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181.
超细粉煤灰基成型吸附剂的动态吸附实验 总被引:2,自引:1,他引:1
以粉煤灰为原料制备成型吸附剂,对水溶液中亚甲基蓝和Cr6+进行动态吸附研究,绘制穿透曲线,利用Origin软件对实验数据分析处理,得出穿透曲线的通式Ct=A1-A2〖〗1+(t/t0)p+A1。结果表明,初始浓度C0=25 mg/L,填料高度不同时,达到穿透点的时间随填料高度的增加而增加;填料高度h=200 mm,初始浓度不同时,达到穿透点的时间随初始浓度的增加而减小;该吸附剂对有机染料和重金属离子均有较好的吸附性能;穿透曲线通式的回归线性相关系数表明,该通式可很好地反映超细粉煤灰成型吸附剂的动态吸附过程。 相似文献
182.
本文对大学生就业存在的自身问题、高校办学专业设置和培养模式问题、用人单位的误区问题以及现今的社会问题等进行了理性分析,并提出了加强对大学生的就业指导,引导大学生树立科学理性的就业观,广泛疏通就业途径和集聚多方力量鼓励大学生自主创业的对策。 相似文献
183.
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185.
荧光光谱法在环境监测中的应用 总被引:3,自引:0,他引:3
孙媛媛 《环境监测管理与技术》2000,12(3):12-16
简要综述了荧光光谱在环境监测中近几年的应用。内容包括方法原理、方法的建立,有关荧光体系的研究,以及与其他技术的联用等一些最新进展。指出:荧光光谱法具有灵敏度高、选择性强、试样量少和测定简单等优点,为复杂环境样品中微量元素及痕量物质的分析提价了新手段,与其他手段结合使用,环境分析将具有更加广阔的前景, 相似文献
186.
Aerobic degradation of bisphenol A by Achromobacter xylosoxidans strain B-16 isolated from compost leachate of municipal solid waste 总被引:3,自引:0,他引:3
A novel bacterium designated strain B-16 was isolated from the compost leachate of the municipal solid waste (MSW) in a laboratory reactor. This strain was identified as a gram-negative bacterium, Achromobacter xylosoxidans that could grow on bisphenol A (BPA, a representative endocrine disruptor) as a sole carbon source under aerobic condition. BPA-degrading characteristics of strain B-16 were investigated in liquid cultures. The results show that BPA degradation was influenced by several factors (e.g. inoculum size, substrate concentration, temperature and pH, etc). The half-lives, optimum temperature and pH were found to be 0.58-3.1d, 35 degrees C and 7.0, respectively. BPA-degrading activity and cell growth were inhibited at high substrate concentration. Metabolic intermediates detected during the degradation process were identified as p-hydroxybenzaldehyde, p-hydroxybenzoic acid and p-hydroquinone, respectively. Metabolic pathway of BPA degradation was proposed in this study. 相似文献
187.
Distribution of elements in needles of Pinus massoniana (Lamb.) was uneven and affected by needle age 总被引:1,自引:0,他引:1
Kuang YW Wen da Z Zhou G Liu SZ 《Environmental pollution (Barking, Essex : 1987)》2007,145(3):730-737
Macronutrients (P, S, K, Na, Mg, Ca), heavy metals (Fe, Zn, Mn, Cu, Pb, Cr, Ni, Cd,) and Al concentrations as well as values of Ca/Al in the tip, middle and base sections, and sheaths of current year and previous year needles of Pinus massoniana from Xiqiao Mountain were analyzed and the distribution patterns of those elements were compared. The results indicated that many elements were unevenly distributed among the different components of needles. Possible deficiency of P, K, Ca, Mn and Al toxicity occurred in needles under air pollution. Heavy metals may threaten the health of Masson pine. Needle sheaths were good places to look for particulate pollutants, in this case including Fe, Cu, Zn, Pb, Cr, Cd and Al. 相似文献
188.
This study investigated the effects of various factors on the anaerobic degradation of nonylphenol (NP) in soil. The results show that the optimal pH for NP degradation was 7.0 and that the degradation rate was enhanced when the temperature was increased. The addition of compost enhanced NP degradation. The individual addition of the electron donors lactate, acetate, and pyruvate inhibited NP degradation. The high-to-low order of NP degradation rates under three anaerobic conditions was sulfate-reducing conditions > methanogenic conditions > nitrate-reducing conditions. The results show that sulfate-reducing bacteria, methanogen, and eubacteria are involved in the anaerobic degradation of NP, with sulfate-reducing bacteria being a major component of the soil. Of the anaerobic strains isolated from the soil samples, strain AT3 expressed the best ability to biodegrade NP. 相似文献
189.
Kuang YW Zhou GY Da Wen Z Liu SZ 《Environmental science and pollution research international》2007,14(4):270-275
Goal, Scope and Background Rapid urbanization and the expansion of industrial activities in the past several decades have led to large increases in emissions
of pollutants in the Pearl River Delta of south China. Recent reports have suggested that industrial emission is a major factor
contributing to the damages in current natural ecosystem in the Delta area. Tree barks have been used successfully to monitor
the levels of atmospheric metal deposition in many areas, but rarely in China. This study aimed at determining whether atmospheric
heavy metal deposition from a Pb-Zn smeltery at Qujiang, Guangdong province, could be accurately reflected both in the inner
bark and the outer bark of Masson pine (Pinus massoniana L.). The impact of the emission from smeltery on the soils beneath the trees and the relationships of the concentrations
between the soils and the barks were also analyzed.
Methods Barks around the bole of Pinus massoniana from a pine forest near a Pb-Zn smeltery at Qujiang and a reference forest at Dinghushan natural reserve were sampled with
a stainless knife at an average height of 1.5 m above the ground. Mosses and lichens on the surface barks were cleaned prior
to sampling. The samples were carefully divided into the inner bark (living part) and the outer bark (dead part) in the laboratory,
and dried and ground, respectively. After being dry-ashed, the powder of the barks was dissolved in HNO3. The solutions were analyzed for iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni) and cobalt
(Co) by inductively coupled plasmas emission spectrometry (ICP, PS-1000AT, USA) and Cadmium (Cd) and lead (Pb) by graphite
furnace atomic absorption spectrometry (GFAAS, ZEENIT 60, Germany). Surface soils (0–10 cm) beneath the sample trees were
also collected and analyzed for the selected metals.
Results and Discussion Concentrations of the selected metals in soils at Qujiang were far above their environmental background values in the area,
except for Fe and Mn, whilst at Dinghushan, they were far below their background values, except for Cd and Co. Levels of the
metals, in particular Pb and Zn, in the soils beneath the sample trees at Qujiang were higher than those at Dinghushan with
statistical significance. The result suggested that the pine forest soils at Qujiang had a great input of heavy metals from
wet and dry atmospheric deposition, with the Pb-Zn smeltery most probably being the source.
Levels of Cu, Fe, Mn, Zn, Ni and Pb at Qujiang, both in the inner and the outer bark, were statistically higher than those
at Dinghushan. Higher concentrations of Pb, Fe, Zn and Cu may come from the stem-flow of elements leached from the canopy,
soil splash on the 1.5 m height and sorption of metals in the mosses and lichens growing on the bark, which were direct or
indirect results from the atmospheric deposition. Levels of heavy metals in the outer barks were associated well with the
metal concentrations in the soil, reflecting the close relationships between the metal atmospheric deposition and their accumulation
in the outer bark of Masson pine. The significant (p<0.01) correlations of Fe-Cu, Fe-Cr, Fe-Pb, Fe-Ni, Pb-Ni, and Pb-Zn in
the outer barks at Qujiang again suggested a common source for the metals. The correlation only occurred between Pb and Ni,
Cd and Co in the outer barks at Dinghushan, which suggested that those metals must possibly have other uncommon sources.
Conclusions Atmospheric deposition of the selected metals was great at Qujiang, based on the levels in the bark of Pinus massoniana and on the concentrations in the soils beneath the trees compared with that at Dinghushan. Bark of Pinus massoniana, especially the outer bark, was an indicator of metal loading at least at the time of sampling.
Recommendations and Perspectives The results from this study and the techniques employed constituted a new contribution to the development of biogeochemical
methods for environmental monitoring particularly in areas with high frequency of pollution in China. The method would be
of value for follow up studies aimed at the assessment of industrial pollution in other areas similar with the Pearl River
Delta. 相似文献
190.
基于三角模糊数的民航企业“管理”安全综合评价模型研究 总被引:2,自引:0,他引:2
在对我国民航企业安全管理的现状和常用的安全评价方法进行分析的基础上,提出并建立了民航企业"管理"安全模糊综合评价模型。首先,从组织管理、风险管理、安全保证、安全促进4个方面对民航企业安全管理的内容和特点进行分析,在此基础上建立民航企业"管理"安全评价指标体系;然后,根据三角模糊数理论和模糊综合评价理论建立民航企业"管理"安全模糊综合评价模型;通过上述指标体系和评价模型从而达到对民航企业"管理"安全进行评价的目的。最后,给出了一个应用实例,其评价结果表明:该模型具有很强的实用性和借鉴价值。 相似文献