subscales. The stepwise logistic regression results showed that, while controlling the effects of confounding factors, the OCF predicts 6%, 9%, 15% and 9% of deliberate violations, unintended violations, driving slips and driving mistakes, respectively. Conclusion. The results of this study show that the score of the OCFQ is a predictor of unsafe driving behaviors and its subscales. 相似文献
Objective. Construction is a hazardous occupation due to the unique nature of activities involved and the repetitiveness of several field behaviors. The aim of this methodological and theoretical review is to explore the empirical factors influencing unsafe behaviors and accidents on construction sites. Methods. In this work, results and findings from 56 related previous studies were investigated. These studies were categorized based on their design, type, methods of data collection, analytical methods, variables, and key findings. A qualitative content analysis procedure was used to extract variables, themes, and factors. In addition, all studies were reviewed to determine the quality rating and to evaluate the strength of provided evidence. Results. The content analysis identified 8 main categories: (a) society, (b) organization, (c) project management, (d) supervision, (e) contractor, (f) site condition, (g) work group, and (h) individual characteristics. The review highlighted the importance of more distal factors, e.g., society and organization, and project management, that may contribute to reducing the likelihood of unsafe behaviors and accidents through the promotion of site condition and individual features (as proximal factors). Conclusion. Further research is necessary to provide a better understanding of the links between unsafe behavior theories and empirical findings, challenge theoretical assumptions, develop new applied theories, and make stronger recommendations. 相似文献