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931.
Potential contributions of clay minerals and organic matter to pentachlorophenol retention in soils 总被引:1,自引:0,他引:1
Sorption of pentachlorophenol (PCP) by pure minerals and humic acids were measured to obtain additional perspective on the potential contributions of both clay minerals and soil organic matter (SOM) to contaminants retention in soils. Four types of common soil minerals and two kinds of humic acids (HAs) were tested. The sorption affinity for PCP conformed to an order of HAs > K-montmorillonite > Ca-montmorillonite > goethite > kaolinite. Such a difference in sorption capacity could be attributed to the crucial control of HAs. Clay minerals also had their contribution, especially K-montmorillonite, which played an important, if not dominant, role in the controlling process of PCP sorption. By removing 80% (on average) of the organic carbon from the soils with H(2)O(2), the sorption decreased by an average of 50%. The sorption reversibility had been greatly favored as well. Considering the uncharged mineral fractions in soil before and after H(2)O(2)-treated, the main variation in sorption behavior of the soil might thus be related to the removed organic carbon and the reduced pH. This testified rightly the interactive effect of SOM and clay minerals on PCP sorption as a function of pH. 相似文献
932.
Pei ZG Shan XQ Wen B Zhang S Yan L Khan SU 《Environmental pollution (Barking, Essex : 1987)》2006,139(3):541-549
The effect of copper on adsorption of p-nitrophenol on two typical Chinese soils was investigated using a batch-equilibration method. Adsorption experiments were carried out when both copper and p-nitrophenol were adsorbed simultaneously, and when copper was previously adsorbed on soils. It was observed that adsorption of p-nitrophenol decreased with increasing copper concentrations thereby indicating a competition between copper and p-nitrophenol for occupying the adsorption sites on soils. Moisture increased the hydrated sphere and the acidity of water surrounding the cation, which further reduced the adsorption of p-nitrophenol. Fourier transform infrared spectroscopy study provided the direct evidence for the coordination of p-nitrophenol sorbed by soils with metal cation in n-hexane system. It was observed that the perturbations included a red shift of the nu(asym) (NO) band, a concomitant blue-shift of the nu(sym) (NO) band and a blue-shift of C-N band when compared with the infrared spectra obtained from water solution. 相似文献
933.
Pan G Zhang MM Chen H Zou H Yan H 《Environmental pollution (Barking, Essex : 1987)》2006,141(2):195-200
Algal removal abilities of 26 clays/minerals were classified into three categories according to the 8-h equilibrium removal efficiency (Q8h) and removal rate at a clay loading of 0.7 g/L. Type I clays (sepiolite, talc, ferric oxide, and kaolinite) had a Q8h > 90%, a t50 (time needed to remove 50% of the algae) < 15 min, and a t80 < 2.5 h. Type II clays (6 clays) had a Q8h 50-90%, a t50 < 2.5 h, and a t80 > 2.5 h. Type III clays (14 clays) with Q8h < 50%, t50 > 8 h and t80 > 14 h had no practical value in removal of algal blooms. When the clay loading was reduced to 0.2 g/L, Q8h for all the 25 materials decreased to below 60%, except for sepiolite whose Q8h remained about 97%. The high efficiency for sepiolite to flocculate M. aeruginosa cells in freshwaters was due to the mechanism of netting and bridging effect. 相似文献
934.
A study of daily and seasonal variations of radon concentrations in underground buildings in major cities of China was carried out. According to the data from the Model 1027 continuous monitor, radon concentrations in the underground buildings changed through two cycles each day. The first cycle was from 12:00 to 0:00 and the highest or lowest value, depending on location, was at about 19:00. The second cycle had a little change. Based on the data from solid state nuclear detectors (SSNTDs), it was concluded that the radon concentrations in underground buildings in winter were lower than in summer, which was opposite to that above the ground level. Similar to that above the ground level, the radon concentrations in spring were close to the year-round average radon concentrations. 相似文献
935.
五种重金属在小麦植株不同器官中的分布特征 总被引:21,自引:0,他引:21
为研究Cd、Pb、As、Cu、Zn等5种重金属在小麦植株不同器官的分布特征,以郑州9023为供试品种,采用田间试验方法,应用原子吸收分光光度法和电感耦合等离子体原子发射光谱法(ICPS)分别测定了小麦植株不同器官的重金属质量分数并进行了分析。结果表明,小麦植株中较易富集Cd的器官是根、叶及废弃物,较易富集Pd、As的器官是根、茎及废弃物,较易富集Zn、Cu的器官是根、茎和籽粒;在这5种重金属中,Zn在小麦茎和籽粒中的富集系数最高,Cd在地上部分其他器官的富集系数最高,而Pb在这些器官中富集系数均为最低,Cu和As则居中。 相似文献
936.
低压导线火蔓延的研究对于飞机和航天器的防火安全具有重要意义。针对镍铬合金线芯、聚乙烯(PE)绝缘层导线火蔓延过程中的熔融滴落现象,在低压舱内开展了不同气压、不同氧气浓度的大量实验研究,获得了导线熔融滴落频率、质量和火蔓延速度,以及不同氧浓度熔融滴落的上下限。结果表明:(1)在熔融滴落过程中,由于滴落会产生向上的动量,从而使火焰在滴落后发生突然的"跳动"现象,火焰高度先增加后降低;(2)滴落上限和滴落下限随着氧浓度的增加而降低,并且可以划分为3个不同的区域:火蔓延仅存区;滴落和火蔓延共存区;无滴落无火蔓延区。滴落上限和滴落下限下降曲线在50%氧浓度、5kPa压力发生会合,此后只有火蔓延而不存在滴落现象。(3)当压力降低时,由于线芯温度增加,线芯传导热量增加,导致绝缘层熔融速率加快,从而使得滴落频率增加,同时液滴的表面张力随着压力的降低而增加,使得低压下液滴的质量变大。 相似文献
937.
938.
矿用救生舱内二氧化碳净化特性研究 总被引:1,自引:0,他引:1
煤矿救生舱是在矿井下发生事故后保护被困矿工生存、等待救援的密闭舱室设备。在救援过程中,二氧化碳的处理是舱内空气净化系统的一项主要功能。本文对救生舱内二氧化碳净化装置的功率、吸收效率、药剂床层厚度等因素进行了一系列试验,确定了救生舱二氧化碳的最优净化方式,并通过救生舱内真人生存试验对其进行了验证。最终得出救生舱内处理二氧化碳最佳反应条件为:药剂量20kg,最佳功率为100W;间歇式工作的运行时间与停机时间比例为2:3;在救生舱内8人生存模拟实验中,得出8kg药剂可供8人使用6.1h,平均吸收速率为1.34L/min。 相似文献
939.
加油站火灾爆炸故障树分析 总被引:2,自引:0,他引:2
采用安全系统工程的方法,对加油站的火灾爆炸事故进行了故障树分析。通过故障树分析,得出4个最小径集,指明了预防事故发生的可能途径;从而确定出加油站火灾爆炸事故的预防措施,并做出安全检查表,以供现场实施参考。 相似文献
940.