Treatment of Basic Red 29 dye solution using iron-aluminum electrode pairs by electrocoagulation and electro-Fenton methods

The aim of this study is the treatment of Basic Red 29 (BR29) dye solution using hybrid iron-aluminum electrodes by electrocoagulation and electro-Fenton methods. The effect of current density, initial pH, supporting electrolyte, H₂O₂, and initial dye concentration on dye removal efficiency was investigated, and the best experimental conditions were obtained. Time-coarse variation of UV-Vis spectra and toxicity and chemical oxygen demand (COD) removal were also examined at the best experimental conditions. Both systems were found very successful for the removal of BR29 dye. The removal efficiency of >95 % for BR29 dye solution was reached easily in a short time. At the best experimental conditions, for the initial BR29 concentration of 100 mg/L, >95 % BR29 dye and 71.43 % COD removal were obtained after 20 and 40 min of electrolysis, respectively. Additionally, toxicity results for electro-Fenton treatment of 100 mg/L BR29 were also very promising. According to the results obtained, although electro-Fenton is more effective, both systems can be used successfully to treat textile wastewater including dyes.     

Environmental impact of aquaculture-sedimentation and nutrient loadings from shrimp culture of the southeast coastal region of the Bay of Bengal

Nutrient Ioadings were measured for surface seawater and bottom sediments of semi-intensive and improved extensive shrimp culture pond, adjacent estuary, and fallow land in the south-east coastal region of Bangladesh during August, 2000--January, 2001 to evaluate the impact of shrimp culture. The mean levels of nutrients found in the pond surface water were 108.780 mg/L for CaCO3, 0.526 mg/L for NH4^ -N, 3.075 wt% for organic carbon, 7.00 mg/L for PO4-P, 5.57 mg/L for NO3-N, and 7.33 mg/L for chlorophyll-a. The maximum mean value of H2S(0.232 mg/L) was found in estuarine water. Nutrients loading were found to be decreased with distance from the shrimp farm discharge unit in estuarine water. The mean level of organic matter, total nitrogen, and organic carbon were found in higher concentrations in sediments of cultured pond compared to bottom soil of adjacent fallow land at the same elevation. Extractable Ca values were found in higher concentration(550.33 ppt) in adjacent fallow land, as the shrimps for molting in shrimp ponds use extractable Ca. The relation between seawater H2S value and sediment pH ( r= -0.94); sediment organic carbon and sediment pH values ( r= -0.76), sediment total nitrogen and sediment pH ( r = - 0.74) were found to be highly negatively correlated. Whereas the relation between seawater H2S value and sediment total nitrogen ( r= 0.92), water NH4^ -N and sediment pH ( r = 0.66) were found to be positively correlated. The results revealed that load of nutrients at eutrophic level in estuarine water, and decrease of soil pH; leading to acid sulphate soil formation indicates a negative impact of shrimp culture.     

Heavy metal pollution in surface sediment and mussel samples in the Gulf of Gemlik

Different sources of pollution in Karasu Creek were investigated to obtain the water quality and ratio of contamination in this region. To achieve the main objectives of the present study, water samples were collected from Karasu Creek, starting from flow pattern at the upstream site of Akkaya Dam to the end of the dam, crossing the place where the Creek drains into. Dissolved oxygen, electrical conductivity, temperature and maximum/minimum pH were measured systematically for 12 months in the stations, where the water samples were collected. Chemical analyses of the water samples were carried out by using Cadas 50 S brand UV spectrometer to find out the Pb, Fe, Cu, Zn, Ni, Cr, Cd, S, F and Cn concentrations. These concentration were determined in μg/lt as 80–850; 180–4,920; 10–6,100; 440–25,530; 130–2,400; 120–280; 20–150; 214,250–1,113,580; 1,560–4,270 and 40–690, respectively. To determine metal levels of the water samples, multivariate analyses (element coefficient correlation, coefficient correlation dendrogram, hierarchical cluster analysis dendrogram, model summary and ANOVA) were used. The analyses yielded highly accurate results. There were positive correlations between some elements and their possible sources were the same. The stations which resembled each other along the creek were divided into three groups. The water quality of the creek was low and had toxic qualities. Eutrophication developed in Akkaya Dam along the creek. The source of pollution was thought to be industrial and residential wastes. Absolute (0–100 m), short distance (100–500 m) and medium distance (500–2,000 m) conservation areas should be determined in pollution areas along Karasu Creek and they should be improved.     

Determining land use changes by radar-optic fused images and monitoring its environmental impacts in Edremit region of western Turkey

Rapid and unplanned urbanization and industrialization are the main reasons of environmental problems. If urban growth is not based on resource sustainability criteria and urban plans are not applied, natural and human resources are damaged dramatically. In this study, land use change and urban expansion in Edremit region of Turkey is determined by means of remote sensing techniques between 1971 and 2002. To improve the accuracy of land use/cover maps, the contribution of SAR images to optic images in defining land cover types was investigated. To determine the situation of land use/cover types in 2002 accurately, Landsat-5 images and Radarsat-1 images were fused, and the land use/cover types were defined from the fused images. Comparisons with the ground truth reveal that land use maps generated using the fuse technique are improved about 6% with an accuracy of 81.20%. To define land use types and urban expansion, screen digitizing and classification methods were used. The results of the study indicate that the urban areas have been increased 1,826 ha across the agricultural fields which are in land use capability classes of I and II, and significant environmental changes such as land degradation and degeneration of ground water quality occurred.     

Assessment of the Water Quality of Troia for the Multipurpose Usages

The aim of this study was to determine the origin and quality of waters in Troia. For this purpose total of 25 water samples including 2 springs, 14 surfaces and 9 groundwaters, were collected at eight different times. Global positioning system (GPS) was used to determine to coordinates of sampling points. The concentration of 6 minor elements (B, Cu, F, Fe, Pb and Zn), 9 major anions and cations (Na(+), Ca(2+), K(+), Mg(2+), SO(4)(2-), PO(4)(3-), HCO(3)(-), Cl(-) and, CO(3)(2-)) were determined by spectrometric, colorimetric and volumetric methods. Water pH, EC, DO, ORP and TDS were measured in situ using probes. The data showed that the concentrations of most of minor elements were below the EPA and TSE limits except Pb which ranged between 0.001 and 4.832 mg L(-1). Statistically significant relationships (P<0.01 and r>0.70) were observed between Fe and Cu, Cu and K(+), Cu and Ca(2+), B and Na(+), Na(+) and K(+). Assessing the water based on irrigation using Wilcox model showed that some well waters were not suitable for irrigation. Troia water was found to be highly corrosive and the average corrosion coefficients varied from 0.5 to 4.6. According to the Piper and Schoeller diagrams results, the water in Troia was classified as mixed water type.     

ESTIMATING STREAMFLOW AND ASSOCIATED HYDRAULIC GEOMETRY,THE MID‐ATLANTIC REGION,USA1

ABSTRACT: Methods to estimate streamflow and channel hydraulic geometry were developed for unpaged streams in the Mid‐Atlantic Region. Observed mean annual streamflow and associated hydraulic geometry data from 75 gaging stations in the Appalachian Plateau, the Ridge and Valley, and the Piedmont Physiographic Provinces of the Mid‐Atlantic Region were used to develop a set of power functions that relate streamflow to drainage area and hydraulic geometry to streamflow. For all three physiographic provinces, drainage area explained 95 to 98 percent of the variance in mean annual streamflow. Relationships between mean annual streamflow and water surface width and mean flow depth had coefficients of determination that ranged from R²= 0.55 to R²= 0.91, but the coefficient of determination between mean flow velocity and mean annual streamflow was lower (R²= 0.44 to R²= 0.54). The advantages of using the regional regression models to estimate streamflow over a conceptual model or a water balance model are its ease of application and reduced input data needs. The prediction of the regression equations were tested with data collected as part of the U.S. Environmental Protection Agency (USEPA) Environmental Monitoring and Assessment Program (EMAP). In addition, equations to transfer streamflow from gaged to ungaged streams are presented.     

Elemental mercury (Hg0) removal from coal syngas using magnetic tea-biochar: Experimental and theoretical insights

Mercury is ranked 3^rd as a global pollutant because of its long persistence in the environment. Approximately 65% of its anthropogenic emission (Hg⁰) to the atmosphere is from coal-thermal power plants. Thus, the Hg⁰ emission control from coal-thermal power plants is inevitable. Therefore, multiple sorbent materials were synthesized using a one-step pyrolysis method to capture the Hg⁰ from simulated coal syngas. Results showed, the Hg⁰ removal performance of the sorbents increased by the citric acid/ultrasonic application. T5CUF_0.3 demonstrated the highest Hg⁰ capturing performance with an adsorption capacity of 106.81 µg/g within 60 min at 200 °C under complex simulated syngas mixture (20% CO, 20% H₂, 10 ppmV HCl, 6% H₂O, and 400 ppmV H₂S). The Hg⁰ removal mechanism was proposed, revealing that the chemisorption governs the Hg⁰ removal process. Besides, the active Hg⁰ removal performance is attributed to the high dispersion of valence Fe₃O₄ and lattice oxygen (α) contents over the T5CUF_0.3 surface. In addition, the temperature programmed desorption (TPD) and XPS analysis confirmed that H₂S/HCl gases generate active sites over the sorbent surface, facilitating high Hg⁰ adsorption from syngas. This work represented a facile and practical pathway for utilizing cheap and eco-friendly tea waste to control the Hg⁰ emission.