Continental scale passive air sampling of persistent organic pollutants using rapidly equilibrating thin films (POGs)

A novel design of rapidly equilibrating passive air sampler was deployed at 38 sites across 19 European countries to investigate short-term spatial variability of persistent organic pollutants (POPs). Devices were sealed in airtight containers to eliminate the possibility of contamination during transit and couriered to recipients with deployment instructions. Exposure times of 7days permitted the use of back trajectory analysis to further understand the factors responsible for influencing the large-scale spatial distribution of PCBs, PBDEs, PCNs, PAHs, lindane and HCB. Following sampler harvest, devices were sealed and returned for analysis. Comparison of sequestered levels showed that PAHs exhibited the greatest spatial variability (by a factor of 30) with higher levels often associated with greater population density. In contrast, HCB values were much more uniform, reflecting its well mixed distribution in the atmosphere. Spatial variation was strongly influenced by air mass origin, with lower levels being observed at most sites impacted by maritime air masses.     

Effect of coal mine soil contamination on the elemental uptake and distribution in two edible Amaranthus species, A. dubius and A. hybridus

The impact of coal mine dump contaminated soil on the elemental uptake by two edible plants, namely, Amaranthus dubius (red herbs) and Amaranthus hybridus (green herbs), was studied by investigating their response and ability to tolerate and accumulate varying levels of elements in their roots and shoots. The vegetation was grown on varying amounts of contaminated soil, viz. 0%, 5%, 15%, 25% w/w using coal mine dump soil. The soil was analyzed for soil pH, cation exchange capacity (CEC), soil organic matter (SOM), moisture content, and selected heavy metals. The distribution of six metals, namely, Pb, Cd, Hg, Ni, Mn, and Fe, in roots, stem, and leaves of the plants was determined in two stages of growth after 5 weeks and 10 weeks. All soil and plant samples were microwave digested and subjected to heavy metal analysis using the ICP-OES, GFAAS, and CVAAS. The pH of the coal mine dump contaminated soil decreased with an increase in contamination. Both the SOM and CEC values decreased, which increases the availability of elements, by providing more binding sites in the soil. Relatively, the red herbs had higher elemental concentrations than the green herbs. Both plants recorded high manganese accumulation. No mercury was detected in the soils or plants.     

Selection of a water-extractable phosphorus test for manures and biosolids as an indicator of runoff loss potential

The correlation of runoff phosphorus (P) with water-extractable phosphorus (WEP) in land-applied manures and biosolids has spurred wide use of WEP as a water quality indicator. Land managers, planners, and researchers need a common WEP protocol to consistently use WEP in nutrient management. Our objectives were to (i) identify a common WEP protocol with sufficient accuracy and precision to be adopted by commercial testing laboratories and (ii) confirm that the common protocol is a reliable index of runoff P. Ten laboratories across North America evaluated alternative protocols with an array of manure and biosolids samples. A single laboratory analyzed all samples and conducted a separate runoff study with the manures and biosolids. Extraction ratio (solution:solids) was the most important factor affecting WEP, with WEP increasing from 10:1 to 100:1 and increasing from 100:1 to 200:1. When WEP was measured by a single laboratory, correlations with runoff P from packed soil boxes amended with manure and biosolids ranged from 0.79 to 0.92 across all protocol combinations (extraction ratio, filtration method, and P determination method). Correlations with P in runoff were slightly lower but significant when WEP was measured by the 10 labs (r=0.56-0.86). Based on laboratory repeatability and water quality evaluation criteria, we recommend the following common protocol: 100:1 extraction ratio; 1-h shaking and centrifuge 10 min at 1500xg (filter with Whatman #1 paper if necessary); and determining P by inductively coupled plasma-atomic emission spectrometry or colorimetric methods.     

Engaging with the Ecological Footprint as a Decision-Making Tool: Process and Responses

Since the initial development of the Ecological Footprint in the early 1990s, the concept has gained increased interest amongst academics and practitioners internationally. In the UK, it is estimated that some 60 to 70 Ecological Footprint studies were undertaken between 1999 and 2004. Although the majority of interest in Ecological Footprinting has come from local government, a recent study has found that government officers involved in the formulation of council policy have not been able to engage with the Ecological Footprint as a process or use the results to inform policy decisions. This paper analyses how an Ecological Footprint has been developed for Cardiff, the capital city of Wales. The approach used to construct an Ecological Footprint for Cardiff has been significantly different to that which had been used previously in the UK, as it has involved a unique consortium of researchers at Cardiff University and policy development officers at Cardiff Council checking the quality of data used in the Footprint calculation, and developing a range of policy scenarios.     

Status of Marine Mammals in the United States

Abstract: The 1994 amendments to the U.S. Marine Mammal Protection Act required, for the first time, an assessment of the status of every marine mammal stock in the United States. We draw conclusions about the status of marine mammals from assessments of 153 stocks conducted to meet the requirements of these amendments. We found important regional differences in the status of stocks. Most stocks in the Atlantic and Pacific experience human-induced mortality (takes), primarily from gill-net fisheries. The proportion of stocks with takes was lower in the Gulf of Mexico and Hawaii, areas with few gill-net fisheries. Estimated takes exceeded removal limits for 29% of stocks in the Atlantic, 14% in the Pacific, 8% in Alaska, 7% in the Gulf of Mexico, and 0% in Hawaii. Twenty-eight stocks are listed as threatened or endangered under the U.S. Endangered Species Act. Most, but not all, baleen whale stocks are recovering after cessation of commercial harvests. Many species of pelagic cetaceans, including beaked and sperm whales, are vulnerable to mortality in pelagic drift-net fisheries. Most pinniped stocks experience takes, but none of these takes exceeds removal limits, and all pinniped stocks on mainland coasts of the United States are increasing in abundance. Quantitative data on trends in abundance are available for few cetacean stocks, emphasizing the difficulty of monitoring trends in these species. These stock assessments have greatly advanced our understanding of the status of marine mammals in the United States, but information gaps remain, particularly regarding stock structure and possible mortality in unmonitored fisheries.     

Book reviews

Sustainable Cities and Sustainable Development Sustainable Cities. G. Haughton & C. Hunter, 1994, Jessica Kingsley/Regional Studies Association, London

Sustainable Cities in Europe. P. Nijkamp & A. Perrels, 1994, Earthscan, London ISBN 185383, £12.95

Toward Sustainable Development Concepts, Methods and Policy. J. C. J. M. van den Bergh & J. van der Straaten, 1994, Island Press, Washington, DC, ISBN 1 55963 3492, £30.00

Just Environments: intergenerational, international and interspecies issues. David E. Cooper & Joy A. Palmer (Eds), 1995, London, Routledge, ISBN 0 415-10336-3, pp. 199, index, £11.99

First Steps: Local Agenda 21 in practice. Stella Whittaker (Ed.), 1995, London, HMSO, 251 pp. ISBN 0 11 701871 6, £29.95

Beyond the Car: essays on the auto culture. Sue Zielinski & Gordon Laird (Eds), 1995, Toronto, Steel Rail Publishing/Transportation Options, 191 pp. ISBN 0 88791 042 4, pbk, C$ 19.95, US$15.95     

Synthesis and characterisation of potassium polytitanate for photocatalytic degradation of crystal violet

Potassium titanate nanostructures were synthesised by hydrothermal treatment of TiO2 （P25） in KOH and H2O2. As-produced powders were characterised by scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, and nitrogen adsorption-desorption methods. Longitudinally-oriented-wire-like structures with a length up to several micrometres and diameters ranging from 10 to 30 nm were obtained. Larger size fibrous nanowires resulting from the hydrotherrnal treatment showed high affinity in adsorbing crystal violet （CV）, which was mainly due to their high surface area. The photocatalytic bleaching of CV solution revealed that the wires are photoactive under ultraviolet light irradiation. Macroporous nanowires are considered as effective adsorbents of CV, capable of photocatalvtic degradation, and they can be easily separated from the solution by settling.     

Management walk-arounds: Lessons from the Gulf of Mexico oil well blowout

Many companies understand that good management requires senior managers to spend time with front line workers. Some companies build into performance agreements for senior managers a requirement that they conduct a certain number of such site visits each year. The challenge is to make productive use of these visits. Safety is often a focus for visiting VIPs, but too often safety is understood to be a matter of “slips, trips and falls”, rather than the major hazards that can blow the plant or the rig apart. This paper will examine a VIP visit made to the Deepwater Horizon rig by senior managers from BP and from the rig owner, Transocean, just hours before the explosion. It will argue that, despite their best of intentions, these managers fell into the trap identified above. The paper looks at things that senior managers can do to focus attention on the most significant hazards.