全文获取类型
收费全文 | 1290篇 |
免费 | 19篇 |
国内免费 | 193篇 |
专业分类
安全科学 | 50篇 |
废物处理 | 78篇 |
环保管理 | 110篇 |
综合类 | 345篇 |
基础理论 | 292篇 |
污染及防治 | 445篇 |
评价与监测 | 87篇 |
社会与环境 | 73篇 |
灾害及防治 | 22篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 55篇 |
2021年 | 18篇 |
2020年 | 21篇 |
2019年 | 23篇 |
2018年 | 83篇 |
2017年 | 32篇 |
2016年 | 59篇 |
2015年 | 65篇 |
2014年 | 59篇 |
2013年 | 79篇 |
2012年 | 50篇 |
2011年 | 84篇 |
2010年 | 61篇 |
2009年 | 67篇 |
2008年 | 82篇 |
2007年 | 96篇 |
2006年 | 71篇 |
2005年 | 38篇 |
2004年 | 79篇 |
2003年 | 54篇 |
2002年 | 50篇 |
2001年 | 105篇 |
2000年 | 47篇 |
1999年 | 26篇 |
1998年 | 10篇 |
1997年 | 14篇 |
1996年 | 13篇 |
1995年 | 11篇 |
1994年 | 8篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1964年 | 1篇 |
1960年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有1502条查询结果,搜索用时 781 毫秒
851.
A. Molinari C. Ayora M. Marcaccio L. Guadagnini X. Sanchez-Vila A. Guadagnini 《Environmental science and pollution research international》2014,21(3):1628-1637
Dissolved arsenic (As) concentrations detected in groundwater bodies of the Emilia-Romagna Region (Italy) exhibit values which are above the regulation limit and could be related to the natural composition of the host porous matrix. To support this hypothesis, we present the results of a geochemical modeling study reproducing the main trends of the dynamics of As, Fe, and Mn concentrations as well as redox potential and pH observed during batch tests performed under alternating redox conditions. The tests were performed on a natural matrix extracted from a deep aquifer located in the Emilia-Romagna Region (Italy). The solid phases implemented in the model were selected from the results of selective sequential extractions performed on the tested matrix. The calibrated model showed that large As concentrations have to be expected in the solution for low crystallinity phases subject to dissolution. The role of Mn oxides on As concentration dynamics appears significant in strongly reducing environments, particularly for large water–solid matrix interaction times. Modeled data evidenced that As is released firstly from the outer surface of Fe oxihydroxides minerals exhibiting large concentrations in water when persistent reducing conditions trigger the dissolution of the crystalline structure of the binding minerals. The presence of organic matter was found to strongly affect pH and redox conditions, thus influencing As mobility. Figure
Graphical Abstract 相似文献
852.
Leo X. C. Dutra Nick Ellis Pascal Perez Cathy M. Dichmont William de la Mare Fabio Boschetti 《Ambio》2014,43(8):1069-1081
This article analyzes interviews with natural resource managers in South East Queensland (SEQ), Australia. The objectives of the research are (i) to apply and test deductive/inductive text analysis methods for constructing a conceptual model of water quality decision-making in SEQ, (ii) to understand the role of information in the decision-making process, and (iii) to understand how to improve adaptive management in SEQ. Our methodology provided the means to quickly and objectively explore interview data and also reduce potential subjective bias normally associated with deductive text analysis methods. At a more practical level, our methodology indicates potential intervention points if one is to influence the decision-making process in the region. Results indicate that relevant information is often ignored in SEQ, with significant consequences for adaptive management. Contextual factors (political, social, and environmental) together with effective communication or lobbying strategies often prevent evidence-based decisions. We propose that in addition to generating information to support decisions, adaptive management also requires an appraisal of the true character of the decision-making process, which includes how stakeholders interact, what information is relevant and salient to management, and how the available information should be communicated to stakeholders and decision-making bodies.
Electronic supplementary material
The online version of this article (doi:10.1007/s13280-014-0537-4) contains supplementary material, which is available to authorized users. 相似文献853.
Ping Zhu Zhen Bang Cao Liang You Wang Yi Li Ye Guang Ren Qian Tie Hua Cao Bo Lu Ming Zhou 《Journal of Material Cycles and Waste Management》2014,16(1):156-161
The Chinese integrated circuit industry has been transformed from a small state-owned sector into a global competitor, but chip manufacturing produces large amounts of calcium fluoride sludge (CFS). The current treating method is landfill in China. In order to solve the problem of unavailable landfill sites and the dissolved CFS polluting water sources, CFS was tested as a component for a ceramic product made with sodium borate, sodium phosphate, and waste alumina using a low temperature sintering technology. The ceramic was characterized by X-ray diffraction (XRD), microstructure, compressive strength. XRD and microstructure analyses verified that CFS was transformed into Na2Ca(PO4)F as an inert crystalline phase in ceramic, which is enclosed by the borophosphate glass liquid phase. Toxicity characteristic leaching procedure and corrosion resistance tests verified that fluorine from CFS was solidified in the inert crystalline phase, which did not release to cause secondary pollution. This novel technology produces high-performance ceramic as a construction material, in accordance with the concept of sustainable development. 相似文献
854.
Claudete G. Chiochetta Marilice R. Radetski Albertina X. R. Corrêa Vinícius Tischer Erasmo N. Tiepo Claudemir M. Radetski 《Environmental science and pollution research international》2013,20(11):7656-7665
The different stages involved in coal mining-related activities result in a degraded landscape and sites associated with large amounts of dumped waste material. Remediation of these contaminated soils can be carried out by application of industrial organic sludge if the concerns regarding the potential negative environmental impacts of this experimental practice are properly addressed. In this context, the objective of this study was to use ecotoxicological tests to determine the quantity of organic industrial sludge that is required as a soil amendment to restore soil production while avoiding environmental impact. Chemical analysis of the solids (industrial sludge and soil) and their leachates was carried out as well as a battery of ecotoxicity tests on enzymes (hydrolytic activity), bacteria, algae, daphnids, earthworms, and higher plants, according to standardized methodologies. Solid and leachate samples of coal-contaminated soil were more toxic than those of industrial sludge towards enzyme activity, bacteria, algae, daphnids, and earthworms. In the case of the higher plants (lettuce, corn, wild cabbage, and Surinam cherry) the industrial sludge was more toxic than the coal-contaminated soil, and a soil/sludge mixture (66:34 % dry weight basis) had a stimulatory effect on the Surinam cherry biomass. The ecotoxicological assessment of the coal-contaminated soil remediation using sludge as an amendment is very important to determine application rates that could promote a stimulatory effect on agronomic species without negatively affecting the environment. 相似文献
855.
Xiao S. Liu Zhang F. Tong Ling Zhen Da X. Huang Xin Gao Chao Y. Xu 《Journal of environmental science and health. Part. B》2013,48(6):591-597
A method using liquid chromatography and a single mix-mode solid-phase extraction cleanup for the simultaneous analysis of thiabendazole [2-(1,3-thiazol-4-yl)-1H-benzoimidazole], carbendazim [(methyl N-(1H-benzoimidazol-2-yl)-carbamate)] and 2-aminobenzimidazole (1H-benzimidazol-2-amine) in concentrated fruit juices is described. The three fungicides were isolated from the samples and concentrated by solid-phase extraction on Oasis MCX cartridges. The determination was performed by liquid chromatography with a diode array, detecting at 288 nm. In this method, the average recoveries from blank control juice samples spiked in a concentration range of 0.01–0.10 mg/kg were in the range of 81–95%, with relative standard deviations below 8%. Detection limits and limits of quantification were 4 μ g/kg and 10 μ g/kg, respectively, for each fungicide. Real juice samples were analyzed by the proposed method. The results were compared to those from liquid chromatography-tandem mass spectrometry. 相似文献
856.
Zhi F. Xu Ge Wen Dai Z. Kuang Fu X. Zhang Si P. Tang 《Journal of environmental science and health. Part. B》2013,48(5):336-343
A deltamethrin-imprinted polymer (MIP1) was prepared using bis(-6-O-butanediacid monoester)-β-cyclodextrin (BBA-β-CD) as the functional monomer and toluene 2,4-diisocyanate (TDI) as the cross-linker. In comparison to the molecularly imprinted polymer where β-CD was applied as the functional monomer (MIP2), MIP1 showed a higher specific binding capacity (ΔCP) and an improved imprinting factor (IF) for deltamethrin. The selective recognition experiments demonstrated that compared to MIP2, MIP1 could better recognize its template over other substrates that had similar chemical structures. The solid phase extraction (SPE) of deltamethrin using MIP1 as the adsorbent was further investigated. The recoveries of the molecularly imprinted solid phase extraction (MISPE) column for deltamethrin were 83.2–93.4% with relative standard deviations (RSD) of 2.03–6.19%. The method has been successfully applied to the enrichment of trace deltamethrin from real water samples. 相似文献
857.
858.
859.
Luna Y Otal E Vilches LF Vale J Querol X Fernández Pereira C 《Waste management (New York, N.Y.)》2007,27(12):1877-1883
Treatment of municipal solid waste (MSW) landfill leachate generally results in low percentages of nutrient removal due to the high concentration and accumulation of refractory compounds. For this reason, individual physical, chemical and biological processes have been used for the treatment of raw landfill leachate and sometimes for the mixture of domestic wastewater and landfill leachate. In this work, the possibility of treating landfill leachate was tested in a bench-scale pilot plant by a two-step method combining adsorption and coagulation-flocculation. Zeolite synthesized from coal fly ash, a by-product of coal-fired power stations, was used in this study both as a decantation aid reagent and as an adsorbent of COD and NH4-N. The coagulation-flocculation step was performed by the use of aluminium sulphate and a polyelectrolyte (ACTIPOL A-401). The leachate was collected directly from a storage unit of the organic fraction of MSW, before it was composted. For this reason the raw leachate was diluted before treatment. The sludge was recirculated to enhance the removal efficiency of nutrients as well as to optimize flocculant saving and to decrease sludge production. The results showed that it is possible to remove 43%, 53% and 82% of COD, NH4-N, and suspended solids, respectively. Therefore, this method may be an alternative for ammonium removal, as well as a suitable pre- or post-treatment step, in combination with other processes in order to meet regulatory limits. 相似文献
860.
Effect of pre-ozonation on optimized coagulation of a typical North-China source water 总被引:3,自引:0,他引:3
Although ozone is widely used as a pre-oxidant before coagulation in water treatment, the effect of pre-ozonation on optimized coagulation for removal of particle and natural organic matter (NOM) is still not fully understood. In this paper, pilot-scale investigation was conducted to examine the impact of pre-ozonation on coagulation for particle and NOM removal. Changes in the particle and NOM distributions were characterized by various methods, including laser light granularity system, particle counter, ultrafiltration, and resin absorbent fractionation. A novel composite flocculant–HPAC was compared with the traditional ferric chloride coagulant in terms of coagulation efficiency under the influence of pre-ozonation. Typical micro-polluted North China surface water was used for pilot coagulation tests. The results show that the effect of pre-ozonation on coagulation is associated with the dosage of ozone, coagulant type, and water contamination characteristics. For FeCl3, pre-ozonation acts as a coagulation aid at low dosage (1.0 mg L−1 O3) for turbidity and UV254 removal; while at higher dosage (2.0 mg L−1 O3), pre-ozonation is detrimental to UV254 removal although it is still beneficial for turbidity removal. In the case of composite flocculant–HPAC, pre-ozonation demonstrates negligible influence on both turbidity and UV254 removal. Ozone can simultaneously aggregate fine particles and break down large ones, making them more mineralized and easier to remove. NOM with intermediate molecular weight and hydrophobic neutral property increases at lower ozone dosage, favoring removal by coagulation. At higher ozone dosages, NOM becomes more hydrophilic and its molecular weight becomes smaller, decreasing NOM removal. 相似文献