Removal efficiencies of PCDDs/PCDFs by air pollution control devices in municipal solid waste incinerators

Removal efficiencies of polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDDs/PCDFs) by air pollution control devices (APCDs) in the commercial-scale municipal solid waste (MSW) incinerators with a capacity of above 200 ton/day were evaluated. The removal efficiencies of PCDDs/PCDFs were up to 95% when the activated carbon (AC) was injected in front of electrostatic precipitator (EP). Spray dryer absorber/bag filter (SDA/BF) had high removal efficiency (99%)) of PCDDs/PCDFs when a mixture of lime and AC was sprayed into the SDA. When the AC was not added in scrubbing solution, the whole congeners of PCDDs/PCDFs were enriched in the wet scrubber (WS) with negative removal efficiencies of -25% to -5731%. Discharge of PCDDs/PCDFs was decreased with increasing the proportions of AC added in scrubbing solution. Selective catalytic reduction (SCR) system had the removal efficiencies of up to 93% during the test operation.     

淮北桃园煤矿北八采区煤系砂岩水水化学特征及其水源判别

桃园煤矿北八采区在开拓掘进过程中煤系砂岩多处出现涌水现象,且涌水量大、水温高、水质异常。为了判断北八采区砂岩水的水源,对矿井各含水层及北八采区砂岩水进行了系统采样,并对常规水化学指标进行了测试和分析。结果表明:北八采区煤系砂岩水与井田南部采区砂岩水水化学指标存在较大差异,而与奥灰水的水化学指标基本一致,该区"砂岩水"已不具有正常砂岩裂隙水的水质特征,具有奥灰水的水质特征,接受奥灰含水层水的补给。研究成果为该区"砂岩水"的防治提出了可靠的地质依据。     

机动车尾气污染与防治措施研究

改善空气质量,减少机动车尾气对雾霾的贡献已是当务之急.防治机动车尾气污染,关键是国家应制定和完善相应的法律、法规、规章和标准,出台鼓励新能源机动车的研发、生产、销售的优惠政策.环保部门要把住机动车环保检测第一关,严格机动车环保绿色标志的发放,会同工商部门对油品实行日常监管,加强环保宣传、提高人们的环保意识.公安、环保联动执法,杜绝超标车上路,淘汰黄标车.政府相关部门要科学规划和绿化城市道路.     

五氟苄基羟胺衍生与GC/MS联用分析大气中的单羰基化合物和多羰基化合物

利用涂布五氟苄基羟胺（PFBHA）的Tenax-TA作为固体吸附剂,采取主动采样的方式采集大气中羰基化合物,再经溶剂洗脱和氮吹浓缩后用气相色谱/质谱（GC/MS）分析,成功检测到14种单羰基化合物和2种二羰基化合物（乙二醛与甲基乙二醛）.研究表明：在吸附剂的装载量为50mg的前提下,当衍生剂的涂布量为260nmol,采集流速为50mL·min^-1时,采集效果最佳.羰基化合物的检测限、平行样的相对标准偏差和样品的加标回收率范围分别为0.54～3.83ng·m^-3、1.0%～14.2%、89.2%～113.8%.该方法在实际大气样品中合适的采样时间为0.5～8.0h.利用此法对上海市宝山区大气中羰基化合物进行了检测,成功检测到16种羰基化合物,且具有明显的日变化趋势.     

石化行业控制室承爆风险评估方法研究

针对传统的气体爆炸风险评估方法的不足之处,提出采用一种基于CFD技术的气体爆炸风险评估方法,对某煤气化厂区氢气爆炸对控制室造成的风险进行模拟计算与预测分析。并把研究结果与传统的TNT当量法、Multi-Energy方法预测结果进行比较。结果表明,该方法能考虑到密集管道与复杂装置布局、气云大小等因素对爆炸超压的影响,且能用于超压波的近场预测,以及确定空间不同位置处的爆炸超压,更适用于石化行业控制室的承爆风险评估。     

Survey of composition and generation rate of household wastes in Beijing, China

It is recognized that information on both quantity and composition of residential waste is important for the effective planning of household waste handling infrastructure. In this paper, we present the results of a survey on household waste generation and composition in Beijing, China. Sample communities were selected by the integration of five indices including family population, income, age, and education. Wastes were sampled on a daily basis from 113 households in six different districts of Beijing City for ten days. The results showed that the generation rate of household wastes was 0.23 kg/pers/day. The bulk density was approximately 221 kg/m³, and the moisture content was approximately 50%. Household waste consisted of kitchen waste, paper/cardboard, plastics, textiles, metals, glass and other wastes, the proportion of each waste was approximately 69.3%, 10.3%, 9.8%, 1.3%, 0.8%, 0.6% and 2.7%, respectively. An evaluation of the relationship between daily per capita generation of household waste and socio-economic factors indicated that household size and income both showed a negative relationship with household waste generation (kg/pers/day). As for the effect of education, families with a secondary educational level produced fewer household wastes (kg/pers/day) than those with a primary or advanced educational level.     

合成有机化学品的超临界水氧化

研究了超临界水氧化系统中合成有机化学品 ,如酚、间苯三酚、对叔丁基酚、间甲酚、3 ,5-二甲酚、苯胺、硝基苯、叔丁醇、三氯乙醛等的氧化作用。在实验条件下 ,上述化学品均能显著降解。酚和苯胺的去除随氧化剂过氧化氢加入量增加而增加。较优的K值 (实验中加入的H2 O2 量与按反应方程化学计量的量的比值 )对酚和苯胺分别为 1 .5和 1 .1。实验结果显示 ,当系统的压力为 3 0MPa ,温度为 4 50℃ ,停留时间为 1 90s,K =2 .0 (对酚 )和系统压力为 2 5MPa,温度为 50 0℃ ,停留时间为 3 0s,K =1 .2 (对苯胺 ) ,氧化效率都接近 1 0 0 %。含酚废水处理结果表明温度、压力、停留时间 3种因素中 ,温度是主要影响因素     

预算软约束下外部融资需求对企业社会责任披露的影响

加强社会责任信息的履行和披露是企业获得社会责任信誉,进而获取资源的重要途径.本文从资源性动机出发,以2009年制造业上市公司为样本,分析了在预算软约束下,我国上市公司外部融资需求与社会责任披露之间的关系,通过研究发现:我国制造业上市公司外部融资需求越高,其披露的社会责任信息质量越好;当我国制造业上市公司有外部融资需求时,更关注社会责任信息披露的整体性质量和内容性质量;另外,我国制造业上市公司披露社会责任的动机更多是为了解决内部融资的不足,其次是长期外部融资,而较少考虑到企业的可持续发展;但是并没有发现在预算软约束环境下,非国有企业披露社会责任信息的资源性动机比国有企业强.因此,要提高企业社会责任履行和披露的数量和质量,可以将企业的融资行为与企业的社会责任挂钩,这种挂钩形式不仅能够引导投资者把资金投入到可持续发展的企业,而且也可以激励企业对社会责任的履行和披露.     

城市污泥中重金属去除研究进展

由于城市污水处理厂中产生的剩余污泥中含有各种重金属,导致大量的营养丰富的污泥堆积如山,无法利用。为了能够实现剩余污泥的资源化,在此主要介绍了如何去除剩余污泥中的重金属,从而简单论述了各种比较有效的方法。