Polycyclic aromatic hydrocarbons and trace metals in mosque’s carpet dust of Riyadh,Saudi Arabia,and their health risk implications

The main objectives of this work were to identify and determine the concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace metals in carpet dust samples from various mosques of the city of Riyadh and to assess the health risks associated with the exposure to these pollutants. Therefore, 31 samples of mosque’s carpet dust from Riyadh were collected. The results showed that 14 PAHs were present in the dust samples with concentrations ranged from 90 to 22,146 ng g^?1 (mean = 4096 ± 4277 ng g^?1) where low molecular weight compounds were dominant. The presence of PAHs were in the order of naphthalene > chrysene and benzo(b)fluoranthene > benzo(a)pyrene > acenaphthene and benzo(k)fluoranthene > pyrene and the absence of indeno(1,2,3-cd)pyrene and dibenz(a,h)anthracene. The diagnostic ratio coupled with principle component analysis (PCA) revealed mix sources of petrogenic from traffic, stack emission, and pyrogenic inputs from essence and perfumed wood burning. Trace metals were significant in the dust samples, and their concentrations decrease in the order of Zn, Mn, Cu, Cr, Pb, Ni, and V where Zn being the highest (94.4 ± 91.5 μg g^?1) and indium was the lowest (1.9 ± 9.3 μg g^?1). The trace metals were major in southern and central parts of Riyadh and followed the order of central Riyadh > southern Riyadh > western Riyadh > eastern Riyadh > northern Riyadh. Estimated risk based on the total PAHs was found to be 4.30 × 10^?11 for adult and 1.56 × 10^?11 for children. Elemental non-cancer risk for adults ranged from 7.9 × 10^?4 for Co to 7.58 × 10^?1 for Li and for children ranged from 3.70 × 10^?3 for Co to 3.54 for Li. Policy implication and mitigations of PAHs in Riyadh and Saudi Arabia were highlighted.     

Evaluation of cleaning and disinfection protocols for commercial farm equipment following a foreign animal disease outbreak

This study evaluated the microbiocidal efficacy of a cleaning and disinfection (C&D) treatment using stainless-steel coupons applied to three common types of animal mortality transport vehicles when exposed to agricultural conditions. Metal test coupons, inoculated with bacteriophage MS2, were affixed to the undercarriage of three types of animal mortality transport vehicles at various locations. Coupons were grimed by maneuvering the test vehicles down a series of wet dirt roads. Coupons were attached and extracted at various points to evaluate C&D performance with and without grime. C&D efficacy using a water-supplied pressure washing system and a dilute sodium hypochlorite (NaOCl) solution was determined by comparing the difference in recovered viable virus between positive control coupons and test coupons. The results demonstrated a relatively high surface decontamination efficacy, with all but one location showing >5 log reduction of MS2. Coupons located on the roll-off truck's inside-back bumper contained the highest level of grime and resulted in a 4 log reduction of MS2. There was no significant difference in C&D efficacy across vehicle types, but locations impacted by grime and lack of accessibility achieved lower efficacies on average. These findings suggest that common C&D protocols, when applied to farm mortality transport vehicles, are effective. Hard-to-access locations containing high levels of grime may be candidates for additional targeted treatment.     

Polyphenolic extracts from the xerophyte Rhamnus lycioides as a radiation biodosimeter

The majority of dosimeters currently in use are synthetic and very expensive. Therefore, the study of the dosimetric characteristics of polyphenolic extracts of xerophytes is useful because drought stress causes an increase in the production of these cheap and natural compounds containing benzene rings. Here, the polyphenolic compounds were extracted from Rhamnus lycioides which was collected from Bou-Hedma National Park in Tunisia and identified using liquid chromatography-mass spectrometry (LC-MS). We investigated the impact of cobalt-60 (60Co) irradiation (0–30 kilogray (kGy)) on the color parameters of polyphenolic extracts of R. lycioides using the Konica Minolta CR 300 portable colorimeter and UV–Visible spectroscopy. The structural and morphological characteristics of the irradiated extracts were assessed using Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) technique and scanning electron microscopy (SEM). Overall, our results suggest that exposure to ionizing radiation (IR) of the polyphenolic components of the xerophyte R. lycioides has produced significant dose-dependent changes in their optical and morphological properties. Thus, these extracts can be valorized as biodosimeters in the dose range from 5 to 25 kGy.     

Magnetic nanoparticles incorporation into different substrates for dyes and heavy metals removal—A Review

Environmental Science and Pollution Research - Substantial discharge of hazardous substances, especially dyes and heavy metal ions to the environment, has become a global concern due to...     

Value addition in the services sector and its heterogeneous impacts on CO2 emissions: revisiting the EKC hypothesis for the OPEC using panel spatial estimation techniques

Environmental Science and Pollution Research - This study examines the Environmental Kuznets Curve (EKC) hypothesis in the context of 12 members of the OPEC by utilizing data on both the aggregate...     

Job satisfaction among physicians in secondary and tertiary medical care levels

Environmental Science and Pollution Research - To identify level of job satisfaction among physicians at secondary and tertiary care levels. Random sample of 450 secondary and 523 tertiary care...     

The distribution and composition of hydrocarbons in sediments from the Fladen Ground, North Sea, an area of oil production

The distribution and composition of hydrocarbons in sediment from the Fladen Ground oilfield in the northern North Sea have been investigated. The total PAH concentrations (2- to 6-ring parent and alkylated PAHs, including the 16 US EPA PAHs) in sediments were relatively low (<100 microg kg(-1) dry weight). The PAH, the Forties crude and diesel oil equivalent concentrations were generally higher in sediment of fine grain size and higher organic carbon concentration. PAH distributions and concentration ratios indicated a predominantly pyrolytic input, being dominated by the heavier, more persistent, 5- and 6-ring compounds, and with a high proportion of parent PAHs. The n-alkane profiles of a number of the sediments contained small, high boiling point, UCMs, indicative of weathered oil arising from a limited petrogenic input. The geochemical biomarker profiles of the sediments that contained UCMs showed a small bisnorhopane peak and a high proportion of norhopane relative to hopane, indicating that there was contamination from both Middle Eastern and North Sea oils. Therefore contamination was not directly as a result of oil exploration activity in the area. The most likely source of petrogenic contamination was from general shipping activity.     

Assessment of noise level and noise propagation generated by light-lift helicopters in mountain natural environments

The use of helicopter rises discussion about environmental noise propagation especially when it operates in proximity of environmentally sensitive areas (ESAs) for an extended period because of its potential implications in wildlife behaviours. In order to support decisions on helicopter logging operation management in proximity of ESAs, this study focused on (i) analysing the noise spectrum of a light-lift helicopter during logging operations and on (ii) assessing the noise propagation in the surrounding environments. This study investigated a helicopter logging operation for wood fuel extraction in the eastern part of the Italian Alps. The potential disturbance area covered for the entire helicopter logging operation was evaluated by a specific GIS application according to hearing sensitivity of the most sensitive wildlife species in the study area (different strigiform species). The noise level at the ground appeared to be affected by the location regardless both the use of equivalent continuous sound pressures level dB(A) (LAeq) and the single-event level (SEL) noise metrics. The lowest values were recorded when the helicopter was flown over the sound meter level located under the forest canopy, while the highest was recorded when the helicopter was unhooking the loads at the landing. The GIS application highlighted the consistent of the exceeded noise area (weighted to strigiform hearing range and sensitivity) for the lower frequency bands (0.016–0.250 kHz). A more restricted exceeded noise area concerned instead the most sensitive frequency bands" for the strigiform (1–2 kHz).

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Heavy metal concentrations in roadside soil and street dust from Petra region,Jordan

Concentrations of Cd, Cu, Fe, Pb, and Zn were measured in the samples of street dust and surface roadside soil before Jordan switched to unleaded fuel usage. The samples were collected from Petra, the most tourist-attractive site in Jordan. The samples were analyzed for heavy metals by atomic absorption spectrophotometry. Our results show that the distribution of metals in the soil samples is affected by wind direction in the investigated area. The highest level of metals was found in the eastern parts of the roads due to the westerly-dominant wind in the studied area. The contamination levels of metals decrease as the distance from the edge of the road increases. In the roadside soil samples, the means for the concentrations of the metals at 1 m from the east side of the main road are 1.0, 19.1, 3791.4, 177.0, and 129.0 mg kg^?1 for Cd, Cu, Fe, Pb, and Zn, respectively. In the samples of street dust, the means of the concentrations of the metals in the investigated area are 9.7, 11.8, 4694.4, 31.6, and 24.8 mg kg^?1 for Cd, Cu, Fe, Pb, and Zn, respectively. In conclusion, the lithogenic origins (traffic emissions) are responsible for the diffusion of these metals in the studied region.