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721.
722.
Su Z. Qi Xiao F. Chen Yong Liu Jia Z. Jiang 《Journal of environmental science and health. Part. B》2013,48(7):456-462
Tebuconazole is a chiral triazole fungicide used as raceme in a variety of agricultural applications. Earlier studies showed that tebuconazole is toxic to many non-target aquatic organisms but relative data for tebuconazole enantiomers are lacking. Thus, goal of this study was to evaluate and compare the toxicity of rac- and S-tebuconazole with Daphnia magna at both acute and chronic levels according to Organization for Economic Cooperation and Development (OECD) guidelines 202 and 211 respectively, to provide some guidelines for optimizing chiral pesticides application and management. The exposure concentrations were 0.1, 0.5, 1, 2, 4, 8, 10 mg L?1 for both rac- and S-tebuconazole and their 48-h EC50 values to D. magna were 3.53 (3.32–3.78) and 2.74 (2.33–3.10) mg L?1 respectively, indicating that these both are medium toxic to D. magna with no significant toxicity difference at acute level. In chronic test, <24-h old D. magna were exposed to 0.01, 0.05, 0.10, 0.20, and 0.40 mg L?1 of rac- and S-tebuconazole with one blank and one solvent control for 21 days according to OECD guideline 211. Four developmental (molting rate, days to the 1st and 3rd brood, and body length) and five reproductive (size of the 1st and 3rd brood, number of broods, and number of neonates) parameters for each D. magna were determined. Results showed that both rac- and S-tebuconazole significantly reduced the reproduction and impacted the development of D. magna at concentrations of 0.05 mg L?1 or higher. Furthermore, S-tebuconazole was more toxic than raceme, and the difference between effects on the same parameters induced by rac- and S-tebuconazole was statistically significant. These results demonstrated that the chronic toxicity of S-tebuconazole might be underestimated in general use, and further studies should focus more on the biological behaviors of enantiomers and not just the raceme of tebuconazole and other chiral pesticides in the environment. 相似文献
723.
Kayleigh Brown Avik J. Ghoshdastidar Jillian Hanmore James Frazee Anthony Z. Tong 《Waste management (New York, N.Y.)》2013,33(11):2188-2194
Compost leachate forms during the composting process of organic material. It is rich in oxidizable organics, ammonia and metals, which pose a risk to the environment if released without proper treatment. An innovative method based on the membrane bioreactor (MBR) technology was developed to treat compost leachate over 39 days. Water quality parameters, such as pH, dissolved oxygen, ammonia, nitrate, nitrite and chemical oxygen demand (COD) were measured daily. Concentrations of caffeine and metals were measured over the course of the experiment using gas chromatography – mass spectrometry (GC/MS) and inductively coupled plasma – mass spectrometry (ICP–MS) respectively. A decrease of more than 99% was achieved for a COD of 116 g/L in the initial leachate. Ammonia was decreased from 2720 mg/L to 0.046 mg/L, while the nitrate concentration in the effluent rose to 710 mg/L. The bacteria in the MBR system adjusted to the presence of the leachate, and increased 4 orders of magnitude. Heavy metals were removed by at least 82.7% except copper. These successful results demonstrated the membrane bioreactor technology is feasible, efficient method for the treatment of compost leachate. 相似文献
724.
S. Ostojić M. Pavlović M. Živić Z. Filipović S. Gorjanović S. Hranisavljević M. Dojčinović 《Environmental Chemistry Letters》2005,3(1):29-32
An investigation carried out in 11 dairies in Serbia has shows that 78.75 % of whey, a by-product of cheese industry, is emitted into river systems, thus contributing to the organic pollution of the environment. This pollution can be avoided by processing of whey into food and pharmaceuticals. It is shown that low-temperature regime of whey concentration and fractionation, based on vacuum concentration and diafiltration, preserves whey proteins undenaturated, as proved by differential scanning calorimetry method. Functional native whey proteins based food products, with potentially high immunomodulatory activity, are obtained. 相似文献
725.
Z. Milán E. Sánchez R. Borja K. Ilangovan A. Pellón N. Rovirosa 《Journal of environmental science and health. Part. B》2013,48(2):305-332
Abstract This study was carried out in a pilot plant for the treatment of anaerobic cattle manure waste. The pilot plant consisted of a semicontinous anaerobic reactor, a settling tank, a filtration process and an ionic exchange column. The study was focused on the filtration process, with natural zeolite as filtering material. In the filtration process different media sizes of natural zeolites packed in columns were tested. The ranges of media size were 0.4 ‐ 1.0, 1.0 ‐ 3.0 and 3.0 ‐ 5.0 mm. Filtration systems operated by gravity flow from 2 to 10 m3m‐2h‐1. The process control was done by assays of solids, turbidity, total and soluble COD, ammonium and orthophosphate. The results showed a better behaviour in the filters packed with a media size range between 1.0 and 3.0 mm, operating at 7 m3m‐2h‐1, principally when effluent gross particles were previously retained in an Heterogeneous Media Filter, operating at 4 m3m‐2h‐1. The head losses diagrams in the filter runs were obtained, at each operational conditions. The hydraulic behaviour of traditional silica sand and natural zeolite beds were compared at the same operational conditions. 相似文献
726.
G.R. Tortella R.A. Mella-Herrera D.Z. Sousa O. Rubilar G. Briceño L. Parra M.C. Diez 《Chemosphere》2013
The impact of repeated carbendazim (CARB) applications on the extent of CARB dissipation, the microbial diversity, the community level physiological profile (CLPP), and the enzymatic activity within the biomixture of an on-farm biopurification system was evaluated. After three successive CARB applications, the CARB dissipation efficiency was high; the efficiency of dissipation was 87%, 94% and 96% after each application, respectively. Although microbial enzymatic activity was affected significantly by CARB application, it could recover after each CARB pulse. Likewise, the numbers of cultivable bacteria, fungi and actinomycetes (as measured in CFUs) were slightly affected by the addition of CARB, but the inhibitory effect of the pesticide application was temporary. Denaturing gradient gel electrophoresis (DGGE) and Biolog Ecoplate assays demonstrated that the microbial populations remained relatively stable over time when compared to the control. The results obtained herein therefore demonstrate the high dissipation capacity of this biomixture and highlight the microbiological robustness of this biological system. 相似文献
727.
728.
729.
The adsorption of a cationic (CTAB, cetyl trimethylammonium bromide) and an anionic surfactant (SLES, sodium dodecylethersulfate)
from aqueous solution onto organic polymer resin (Lewatit VPOC 1064 MD PH) was studied. A series of batch experiments were
performed to determine the sorption isotherms of surfactants to organic polymer resin. The experimental studies were analyzed
by Langmuir and Freundlich isotherms. Furthermore, the isotherm parameters, average percentage errors (ε) of model data, and
separation factor (R
L) were calculated. Other factors influencing the adsorption capacity (contact time, adsorbent amount, and initial surfactant
concentration) were also discussed. The experimental data fitted very well to the Langmuir equilibrium model in the studied
concentration range. The calculated R
L values showed that the adsorption of both surfactants were favorable. Among the surfactants, CTAB showed higher adsorption
capacity onto organic polymer resin compared to SLES (Q
0 = 250 and 34.36 mg g−1, respectively). 相似文献
730.
Elżbieta Zębek 《Russian Journal of Ecology》2013,44(6):492-499
Relationships between abundance of basic net phytoplankton taxonomic groups (cyanobacteria, diatoms, and chlorophytes) and nutrient concentrations in water were studied on the Pas??ka River in years with varied water levels. In high water level conditions, large amounts of orthophosphates and total nitrogen from the catchment could favor development of cyanobacteria and chlorophytes. The species could be allochthonic. At low water levels, the factor stimulating phytoplankton development could be nutrients coming from mineralization of accumulated organic matter. The highest nutrient concentrations could favor diatom development. In such conditions, dominant taxa were autochthonic. In terms of numbers, F. capucina was dominant, and in terms of biomass—genus Spirogyra sp. It could come from plant periphyton inhabiting the concrete drops of the dam included in the river’s development in the vicinity of the hydroelectric power station. 相似文献