Characteristics of products and PCDD/DF emissions from a pyrolysis process of urethane/styrofoam waste from electrical home appliances

A plastic fraction consisting mainly of polyurethane/styrofoam waste is generated after separating valuable spare parts and metals from used electrical home appliances. In Korea, such waste is currently incinerated in cement kilns or is landfilled. However, owing to its high volatile matter content, conversion into gaseous or liquid pyrolysis products is a preferable alternative. A pyrolysis process of polyurethane and styrofoam waste from electrical home appliances was evaluated by characterizing the products generated at 500°–800°C. The para meters determined were the yields of gas, oil, and char; the characteristics of the remaining char; and the con centration of polychlorinated dibenzo-p-dioxins/polychlorinated dibenzo-furans in the product gas. As expected, the char yield decreased at higher temperatures, whereas gas and oil yields showed increasing tendency. The oil products could be used as storable fuels with a calorific value of 6000–8000 kcal/kg. Fine pores were observed in the char. The adsorption and decolorizing ability of the char were almost the same as those of activated carbon, so that pyrolysis char has potential for use as a sorbent. Further feasibility studies will be needed before utilizing pyrolysis technology to recover either fuels or usable products from polyurethane/styrofoam waste.     

Phosphorous in the environment: characteristics with distribution and effects,removal mechanisms,treatment technologies,and factors affecting recovery as minerals in natural and engineered systems

Environmental Science and Pollution Research - Phosphorus (P), an essential element for living cells, is present in different soluble and adsorbed chemical forms found in soil, sediment, and water....     

1H-NMR-based profiling of organic components in leachate from animal carcasses disposal site with time

Leachate, generated by the decomposition of animal carcasses, presents many environmental, sanitary, and food safety hazards. However, research on the characteristics of leachate is lacking. In this study, we performed biochemical profiling of leachate from two animal species (pig and cattle) in two soil types (sandy loam and sandy soil) using ¹H-NMR-based profiling, followed by multivariate data analysis. The leachate was collected from a well-controlled artificial burial site over a 31-week period. Principal components analysis (PCA) of the NMR data showed similar patterns between species and soil types. Organic components, including organic acids and phenols, predominated, and their levels increased with time. The methylamine level in leachate from pig carcasses 18 weeks following burial was significantly higher than that from cattle carcasses; leachate from cattle carcasses in sandy soil 1 week after burial contained unique components (specifically ethanol, formate, alanine, N-methylation, and taurine), in contrast with those from sandy loam soil. This study suggests that a NMR-based profiling approach is useful to characterize the organic components in leachate from animal carcasses over time.     

Degradation of different pesticides in water by microplasma: the roles of individual radicals and degradation pathways

Environmental Science and Pollution Research - Pesticides are emergent toxins often identified in aquatic environments. In the present study, microplasma was employed to reduce the pesticide...     

Reduced Soil Macropores and Forest Cover Reduce Warm‐Season Baseflow below Ecological Thresholds in the Upper Delaware River Basin

We examined the impacts of changes in land cover and soil conditions on the flow regime of the upper Delaware River Basin using the Water Availability Tool for Environmental Resources. We simulated flows for two periods, c. 1600 and 1940, at three sites using the same temperature and precipitation conditions: the East Branch, West Branch, and mainstem Delaware River at Callicoon, New York. The 1600 period represented pristine forest and soils. The 1940 period included reduced forest cover, increased agriculture, and degraded soils with reduced soil macropore fractions. A model‐sensitivity test examined the impact of soil macropore and land cover change separately. We assessed changes in flow regimes between the 1600 and 1940 periods using a variety of flow statistics, including established ecological limits of hydrologic alteration (ELOHA) thresholds. Reduced forest soil macropore fraction significantly reduced summer and fall baseflows. The 1940 period had significantly lower Q50 flows (50% exceedance) than the 1600 period, as well as summer and fall Q90 and Q75–Q90 flows below the ELOHA thresholds. The one‐ to seven‐day minimum flows were also lower for the 1940 period, by 17% on the mainstem. 1940 flows were 6% more likely than the 1600 period to fall below the low‐flow threshold for federally endangered dwarf wedgemussel (Alasmidonta heterodon) habitat. In contrast, the 1940 period had higher flows than the 1600 period from late fall to early winter.     

Ex-situ field application of electrokinetics for remediation of shooting-range soil

Electrokinetic process for remediation of a shooting-range site was evaluated in this study. By field operation for 100 days, the newly designed electrokinetic system was evaluated for process stability, performance, and efficiency. The field site of this study was an abandoned military shooting range located in the Civilian Control Line of South Korea. The target area, only, was heavily contaminated by Pb and Cu to a depth of 0.5 m. After dry-sieving of the field soil to separate particulate Pb, two cells in a hexagonal (two-dimensional) arrangement, including ten anodes outside the cell and two cathodes in the middle, were prepared. The pH of each electrolyte was adjusted by use of concentrated HNO₃, resulting in acid-enhanced electrokinetics. The monitoring results indicated that overall removal of heavy metals (Pb, Cu) was achieved, and that both heavy metals were removed from outside the cell. The average final efficiency of removal of Pb and Cu was 39.5 ± 35 and 63.8 ± 12%, respectively. Although the feasibility of this system was confirmed, for commercialization of the process confirmed drawbacks must be improved by further study.

     

Microbial PCB dechlorination in dredged sediments and the effect of moisture

Evidence of reductive dechlorination of polychlorinated biphenyls (PCBs) in sediments was investigated in Hudson River sediments dredged and encapsulated in 1978 at Moreau, NY. The effect of different moisture contents in dredged sediments on dechlorination and dechlorinating microorganisms was also determined using PCB-spiked sediments in which the moisture level was adjusted by simulating a dewatering process. The congener pattern of PCBs indicated that the dechlorination in the dredged sediments was far less advanced than that in the river sediments collected from the general area of the dredged site (Ft. Edward site). Dechlorination in encapsulated sediments at the Moreau site appeared to have stopped soon after dredging. When microorganisms eluted from the encapsulated sediments were inoculated in clean sediments spiked with Aroclor 1242, an extensive dechlorination was observed, indicating that the encapsulated sediments still harbored dechlorinating microorganisms. However, the same inoculum failed to further dechlorinate residual congeners in the dredged sediments. On the other hand, an inoculum obtained in 1990 from the dredged site in the Hudson River dechlorinated the residual congeners further. In simulated dredged sediments, the maximum level of dechlorination was lower at reduced moisture contents. The population size of dechlorinating microorganisms, as determined by the most probable number (MPN) technique, was also smaller at the lower moisture levels. There was a significant correlation between the maximum extent of dechlorination and the specific death rate of dechlorinating populations. These results indicate that the underlying mechanism of the moisture-dependent maximum dechlorination is the moisture-dependence of the death rate of dechlorinating microorganisms.