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31.
Bioaccumulation models take various elimination and uptake processes into account, estimating rates from chemical lipophilicity, expressed as the octanol-water partition ratio (Kow). Here, we focussed on metabolism, which transforms parent compounds into usually more polar metabolites, thus enhancing elimination. The aim of this study was to quantify the change in lipophilicity of relevant organic pollutants undergoing various biotransformation reactions in mammals. We considered oxidation reactions catalyzed by three enzyme groups: cytochrome P450 (CYP), alcohol dehydrogenase (ADH), and aldehyde dehydrogenase (ALDH). Estimated log Kow values of a selected dataset of parent compounds were compared with the log Kow of their first metabolites. The log Kow decreased by a factor that varies between 0 and −2, depending on the metabolic pathway. For reactions mediated by CYP, the decrease in Kow was one order of magnitude for hydroxylated and epoxidated compounds and two orders of magnitude for dihydroxylated and sulphoxidated xenobiotics. On the other hand, no significant change in lipophilicity was observed for compounds N-hydroxylated by CYP and for alcohols and aldehydes metabolized by ADH and ALDH. These trends could be anticipated by the calculus method of log Kow. Yet, they were validated using experimental log Kow values, when available. These relationships estimate the extent to which the elimination of pollutants is increased by biotransformation. Thus, the quantification of the Kow reduction can be considered as a first necessary step in an alternative approach to anticipate biotransformation rates, which are hard to estimate with existing methods. 相似文献
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de Zorzi P Barbizzi S Belli M Barbina M Fajgelj A Jacimovic R Jeran Z Menegon S Pati A Petruzzelli G Sansone U Van der Perk M 《Chemosphere》2008,70(5):745-752
In the frame of the international SOILSAMP project, funded and coordinated by the National Environmental Protection Agency of Italy (APAT), uncertainties due to field soil sampling were assessed. Three different sampling devices were applied in an agricultural area using the same sampling protocol. Cr, Sc and Zn mass fractions in the collected soil samples were measured by k(0)-instrumental neutron activation analysis (k(0)-INAA). For each element-device combination the experimental variograms were calculated using geostatistical tools. The variogram parameters were used to estimate the standard uncertainty arising from sampling. The sampling component represents the dominant contribution of the measurement uncertainty with a sampling uncertainty to measurement uncertainty ratio ranging between 0.6 and 0.9. The approach based on the use of variogram parameters leads to uncertainty values of the sampling component in agreement with those estimated by replicate sampling approach. 相似文献
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The spatial and temporal variability of transparency measured for 15 years at 7 stations near the San Diego sewage outfall has been investigated and compared to the temporal variability of sewage suspended solid discharge and flow rate. the purpose of the time-series analyses was to distinguish natural from human (sewage discharge) causes of temporal changes in transparency. the results show that: 1) variations in transparency are highly correlated over the entire area, but there is a gradient in means and variability in the direction perpendicular to the coast; 2) there are no long term trends for increase or decrease in the water clarity at any of the stations; 3) most of the variance of transparency is contained in the seasonal frequency band; 4) over the same time period sewage discharge has significantly increased and suspended solids decreased; 5) most of the variance of these human-caused properties is in the interannual frequency band; (6) there is no correlation at any time-lag between water clarity and suspended solid discharge or flow. These results lead to the conclusion that these anthropogenic properties are not affecting transparency, while natural factors such as seasonality and distance from coast do. 相似文献
34.
Kinetic and chemical assessment of the UV/H2O2 treatment of antiepileptic drug carbamazepine 总被引:1,自引:0,他引:1
The UV/H2O2-induced degradation of carbamazepine, a worldwide used antiepileptic drug, recently found as contaminant in many municipal sewage treatment plant (STP) effluents and other aquatic environments, is investigated. The oxidation treatment caused an effective removal of the drug. At complete abatement of the substrate after 4 min treatment, a 35% value of removed total organic carbon (TOC) was obtained. A kinetic constant of (2.05+/-0.14) x 10(9) lmol(-1)s(-1) was determined for OH radical attack to carbamazepine in the UV/H2O2 process. Preparative TLC of the reaction mixture led to the isolation of acridine-9-carboxaldehyde as a reaction intermediate. HPLC and GC/MS analysis indicated formation of small amounts of acridine, salicylic acid, catechol and anthranilic acid among the reaction products. Under the same reaction conditions, synthetically prepared 10,11-epoxycarbamazepine was easily degraded to acridine as main product, suggesting that this epoxide is a likely intermediate in the oxidative conversion of carbamazepine to acridine. Under sunlight irradiation, carbamazepine in water underwent slow degradation to afford likewise acridine as main product. In view of the mutagenic properties of acridine, these results would raise important issues concerning the possible environmental impact of carbamazepine release through domestic wastewaters and support the importance of prolonged oxidation treatments to ensure complete degradation of aromatic intermediates. 相似文献
35.
Cinzia Zoppini Angelo Vanzulli Alessandra Kustermann Tommaso Rizzuti Angelo Selicorni Umberto Nicolini 《黑龙江环境通报》1993,13(10):995-999
Omphalopagus conjoined twins were diagnosed by ultrasonography in a pregnant woman at 21 weeks' gestation. In order to clarify the anatomical connections, magnetic resonance imaging (MRI) was performed, having achieved fetal paralysis by intravascular injection of 100 mg of pancuronium into each twin. Prior to MRI, 2 ml of a 0.0001 mmol/ml solution of gadolinium DTPA was also injected into the stomach of one twin. The contrast agent opacified the bowel loops of both twins, indicating bowel to bowel anastomosis. Following pregnancy termination, autopsy confirmed the prenatal diagnosis. 相似文献
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Beatrice Oneda Rosa Baldinger Regina Reissmann Irina Reshetnikova Pavel Krejci Rahim Masood Nicole Ochsenbein-Kölble Deborah Bartholdi Katharina Steindl Denise Morotti Marzia Faranda Alessandra Baumer Reza Asadollahi Pascal Joset Dunja Niedrist Christian Breymann Gundula Hebisch Margaret Hüsler René Mueller Elke Prentl Josef Wisser Roland Zimmermann Anita Rauch 《黑龙江环境通报》2014,34(6):525-533
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Alessandra Schiavone Kurunthachalam Kannan Silvano Focardi 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):599-606
Prior to this study, reports of occurrence of polycyclic musks and polychlorinated naphthalenes (PCNs) in human tissues from Italy were not available. In this study, concentrations of PCNs and polycyclic musks were determined in human adipose tissue from Italy collected during 2005-2006; for comparison, legacy organohalogen pollutants such as organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were determined. ΣPCN concentrations ranged from 0.5 to 14 ng/g lipid wt (lw). Polycyclic musks such as HHCB and AHTN were found in 92% and 83% of the human samples, respectively. Concentrations of PBDEs in Italian adipose tissue ranged between 3.2 and 35.6 ng/g lw. 相似文献