Fast and reversible adsorption for dibenzothiophene in fuel oils with metallic nano-copper supported on mesoporous silica

Environmental Science and Pollution Research - Dibenzothiophene (DBT) in fuel oils causes the release of toxic sulfur oxide gases, and it is necessary to remove DBT in fuels. Herein, metallic...     

Distribution and seasonal variation of estrogenic endocrine disrupting compounds, N-nitrosodimethylamine, and N-nitrosodimethylamine formation potential in the Huangpu River, China

Detection of estrogenic endocrine disrupting compounds(EDCs) and N-nitrosodimethylamine(NDMA) in drinking water has led to rising concerns. There are, however, a paucity of studies on the distribution and seasonal variation of NDMA and NDMA formation potential(NDMA-FP) in natural waters, especially in China. For EDCs, limited studies have investigated the distribution and seasonal variation of estrone(E1), 17β-estradiol(E2), estriol(E3), 17α-ethinylestradiol(EE2), technical-nonylphenols(t-NP), and bisphenol A(BPA) in Shanghai. In this study, water samples were collected from 11 sampling sites along the Huangpu River in 2012. The distribution and seasonal variation of EDCs, NDMA, and NDMA-FP were investigated. The results showed that all of the 11 sampling sites were contaminated by the target compounds. Compared with E2 and EE2, higher E1 and E3 concentrations were usually detected in the Huangpu River. The values of 17β-estradiol equivalents(EEQ) suggest a high possibility of endocrine effects on exposed organisms in the Huangpu River. NDMA-FP and t-NP were the dominant contaminants among the eight target compounds. The detection rates of the target compounds and their concentrations were both higher in dry seasons than in wet seasons. Higher concentrations of target compounds were observed in urban sampling sites near drainage outlets, and also in suburban sampling sites where intensive livestock farming and farmlands were located.     

有机无机肥长期配施对果园土壤碳库及温室气体排放的影响

有机肥的施用可以提高土壤总有机碳和活性有机碳含量,在改善土壤质量,提升土壤肥力方面有重要意义.设4个处理：不施肥（CK）、单施有机肥（M）、单施化肥（NPK）和有机无机肥配施（MNPK）,研究长期有机无机配施下土壤有机碳和其活性组分含量变化,分析不同施肥措施对温室气体排放的影响,并评估了土壤碳库管理指数的变化.结果表明,与CK处理相比,MNPK处理的土壤总有机碳（TOC）、微生物量碳（MBC）、可溶性有机碳（DOC）、易氧化有机碳（EOC）和颗粒有机碳（POC）含量分别增加了82.84%、66.30%、21.12%、93.28%和145.80%.NPK处理对土壤总有机碳和有机碳组分含量无显著差异.有机无机配施有利于提高土壤碳库活度指数（LI）、土壤碳库指数（CPI）和土壤碳库管理指数（CPMI）,LI和CPI的增加是CPMI增加的主要原因.相关分析表明土壤有机碳组分和CPMI与温室气体排放呈显著正相关关系;有机无机配施增加了CO₂累积排放量和增温潜势（GWP）,但却能够降低温室气体排放强度（GHGI）;MNPK处理产量最高,为56365 kg ·hm^-2,较CK处理（29073 kg ·hm^-2）提高了93.87%.因此,旱地苹果园有机无机肥配施,可促进有机碳的累积,稳定土壤碳库,更有利于果园的可持续发展.     

苦草对不同浓度氮净化效果及其形态转化规律

为研究不同营养程度下水生植物对污染物的净化效果,选择长江中下游河流和湖泊水体中典型沉水植物苦草作为研究对象,在2006-09-07～2006-09-22期间开展了7种氮浓度条件下,苦草对水体氮的净化效应及氮在植物体内累积分布规律研究,并分析了水体中氮形态的转化特征.结果表明,试验期内苦草在氮浓度低于60.0 mg/L范围内表现为对水体中氮较强的净化作用,且对总氮的净化效果具有相似的规律性.但是当水体氮浓度大于80.0 mg/L时,苦草对水体氮净化的贡献无明显的规律性.氮在植物体内的累积与水体中氮浓度相关,但其在地下部和地上部的分配规律与浓度的差异无关.水体中氮的形态转换与总氮浓度相关,水中氮浓度低于20.0 mg/L时,氨氮浓度迅速降低,但随着氮浓度的增加,氨氮所占比例明显增大,表明苦草对不同氮浓度条件氮净化具有明显的差异和影响.     

Carbon dioxide electroreduction into formic acid and ethylene: a review

Environmental Chemistry Letters - Climate change damage induced by growing carbon dioxide (CO2) emissions has rapidly fostered research on capturing, utilizing, and converting CO2 into valuable C1...     

河西走廊绿洲城市化及可持续对策

本文分析了河西走廊绿州城市化现状 ,认为经济基础薄弱、产业结构不合理、水资源匮乏、生态环境脆弱是河西走廊绿洲城市化的主要限制因素 ,指出河西绿洲加速城市化应加大产业结构调整力度 ,系统规划城市建设 ,加强水资源统一管理和节水建设 ,大力发展教育事业和提高农业产业化水平     

The preparation and evaluation mechanism of mesoporous spherical silica/porous carbon-filled polypropylene composites obtained from coal gasification fine slag

Environmental Science and Pollution Research - Coal gasification fine slag is a by-product of the entrained-flow gasifier, which has caused some environmental pollution. Through acid dissolution...     

Development of Mg/La-layered double hydroxide nanocomposites and application of recovered phosphorus from modelled biogas slurry

Journal of Material Cycles and Waste Management - Presently, a large amount of agriculture-produced sewage generally contains excessive phosphorus discharge and water eutrophication. However, it is...