Sulfur trioxide formation during oxy-coal combustion

The purpose of this study was to investigate the effects of increased oxygen and carbon dioxide concentration on the formation of sulfur trioxide during oxy-coal combustion in two different types of pilot-scale furnaces: a pulverized-coal and a circulating-fluidized-bed-fired system.For pulverized-coal (PC) testing, concentrations of SO₃ and SO₂ were significantly higher for oxy-fired conditions as compared to air-fired conditions. For a high-sulfur Illinois bituminous coal, SO₃ concentrations were 4–6 times greater on average. When firing a low-sulfur Utah Bituminous coal, SO₃ concentrations were similar for oxy-firing vs. air-firing, and the overall levels were very low compared to the Illinois coal, consistent with differences in the fuel sulfur contents. PC-fired emissions on a normalized mass basis (mass SO₃ per unit energy input) indicated higher SO₃ emissions under air-fired conditions vs. oxy-firing, for both the Illinois and Utah coals.Circulating fluidized bed testing was also carried out using the low-sulfur Utah coal, and SO₃ concentrations were notably higher for oxy-firing vs. air-firing, in contrast to the similar concentration levels observed for PC-firing. When compared on a normalized mass basis, the emissions were similar for both air- and oxy-firing, which is also in contrast to the PC-fired results for this coal.     

From union to union: forest governance in a post-soviet political system

This paper explores policy choices made in the governance of forest resources in Lithuania during the period of 1990–2005. The present system of governance of forest resources in Lithuania is compared with a theoretical framework for good governance. In addition, the reforms in the governance model in Lithuania are placed in the context of forest governance in other countries of the region.The results of the study indicate that Lithuanian forestry has evolved from hierarchical and extreme state interventionist governance to relatively transparent and accountable governance that respects private ownership, is sensitive to the public needs and interests as well as demand and supply in the market. The results of our work have indicated that the privatization has served as the main impetus for change.On a larger scale, the reforms of the forest sector in the three Baltic States seem to have progressed in a more similar manner than compared to those in Poland, Russia, and Ukraine.     

Evaluation of the physical stability,groundwater seepage control,and faunal changes associated with an AquaBlok® sediment cap

Active sediment caps are being considered for addressing contaminated sediment areas in surface‐water bodies. A demonstration of an active cap designed to reduce advective transport of contaminants using AquaBlok® (active cap material) was initiated in a small study area of the Anacostia River in Washington, D.C. The cap remained physically stable, demonstrated the ability to divert groundwater flow, and was recolonized with native organisms after 30 months of monitoring following cap placement. However, the long‐term performance of active caps associated with harsh environmental conditions, hydrogeological settings, and subsurface gas production needs to be further evaluated. © 2008 Wiley Periodicals, Inc.     

Mass exchange in a shallow channel flow with a series of groynes: LES study and comparison with laboratory and field experiments

The exchange of dissolved matter between a straight open channel and a series of shallow embayments present at one of its sides is investigated using large eddy simulation (LES). The direct link between the mechanism of mass exchange and the dynamics of coherent structures is demonstrated. It is shown that for the geometrical configuration considered in the present study, the mass exchange process is very non-uniform over the depth in the vicinity of the channel–embayment interface. Most of the contaminant is ejected from the embayments close to the free surface. The amount of contaminant re-entrained into the embayments situated downstream of the one in which contaminant was introduced is quantified. The mass exchange coefficient predicted by LES does not vary significantly with the embayment rank and is in very good agreement with the one predicted by the model proposed by Weitbrecht et al. (J Hydraul Eng 134(2):173–183, 2008) based on the value of a dimensionless morphometric groyne-field parameter. Field experiments were purposely performed in a natural stream with embayments whose length over width ratios were close to the ratio in the LES study. The concentration fields predicted by LES are compared with video-records of colored dye used to visualize the mass exchange in the field experiment. It is shown that, for both LES and the field experiment, the dominant passage frequency of the eddies inside the interfacial mixing layer is well predicted by the analytical model of Sukhodolov and Sukhodolova (in: Cowen et al (eds) Hydraulic measurements & experimental methods. Proceedings of international conference, Lake Placid, USA, pp 172–177, 2007). The model is then used to scale the time in the LES animations and field video-records showing the temporal evolution of the concentration field. The results of the comparison indicate several similarities in the mixing process, despite the differences in the bathymetry and the large difference in the Reynolds number between LES and the field experiment. This proves the usefulness of performing detailed LES and laboratory studies in well-controlled environments to understand mass-exchange processes around river groyne fields.     

Conservation value of small reserves

The importance of large reserves has been long maintained in the scientific literature, often leading to dismissal of the conservation potential of small reserves. However, over half the global protected-area inventory is composed of protected areas that are <100 ha, and the median size of added protected area is decreasing. Studies of the conservation value of small reserves and fragments of natural area are relatively uncommon in the literature. We reviewed SCOPUS and WOK for studies on small reserve and fragment contributions to biodiversity conservation and ecosystem services, and fifty-eight taxon-specific studies were included in the review. Small reserves harbored substantial portions (upward of 50%) of regional species diversity for many taxa (birds, plants, amphibians, and small mammals) and even some endemic, specialist bird species. Unfortunately, small reserves and fragments almost always harbored more generalist and exotic species than large reserves. Community composition depended on habitat quality, surrounding land use (agricultural vs. urban), and reserve and fragment size, which presents opportunities for management and improvement. Small reserves also provided ecosystem services, such as pollination and biological pest control, and cultural services, such as recreation and improved human health. Limitations associated with small reserves, such as extinction debt and support of area-sensitive species, necessitate a complement of larger reserves. However, we argue that small reserves can make viable and significant contributions to conservation goals directly as habitat and indirectly by increasing landscape connectivity and quality to the benefit of large reserves. To effectively conserve biodiversity for future generations in landscapes fragmented by human development, small reserves and fragments must be included in conservation planning.     

RIPARIAN ZONE CLASSIFICATION FOR MANAGEMENT OF STREAM WATER QUALITY AND ECOSYSTEM HEALTH1

ABSTRACT: Riparian zones perform a variety of biophysical functions that can be managed to reduce the effects of land use on instream habitat and water quality. However, the functions and human uses of riparian zones vary with biophysical factors such as landform, vegetation, and position along the stream continuum. These variations mean that “one size fits all” approaches to riparian management can be ineffective for reducing land use impacts. Thus riparian management planning at the watershed scale requires a framework that can consider spatial differences in riparian functions and human uses We describe a pilot riparian zone classification developed to provide such a framework for riparian management in two diverse river systems in the Waikato region of New Zealand. Ten classes of riparian zones were identified that differed sufficiently in their biophysical features to require different management. Generic “first steps” and “best practical” riparian management recommendations and associated costs were developed for each riparian class. The classification aims to not only improve our understanding of the effectiveness of riparian zone management as a watershed management tool among water managers and land owners, but to also provide a basis for deciding on management actions.     

The role of psychology in determining human–predator conflict across southern Kenya

Conflict between people and carnivores can lead to the widespread killing of predators in retaliation for livestock loss and is a major threat to predator populations. In Kenya, a large, rural, pastoralist population comes into regular conflict with predators, which persist across southern Kenya. We explored the social and psychological backdrop to livestock management practices in this area in a process designed to be easy to use and suitable for use across large areas for the study of conflict and transboundary implementation of wildlife conflict reduction measures, focusing on community involvement and needs. We carried out fully structured interviews of livestock managers with a survey tool that examined how social and psychological factors may influence livestock management behavior. We compared survey responses on 3 sites across the study area, resulting in 723 usable responses. Efficacy of individuals’ livestock management varied between and within communities. This variation was partially explained by normative and control beliefs regarding livestock management. Individual livestock managers’ self-reported management issues were often an accurate reflection of their practical management difficulties. Psychological norms, control beliefs, and attitudes differed among sites, and these differences partially explained patterns associated with conflict (i.e., variation in livestock management behavior). Thus, we conclude that a one-size-fits-all approach to improving livestock management and reducing human–predator conflict is not suitable.     

The importance of tangible and intangible factors in human–carnivore coexistence

Conflict with humans is one of the major threats facing the world's remaining large carnivore populations, and understanding human attitudes is key to improving coexistence. We surveyed people living near Hwange National Park about their attitudes toward coexisting with lions. We used ordinal regression models with the results of the survey to investigate the importance of a range of tangible and intangible factors on attitudes. The variables investigated included the costs and benefits of wildlife presence, emotion, culture, religion, vulnerability, risk perception, notions of responsibility, and personal value orientations. This was for the purpose of effectively tailoring conservation efforts but also for ethical policy making. Intangible factors (e.g., fear and ecocentric values) were as important as, if not more important than, tangible factors (such as livestock losses) for understanding attitudes, based on the effect sizes of these variables. The degree to which participants’ fear of lions interfered with their daily activities was the most influential variable. The degree to which benefits accrue to households from the nearby protected area was also highly influential, as was number of livestock lost, number of dependents, ecocentric value orientation, and participation in conflict mitigation programs. Contrary to what is often assumed, metrics of livestock loss did not dominate attitudes to coexistence with lions. Furthermore, we found that socioeconomic variables may appear important when studied in isolation, but their effect may disappear when controlling for variables related to beliefs, perceptions, and past experiences. This raises questions about the widespread reliance on socioeconomic variables in the field of human–wildlife conflict and coexistence. To facilitate coexistence with large carnivores, we recommend measures that reduce fear (through education and through protective measures that reduce the need to be fearful), reduction of livestock losses, and ensuring local communities benefit from conservation. Ecocentric values also emerged as influential, highlighting the need to develop conservation initiatives tailored to local values.