Agricultural Land Use Effects on Sediment Loading and Fish Assemblages in Two Minnesota (USA) Watersheds

We examined the relationship between water quality and fish communities within two agricultural areas using a computer simulation model. Our analyses focused on a coolwater stream, Wells Creek in southeastern Minnesota, and a warmwater stream, the Chippewa River in western Minnesota. We used the Agricultural Drainage and Pesticide Transport (ADAPT) model in relation to land use to calculate instream suspended sediment concentrations using estimates of sediment delivery, runoff, baseflow and streambank erosion, and quantified the effects of suspended sediment exposure on fish communities. We predicted the effects of agricultural practices on stream fish communities under several possible land use scenarios, with reference to current conditions. Land use changes led to reductions in sediment loading of up to 84% in Wells Creek and 49% in the Chippewa River. The reduction in sediment loading across scenarios may be directly related to a reduction in runoff by about 35% in both study areas. We found a 98% decrease in lethal concentrations of suspended sediment on fish in Wells Creek with an increase in conservation tillage, riparian buffers, and permanent vegetative cover. However, the effects of suspended sediment did not significantly decrease in the Chippewa River. This difference between study areas was likely due to differences in tolerance to suspended sediment between coolwater and warmwater fish communities and differences in topography, runoff and bank erosion between the two streams. The Minnesota Cooperative Fish and Wildlife Research Unit is jointly sponsored by the US Geological Survey, the University of Minnesota, the Minnesota Department of Natural Resources, and the Wildlife Management Institute.     

Comparison of Hydrology of Wetlands in Pennsylvania and Oregon (USA) as an Indicator of Transferability of Hydrogeomorphic (HGM) Functional Models Between Regions

The hydrogeomorphic (HGM) approach to wetland classification and functional assessment is becoming more widespread in the United States but its use has been limited by the length of time needed to develop appropriate data sets and functional assessment models. One particularly difficult aspect is the transferability among geographic regions of specific models used to assess wetland function. Sharing of models could considerably shorten development and implementation of HGM throughout the United States and elsewhere. As hydrology is the driving force behind wetland functions, we assessed the comparability of hydrologic characteristics of three HGM subclasses (slope, headwater floodplain, mainstem floodplain) using comparable long-term hydrologic data sets from different regions of the United States (Ridge and Valley Province in Pennsylvania and the Willamette Valley in Oregon). If hydrology by HGM subclass were similar between different geographic regions, it might be possible to more readily transfer extant models between those regions. We found that slope wetlands (typically groundwater-driven) had similar hydrologic characteristics, even though absolute details (such as depth of water) differed. We did not find the floodplain subclasses to be comparable, likely due to effects of urbanization in Oregon, regional differences in soils and, perhaps, climate. Slight differences in hydrology can shift wetland functions from those mediated by aerobic processes to those dominated by anaerobic processes. Functions such as nutrient cycling can be noticeably altered as a result. Our data suggest considerable caution in the application of models outside of the region for which they were developed.     

Quantitative Assessment of Agricultural Runoff and Soil Erosion Using Mathematical Modeling: Applications in the Mediterranean Region

Three mathematical models, the runoff curve number equation, the universal soil loss equation, and the mass response functions, were evaluated for predicting nonpoint source nutrient loading from agricultural watersheds of the Mediterranean region. These methodologies were applied to a catchment, the gulf of Gera Basin, that is a typical terrestrial ecosystem of the islands of the Aegean archipelago. The calibration of the model parameters was based on data from experimental plots from which edge-of-field losses of sediment, water runoff, and nutrients were measured. Special emphasis was given to the transport of dissolved and solid-phase nutrients from their sources in the farmers' fields to the outlet of the watershed in order to estimate respective attenuation rates. It was found that nonpoint nutrient loading due to surface losses was high during winter, the contribution being between 50% and 80% of the total annual nutrient losses from the terrestrial ecosystem. The good fit between simulated and experimental data supports the view that these modeling procedures should be considered as reliable and effective methodological tools in Mediterranean areas for evaluating potential control measures, such as management practices for soil and water conservation and changes in land uses, aimed at diminishing soil loss and nutrient delivery to surface waters. Furthermore, the modifications of the general mathematical formulations and the experimental values of the model parameters provided by the study can be used in further application of these methodologies in watersheds with similar characteristics.     

Ethoxylated Soybean Polyols for Polyurethanes

Soybean polyols prepared by ring opening reactions of epoxidized soybean oil with hydrogen active compounds (water, alcohols, organic or inorganic acids, thiols, hydrogen etc.) have a low reactivity in the reaction with isocyanates because the hydroxyl groups are secondary. This paper presents a simple and convenient method to increase the reactivity of soybean polyols with secondary hydroxyl groups by ethoxylation reactions with the preservation of triglyceride ester bonds. The method uses mild reaction conditions: low alkoxylation temperature of 35–45 °C, low pressure of 0.1–0.2 MPa (15–30 p.s.i.) and a superacid as catalyst (HBF₄). The new soybean polyols have a higher reactivity toward isocyanates in polyurethane formation due to the high percentage of primary hydroxyl groups. The primary hydroxyl content was determined by the second order kinetics of polyol reaction with phenyl isocyanate.     

Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review

Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However, the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties. In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed. Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates, permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites is reduced and their mechanical properties are improved.     

Study of Fatigue Life and Filler Interaction of Paper Sludge Filled Epoxidized Natural Rubber (ENR) and Maleated Natural Rubber (MNR) Composites

An investigation on the effect of epoxidation and maleated natural rubber (MNR) on fatigue and rubber-filler interaction properties of paper sludge filled natural rubber composites was elucidated. Paper sludge loading was varied from 0 to 40 phr and conventional vulcanisation system was used while compounding was carried out on a laboratory sized two roll mill. Two different types of natural rubber, SMR L and ENR 50 having 0 and 50 mole% of epoxidation were used in order to investigate the effect of epoxidation on the composites. Results indicate that, at a fixed filler loading, ENR 50 vulcanizates exhibit higher fatigue life than SMR L vulcanizates especially at filler loading below 20 phr which might be associated with better rubber-filler interaction. In the case of composites with the addition of maleated natural rubber (MNR), a higher fatigue life was observed due to presence of physical and/or chemical linkages, which increases the interfacial adhesion. Scanning electron microscopy (SEM) micrographs of fatigue fracture surfaces and rubber-filler interaction study supported the observed result on fatigue life.     

Effect of Recycling on Material Properties of Glass-filled Polyethylene Terephthalate

Recycled plastics are considered low performance materials because their properties are expected to decrease drastically with recycling. The objective of this study was to characterize a 15 wt.% glass filled polyethylene terephthalate (rPET-15GF) using six recycle generations and four recycle ratios. Mechanical properties such as tensile strength, elastic modulus, and percent elongation to failure of the PET composite were determined for various recycle generations and recycle ratios. Results show that the mechanical properties of rPET-15GF decrease slightly per recycle generation. In contrast, thermal properties of rPET-15GF were not at all affected by the recycling process. This data demonstrates that recycled glass filled PET can be used effectively to fabricate components without significantly affecting their mechanical performance.     

Characterization and recycling of polymeric components present in cell phones

The cell phone market is developing at a rapid speed. Today there are more than 1.6 billion consumers in the world, and the lifetime of a cell phone is less than 2 years. As a consequence, there is an increase in the waste associated to this product, and many alternatives to the disposal of the cell phones are being studied, such as recycling which shows to be the most important. It is crucial to know what materials constitute the cell phone in order to carry out recycling and determine environmental and economical issues. This work presents an evaluation of the cell phone components, characterizing the raw materials and some properties of the recycled materials.     

EEG bioeffects on cochlear deaf from cellular phones

Objectives This paper aims to provide evidence of an inductive electromagnetic bioeffect on the human brain, which is independent from sound waves and produced by mobile phones, in proximal field, through correlating the EEG data obtained from electrodes placed on both normal and cochlear deaf individuals. Methods Two groups of subjects are placed under controlled electromagnetic conditions inside a Faraday chamber, 12 healthy and another 12 suffering from cochlear deafness). Each is sitting on a chair, fitted with additional support, and holding a cellular phone 2 cm away form the right auricular, in order to avoid a thermal effect as much as possible. All of them, relaxed and with their eyes closed, are EEG recorded in a basal state with their mobile phones off. Then, each of them is again recorded under the same conditions but with the mobile on and listening to the same conversation. In order to assess the observed EEG changes, a statistical analysis by means of the FFT (Fast Fourier Transform) was carried out. Results For both, healthy and cochlear deaf, assimilation or integration of the mobile phone signal by some electrodes is to be found. This is due to the increase of amplitudes for alpha and theta waves, whereas the signal is not integrated in other electrodes. By correlating the spectra of frequencies of corresponding EEG records for the same brain areas, we have not observed significative differences for both groups. Conclusions A possible electromagnetic direct inductive, non-thermal, bioeffect on the human brain is observed. This effect is produced by the use of mobile phones and it bears no relation to the sound waves.