全文获取类型
收费全文 | 118篇 |
免费 | 0篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 4篇 |
环保管理 | 8篇 |
综合类 | 30篇 |
基础理论 | 10篇 |
污染及防治 | 50篇 |
评价与监测 | 8篇 |
社会与环境 | 4篇 |
出版年
2017年 | 2篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2013年 | 12篇 |
2012年 | 9篇 |
2011年 | 8篇 |
2010年 | 2篇 |
2009年 | 6篇 |
2008年 | 6篇 |
2007年 | 11篇 |
2006年 | 13篇 |
2005年 | 11篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有118条查询结果,搜索用时 341 毫秒
21.
Yuchi Lee Shanglien Lo Jeff Kuo Chinghong Hsieh 《Frontiers of Environmental Science & Engineering》2012,6(1):17-25
Microwave-hydrothermal treatment of persistent and bioaccumulative perfluorooctanoic acid (PFOA) in water with persulfate (S2O 8 2? ) has been found effective. However, applications of this process to effectively remediate PFOA pollution require a better understanding on free-radical scavenging reactions that also take place. The objectives of this study were to investigate the effects of pH (pH = 2.5, 6.6, 8.8, and 10.5), chloride concentrations (0.01?C0.15 mol·L?1), and temperature (60°C, 90°C, and 130°C) on persulfate oxidation of PFOA under microwave irradiation. Maximum PFOA degradation occurred at pH 2.5, while little or no degradation at pH 10.5. Lowering system pH resulted in an increase in PFOA degradation rate. Both high pH and chloride concentrations would result in more scavenging of sulfate free radicals and slow down PFOA degradation. When chloride concentrations were less than 0.04 mol·L?1 at 90°C and 0.06 mol·L?1 at 60°C, presence of chloride ions had insignificant impacts on PFOA degradation. However, beyond these concentration levels, PFOA degradation rates reduced significantly with an increase in chloride concentrations, especially under the higher temperature. 相似文献
22.
Chih-Wei Yang Tsung-Ling Hsieh Shiau-Feng Lin Chiuhsiang Joe Lin Hui-Ming Teng Yu-Fang Chiu 《Safety Science》2011,49(10):1309-1313
This study evaluated the operators’ signal-detection performance in video display unit (VDU) monitoring tasks of the main control room (MCR). So far the study of the relationship between VDU design strategy and human errors has been superficial. To validate the effect of VDUs design strategies on operating errors in the MCR, this present research adopted a within subject experimental design to develop different experimental treatments based on two types of display modes included consistent mode and mixed mode. A total of 13 undergraduate and graduate students were recruited as participants in the experiment. Dependent variables included situation awareness, reaction time, error frequency, and subjective performance. Some research support was found for the representation principles. The conclusions of this study could not only be implemented by the human-system interface (HSI) designers of a MCR in the advanced nuclear power plant (NPP) but also could be generalized to the extent that other digital workstation similar to the MCR. 相似文献
23.
In this study, a fluidized-bed reactor (FBR) was employed to treat copper-containing wastewater by mean of copper precipitation on the surface of sand grains. The conditions for optimum copper removal efficiency were also investigated. This technology was controlled so as to keep supersaturation low to induce the nucleated precipitation of copper coating on the sand surface in an FBR. The effects of relevant parameters, such as the pH value, the molar ratio of [C(T)] to [Cu(2+)], hydraulic loading and the types of chemical reagents used, were examined. The experimental results indicated that 96% copper removal efficiency could be achieved when the influent copper concentration was 10mg l(-1). The optimum chemical reagent was Na(2)CO(3); the molar ratio of [C(T)]/[Cu(2+)] was 2, and the optimal hydraulic loading was not be more than 25m h(-1). In addition, preventing homogeneous nucleation in the FBR was an important operation parameter. Homogeneous nucleation and molecular growth would lead to undesirable microparticle formation in the effluent. A good mixture of carbonate and copper in the presence of sand grains could reduce the level of homogeneous nucleation in the bottom of the reactor. Energy dispersive analysis (EDS) of X-rays provided insight into the copper coating on the sand surface, and element analysis indicated the weight percentages of CuCO(3) and Cu(OH)(2) in precipitate. 相似文献
24.
Organotin contamination in fishes with different living patterns and its implications for human health risk in Taiwan 总被引:1,自引:0,他引:1
Contaminated levels of butyl- and phenyltin compounds, tributyltin (TBT), dibutyltin (DBT), monobutyltin (MBT), triphenyltin (TPT), diphenlytin (DPT), and monophenyltin (MPT), were investigated in pelagic, demersal and cultured fish species from different seasons and locations in Taiwan. Seasonal variations were found in fishes from Wuchi and Hsingta fishing harbors for their butyltin levels (winter>summer) with the opposite trend for phenyltins in fishes from Patoutzu fishing harbor and demersal fishes from four fishing harbors (summer>winter). Fish liver contained the lowest percentage of TBT and the highest percentage of TPT among six organotin compounds. Consumption of contaminated pelagic species and fishes from Hsingta fishing harbor had the highest hazard index. However, the hazard quotients and hazard indices were all less than 1, suggesting a daily exposure at these levels of TBT, DBT and TPT may not be likely to cause any deleterious effects during lifetime in human population. 相似文献
25.
Profiles of PAH emission from steel and iron industries 总被引:5,自引:0,他引:5
In order to characterize the polycyclic aromatic hydrocarbons (PAHs) emission from steel and iron industries, this study measured the stack emission of twelve steel and iron plants in southern Taiwan to construct a set of source fingerprints. The study sampled the emissions by the USEPA's sampling method 5 with the modification of Graseby for the gas and particulate phase PAH and, then, used Hewlett-Packard 5890 gas chromatograph equipped with mass spectrometer detector to analyze the samples. The steel and iron industries are classified into three categories on the basis of auxiliary energy source: Category I uses coal as fuel, Category II uses heavy oil as fuel and Category III uses electric arc furnace. The pollution source profiles are obtained by averaging the ratios of individual PAH concentrations to the total concentration of 21 PAHs and total particulate matter measured in this study. Results of the study show that low molecular weight PAHs are predominant in gas plus particulate phase for all three categories. For particulate phase PAHs, however, the contribution of large molecular weight compounds increases. Two-ring PAHs account for the majority of the mass, varying from 84% to 92% with an average of 89%. The mass fractions of 3-, 4-, 5-, 6-ring PAHs in Category I are found to be more than those of the other two categories. The mass of Category III is dominated by 7-ring PAHs. Large (or heavy) molecular weight PAHs (HMW PAHs) are carcinogenic. Over all categories, these compounds are less than 1% of the total-PAH mass on the average. The indicatory PAHs are benz[a]anthracene, benzo[k]fluoranthene, benzo[ghi]perylene for Category I, benzo[a]pyrene, acenaphthene, acenaphthylene for Category II and coronene, pyrene, benzo[b]chrycene for Category III. The indicatory PAHs among categories are very different. Thus, dividing steel and iron industry into categories by auxiliary fuel is to increase the precision of estimation by a receptor model. Average total-PAH emission factors for coal, heavy oil and electric arc furnace were 4050 μg/kg-coal, 5750 μg/l-oil, 2620 μg/kW h, respectively. Carcinogenic benzo[a]pyrene for gas plus particulate phase was 2.0 g/kg-coal, 2.4 μg/l-oil and 1.4 μg/kW h for Category I, II and III, respectively. 相似文献
26.
Ming-Kwang Shyu Chin-Der Chen Fon-Jou Hsieh M.D. Kuo-Inn Tsou Yau Ghi-Jen Lin Ming-Liang Lee 《黑龙江环境通报》1994,14(10):993-995
We present a case of recurrent meconium peritonitis detected in the second trimester and treated by intrauterine intervention. Antenatal ultrasound findings included fetal ascites and intra-abdominal calcification. Aspiration of fetal ascites under ultrasound guidance and determination of the bilirubin concentration established the diagnosis of meconium peritonitis. Paracentesis was repeated to remove irritating intestinal contents and to decrease pressure on the fetal thorax. Although the exact cause of the meconium peritonitis remains unknown, the recurrence of the condition suggests a genetic basis. A possibility of cystic fibrosis was not considered because the clinical picture did not suggest it. Intrauterine intervention helped to establish the diagnosis of meconium peritonitis and may have contributed to the good outcome. 相似文献
27.
28.
29.
Optimal nonpoint source pollution control strategies for a reservoir watershed in Taiwan 总被引:1,自引:0,他引:1
The purpose of this study is to develop a model for optimal nonpoint source pollution control for the Fei-Tsui Reservoir watershed in Northern Taiwan. Several structural best management practices (BMPs) are selected to treat stormwater runoff. The complete model consists of two interacting components: an optimization model based on discrete differential dynamic programming (DDDP) and a zero-dimensional reservoir water quality model. A predefined procedure is used to locate suitable sites for construction of various selected BMPs in the watershed. In the optimization model, the objective function is to find the best combination of BMP type and placement, which minimizes the total construction and operation, maintenance, and repair (OMR) costs of the BMPs. The constraints are the water quality standards for total phosphorus (TP) and total suspended solids (TSS) concentrations in the reservoir. A zero-dimensional reservoir water quality model of the Vollenweider type is embedded in the optimization framework to simulate pollutant concentrations in Fei-Tsui Reservoir. The resulting optimal cost and benefit of water quality improvement are depicted by the model-derived trade-off curves. The modeling framework developed in the present study could be used as an efficient tool for planning a watershed-wide implementation of BMPs for mitigating stormwater pollution impact on the receiving water bodies. 相似文献
30.
Determining the relative contributions of intrinsic and extrinsic processes to the regulation of biological populations has been a recurrent ecological issue. Recent discussions concerning ecosystem "regime shifts" again raise the question of whether population fluctuations are mainly controlled by external forcing. Results of nonlinear time series analyses indicate that pelagic populations typically do not passively track stochastic environmental variables. Rather, population dynamics are better described as nonlinear amplification of physical forcing by biological interactions. However, we illustrate that in some cases populations do show linear tracking of the physical environment. To explain why population dynamics can sometimes be linear, we propose the linear tracking window hypothesis: populations are most likely to track the stochastic environmental forcing when their generation time matches the characteristic time scale of the environmental signal. While our observations follow this hypothesis well, our results indicate that the linear tracking window is a necessary but not a sufficient condition. 相似文献