全文获取类型
收费全文 | 4505篇 |
免费 | 16篇 |
国内免费 | 138篇 |
专业分类
安全科学 | 115篇 |
废物处理 | 246篇 |
环保管理 | 450篇 |
综合类 | 713篇 |
基础理论 | 1453篇 |
环境理论 | 1篇 |
污染及防治 | 1071篇 |
评价与监测 | 295篇 |
社会与环境 | 303篇 |
灾害及防治 | 12篇 |
出版年
2023年 | 20篇 |
2022年 | 59篇 |
2021年 | 22篇 |
2020年 | 12篇 |
2019年 | 24篇 |
2018年 | 172篇 |
2017年 | 152篇 |
2016年 | 213篇 |
2015年 | 106篇 |
2014年 | 60篇 |
2013年 | 165篇 |
2012年 | 475篇 |
2011年 | 289篇 |
2010年 | 105篇 |
2009年 | 114篇 |
2008年 | 127篇 |
2007年 | 131篇 |
2006年 | 118篇 |
2005年 | 448篇 |
2004年 | 615篇 |
2003年 | 482篇 |
2002年 | 93篇 |
2001年 | 145篇 |
2000年 | 69篇 |
1999年 | 61篇 |
1998年 | 23篇 |
1997年 | 24篇 |
1996年 | 18篇 |
1995年 | 36篇 |
1994年 | 15篇 |
1993年 | 14篇 |
1992年 | 21篇 |
1991年 | 17篇 |
1990年 | 17篇 |
1989年 | 14篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1985年 | 8篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1975年 | 10篇 |
1974年 | 12篇 |
1973年 | 8篇 |
1972年 | 14篇 |
1971年 | 6篇 |
1966年 | 7篇 |
1957年 | 6篇 |
排序方式: 共有4659条查询结果,搜索用时 15 毫秒
151.
152.
Helena M?kinen Kalevi Nieminen Susanna M?ki Sirkku Siiskonen 《International journal of occupational safety and ergonomics》2008,14(1):19-28
High temperature alkaline chemical liquids have caused injuries and hazardous situations in Finnish pulp manufacturing mills. There are no requirements and/or test method standards concerning protection against high temperature alkaline chemical splashes. This paper describes the test method development process to test and identify materials appropriate for hot liquid chemical hazard protection. In the first phase, the liquid was spilled through a stainless steel funnel and the protection performance was evaluated using a polyvinyl chloride (PVC) film under the test material. After several tentative improvements, a graphite crucible was used for heating and spilling the chemical, and a copper-coated K-type thermometer with 4 independent measuring areas was designed to measure the temperature under the material samples. The thermometer was designed to respond quickly so that peak temperatures could be measured. The main problem was to keep the spilled amount of chemical constant, which unfortunately resulted in significant variability in data. 相似文献
153.
L. Bdard-Tremblay L. Fang L. Bauwens Z. Cheng A.V. Tchouvelev 《Journal of Loss Prevention in the Process Industries》2008,21(2):154-161
An accidental hydrogen release within an equipment enclosure may result in the presence of detonable mixture in a confined environment. From a safety standpoint, it is then useful to assess the potential for damage. In that context, numerical simulation of the sequence of events subsequent to detonative ignition provides a useful tool, although with obvious limitations. This article describes the procedure, summarizes two case studies, and reviews the limitations. First, a hydrogen dispersion pattern is obtained from numerical simulation of dispersion, using a commercial package designed primarily for incompressible flow. This dispersion cloud is then used as the initial condition in an inviscid, compressible, reactive flow simulation. To force detonative ignition, a sufficiently large amount of energy is deposited in a small region that corresponds to the ignition location. Chemistry is modeled using a single step Arrhenius model. Because the wave thickness is small compared with the computational domain, a fine mesh is needed, limiting the practicality of the process to two-dimensional geometries. This is the most significant limitation; it is conservative. The two cases described in the paper include an electrolyzer, in which a small release occurs, leading potentially to some damage to the enclosure, and a reformer, in which the consequences are potentially more serious. 相似文献
154.
155.
Yasundo?KurataEmail author Yusaku?Ono Yoshiro?Ono 《Journal of Material Cycles and Waste Management》2008,10(2):144-152
The concentrations of 41 phenols in leachates from 38 municipal solid waste (MSW) landfill sites in Japan were measured. The
main phenols detected in leachates were phenol, three cresols, 4-tert-butylphenol, 4-tertoctylphenol, 4-nonylphenol, bisphenol
A, and some chlorophenols. The concentration levels of phenols were affected by the pH values of the leachates and the different
types of landfill waste. The origins of phenol and p-cresol were considered to be incineration residues, and the major origin of 4-tert-butylphenol, bisphenol A, and 2,4,6-trichlorophenol
was considered to be solidified fly ash. In contrast, the major origins of 4-tert-octylphenol and 4-nonylphenol were considered
to be incombustibles. The discharge of leachates to the environment around MSW landfill sites without water treatment facilities
can cause environmental pollution by phenols. In particular, the disposal of incineration residues including solidified fly
ash and the codisposal of solidified fly ash and incombustibles might raise the possibility of environmental pollution. Moreover,
the discharge of leachates at pH values of 9.8 or more could pollute the water environment with phenol. However, phenol, 4-nonylphenol,
and bisphenol A can be removed to below the con centration levels that impact the environment around landfill sites by a series
of conventional water treatment processes. 相似文献
156.
We presented a model that estimates the bioconcentration factor (BCF) of pesticides in potatoes supposing that the pesticide in the soil solution is absorbed by the potato by passive diffusion, following Fick's second law. The pesticides in the model are nonionic organic substances, traditionally used in potato crops that degrade in the soil according to a first-order kinetic equation. This presents an expression that relates BCF with the pesticide elimination rate by the potato, with the pesticide accumulation rate within the potato, with the rate of growth of the potato and with the pesticide degradation rate in the soil. BCF was estimated supposing steady state equilibrium of the quotient between the pesticide concentration in the potato and the pesticide concentration in the soil solution. It is suggested that a negative correlation exists between the pesticide BCF and the soil sorption partition coefficient. The model was built based on the work of Trapp et al. [Trapp, S., Cammarano, A., Capri, E., Reichenberg, F., Mayer, P., 2007. Diffusion of PAH in potato and carrot slices and application for a potato model. Environ. Sci. Technol. 41 (9), 3103-3108], in which an expression to calculate the diffusivity of persistent organic substances in potatoes is presented. The model consists in adding to the expression of Trapp et al. [Trapp, S., Cammarano, A., Capri, E., Reichenberg, F., Mayer, P., 2007. Diffusion of PAH in potato and carrot slices and application for a potato model. Environ. Sci. Technol. 41 (9), 3103-3108] the hypothesis that the pesticide degrades in the soil. The value of BCF suggests which pesticides should be monitored in potatoes. 相似文献
157.
The impact of motorcycle traffic on soil and vegetation of stabilized coastal dunes, Israel 总被引:1,自引:0,他引:1
This study aimed to assess the response of soil and annual plant vegetation of stabilized coastal dunes in Israel, to varying
intensities of off-road motorcycle (ORM) traffic, and to assess their resistance and resilience to such a disturbance. A standard
experimental procedure that included 0, 20, 50, 100 and 200 ORM straight passes and 150 ORM turn passes was used. Plant ground
cover, mean plant height, species richness, species diversity, soil penetrable depth, organic matter and moisture contents
were measured on several dates within a period of 372 days after the experiment. Results have shown that: (1) ORM passes had
a significant immediate impact on annual plants that increased with traffic intensity. The impact on the soil was detected
only as an increase of penetrable depth. (2) The maximum impact on annual plants was observed in the wheel ruts and turn areas.
The impact on the area between the wheel ruts and on the margins outside the wheel ruts was indirect and smaller. (3) Annual
plant ground cover and mean plant height were less sensitive parameters than species richness and species diversity for determining
the impact of ORM traffic on the area. (4) One year after the experiment, soil and annual plant vegetation in all passes were
very similar to their pre-experimental condition. This indicates high resilience and recovery potential of the Mediterranean
stabilized coastal dune ecosystem to ORM disturbance. 相似文献
158.
Xiaoqing?DongEmail author Chaolin?Li Binbin?Ding Xiaofeng?He Jia?Zhu Peibing?Shao 《Environmental Modeling and Assessment》2016,21(4):517-529
Frequent monitoring and relatively high fines are usually necessary to bring about improvements in environmental quality, but more challenging for many countries with limited human, material, and financial resources is to put them into practice. This paper developed a three-group model of a state-dependent enforcement in a repeated game to improve the policy implementation under limited inspection capacities. A certain number of firms are grouped (group 1, group 2, group 3) for different supervision intensity (e.g., the order of inspection probability corresponding to each group is p 1?<?p 2?<?p 3) based on their environmental performance. The optimal policy parameters, such as inspection probability of each group and the probability that a firm found in compliance is moved to a better reputation group, were obtained as the basis for regulator’s policy making. Numerical simulations indicated that the three-group inspection regime can significantly increase compliance rate as compared with static enforcement with the same monitoring probability. Among the number of firms in each group under steady state conditions, group 2 had the most, group 1 was the second, and group 3 had the smallest. Analysis and prediction of a three-group reputation example provided a good experiment for the model. The results give a practical reference for the policy makers with inspection capacity constraints to achieve higher compliance rate. 相似文献
159.
H. W. Zhang Y. Q. Sun Y. Li X. D. Zhou X. Z. Tang P. Yi A. Murad S. Hussein D. Alshamsi A. Aldahan Z. B. Yu X. G. Chen V. d. P. MUGWANEZA 《Environmental monitoring and assessment》2017,189(8):411
Assessment of groundwater quality plays a significant role in the utilization of the scarce water resources globally and especially in arid regions. The increasing abstraction together with man-made contamination and seawater intrusion have strongly affected groundwater quality in the Arabia Peninsula, exemplified by the investigation given here from the United Arab Emirates, where the groundwater is seldom reviewed and assessed. In the aim of assessing current groundwater quality, we here present a comparison of chemical data linked to aquifers types. The results reveal that most of the investigated groundwater is not suitable for drinking, household, and agricultural purposes following the WHO permissible limits. Aquifer composition and climate have vital control on the water quality, with the carbonate aquifers contain the least potable water compared to the ophiolites and Quaternary clastics. Seawater intrusion along coastal regions has deteriorated the water quality and the phenomenon may become more intensive with future warming climate and rising sea level. 相似文献
160.
Muhammad?Shafiq Tahira?Shaukat Aisha?Nazir Firdaus-e-?BareenEmail author 《Environmental monitoring and assessment》2017,189(8):423
Kasur is one of the hubs of leather industry in the Punjab, Pakistan, where chrome tanning method of leather processing is extensively being used. Chromium (Cr) accumulation levels in the irrigation water, soil, and seasonal vegetables were studied in three villages located in the vicinity of wastewater treatment plant and solid waste dumping site operated by the Kasur Tanneries Waste Management Agency (KTWMA). The data was interpreted using analysis of variance (ANOVA), clustering analysis (CA), and principal component analysis (PCA). Interpolated surface maps for Cr were generated using the actual data obtained for the 30 sampling sites in each of the three villages for irrigation water, soil, and seasonal vegetables. The level of contamination in the three villages was directly proportional to their distance from KTWMA wastewater treatment plant and the direction of water runoff. The highest level of Cr contamination in soil (mg kg?1) was observed at Faqeeria Wala (37.67), intermediate at Dollay Wala (30.33), and the least in Maan (25.16). A gradational variation in Cr accumulation was observed in the three villages from contaminated wastewater having the least contamination level (2.02–4.40 mg L?1), to soil (25.16–37.67 mg kg?1), and ultimately in the seasonal vegetable crops (156.67–248.33 mg kg?1) cultivated in the region, having the highest level of Cr contamination above the permissible limit. The model used not only predicted the current situation of Cr contamination in the three villages but also indicated the trend of magnification of Cr contamination from irrigation water to soil and to the base of the food chain. Among the multiple causes of Cr contamination of vegetables, soil irrigation with contaminated groundwater was observed to be the dominant one. 相似文献