全文获取类型
收费全文 | 283篇 |
免费 | 8篇 |
国内免费 | 119篇 |
专业分类
安全科学 | 13篇 |
废物处理 | 26篇 |
环保管理 | 13篇 |
综合类 | 152篇 |
基础理论 | 59篇 |
污染及防治 | 115篇 |
评价与监测 | 6篇 |
社会与环境 | 15篇 |
灾害及防治 | 11篇 |
出版年
2023年 | 11篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 11篇 |
2017年 | 21篇 |
2016年 | 20篇 |
2015年 | 9篇 |
2014年 | 31篇 |
2013年 | 28篇 |
2012年 | 30篇 |
2011年 | 28篇 |
2010年 | 17篇 |
2009年 | 19篇 |
2008年 | 22篇 |
2007年 | 23篇 |
2006年 | 13篇 |
2005年 | 11篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 10篇 |
2000年 | 7篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1988年 | 1篇 |
排序方式: 共有410条查询结果,搜索用时 62 毫秒
151.
Size distribution, characteristics and sources of heavy metals in haze episod in Beijing 总被引:3,自引:0,他引:3
Size segragated samples were collected during high polluted winter haze days in 2006 in Beijing, China. Twenty nine elements and 9 water soluble ions were determined. Heavy metals of Zn, Pb, Mn, Cu, As, Cr, Ni, V and Cd were deeply studied considering their toxic effect on human being. Among these heavy metals, the levels of Mn, As and Cd exceeded the reference values of National Ambient Air Quality Standard (GB3095-2012) and guidelines of World Health Organization. By estimation, high percentage of atmospheric heavy metals in PM2.5 indicates it is an effective way to control atmospheric heavy metals by PM2.5 controlling. Pb, Cd, and Zn show mostly in accumulation mode, V, Mn and Cu exist mostly in both coarse and accumulation modes, and Ni and Cr exist in all of the three modes. Considering the health effect, the breakthrough rates of atmospheric heavy metals into pulmonary alveoli are: Pb (62.1%) 〉 As (58.1%) 〉 Cd (57.9%) 〉 Zn (57.7%) 〉 Cu (55.8%) 〉 Ni (53.5%) 〉 Cr (52.2%) 〉 Mn (49.2%) 〉 V (43.5%). Positive matrix factorization method was applied for source apportionment of studied heavy metals combined with some marker elements and ions such as K, As, SO42- etc., and four factors (dust, vehicle, aged and transportation, unknown) are identified and the size distribution contribution of them to atmospheric heavy metals are discussed. 相似文献
152.
官司河流域防护林景观结构及生态功能研究 总被引:3,自引:0,他引:3
利用2005年度的IKONOS4卫片解译数据和2007年度小班调查资料,结合样地调查资料以及四川省林业科学研究院森林生态效益定位站(四川绵阳新桥)径流场的有关数据,对绵阳官司河流域的防护林体系景观结构及生态功能进行了分析。结果表明:该区域防护林景观中,以松柏混交林(Mixed Alnus—Cupressus forest)面积最大,占27.37%,其次是马尾松纯林(Pinus massoniana forest),占25.41%。栎柏混交林(Mixed Quercus-Cupressus forest)最少,只占0.96%。纯林面积明显大于混交林,前者比后者大45.31%。栎柏混交林、松柏栎混交林(Mixed Pinus-Cupressus—Quercus forest)最大斑块指数(LPI)、边缘密度(ED)和斑块密度(PD)较小,分布较为破碎。而马尾松纯林、松柏混交林和柏木纯林(Cupressus forest)分布较为集中。桤柏混交林(Mixed Alnus—Cupressus forest)和松柏混交林的散布与并列指数(IJI)较大,其空间关系较为复杂。栎柏混交林、柏木纯林的聚集度(A1)较小,斑块分散度大,连接睦较差;而桤柏混交林、松柏混交林的分散度较大,连接性较好。桤柏混交林、松柏混交林的形状指数(LSI)较小,形状分布较规则,而马尾松纯林、柏木纯林的形状指数较大,形状较复杂。从不同景观类型林下灌草层的生物多样性指数可知,松柏混交林、栎柏混交林的灌草多样性指数均较大,而马尾松纯林、柏木纯林则较小。从保持水土功能来看:桤柏混交林、松柏混交林的水土保持效果优于柏木纯林、马尾松纯林,桤柏混交林的水土保持效果优于松柏混交林。因此,对长江防护林进行空间结构调整,应多采用混交林模式,针阔混交林代替针针混交,乔灌草结合,调整合理的密度,使防护林景观的生态功能更好地发挥。 相似文献
153.
Yu Y Huang Q Wang Z Zhang K Tang C Cui J Feng J Peng X 《Journal of environmental monitoring : JEM》2011,13(4):871-878
The occurrence and behavior of β-blockers, antiepileptic drug carbamazepine and its metabolites, X-ray contrast agent iopromide, natural and synthetic hormones, and several groups of hormone-like personal care products (PCPs), including antiseptics (triclocarban, triclosan, and 2-phenylphenol), parabens and bisphenol A, were investigated in municipal wastewater, sewage sludge, and urban river water of the Pearl River Delta, South China. The pharmaceuticals, natural hormones and PCPs were ubiquitously detected in the raw wastewater from a sewage treatment plant (STP). Only triclocarban and triclosan were detected at significant amounts in the dewatered sludge. Iopromide and the PCPs were greatly removed/transformed from the aqueous phase of the wastewater. The β-blockers were only moderately removed/transformed. Carbamazepine passed through the STP almost unchanged. Biodegradation was the dominant process for elimination/transformation of the pharmaceuticals, hormones, and most PCPs in the STP. However, sorption also played an important role in the fate of triclocarban with nearly 50% of the mass load entering the STP ended up and persisted in the dewatered sludge. The pharmaceuticals, estrone, and PCPs were also widely detected in the Pearl River at Guangzhou. Bisphenol A had the highest concentration. The pharmaceutical concentrations in the Pearl River were higher in March than in May, most likely due to less dilution by lower precipitation. The omnipresence and high levels of the pharmaceuticals and PCPs in the Pearl River may be associated with direct discharge of untreated wastewater and pose potential risks to the ecological system. 相似文献
154.
以甘蔗渣为原料,采用微波辅助磷酸活化法制备了同时富含中孔结构和含氧酸官能团的生物质炭,以氮气吸附、红外光谱FT-IR等技术对炭样品表面物化性质进行了表征,通过静态实验法测定了生物质炭对水中亚甲基蓝的吸附特性,分析了溶液pH、初始浓度、温度对吸附的影响,研究了不同pH下蔗渣生物质炭对亚甲基蓝的吸附行为,并从热力学及动力学角度探讨了生物质炭对亚甲基蓝的吸附机理。结果表明,不同制备参数下生物质炭的得率均大于39.2%,但表面物化性质因参数变化有较大差异。在浸渍比1∶1,烘干时间10 h,活化功率900 W,活化时间22 min的条件下,制得的生物质炭的比表面积为1 021 m2/g,亚甲基蓝值超过国家一级品标准1.70倍,表面富含微中孔结构和羟基、羰基、羧基等酸性官能团,中孔约占总孔的40%。静态吸附实验表明,溶液初始浓度对吸附有较大的影响,吸附量随初始浓度的增加,pH的升高及温度的上升而增大,Freundlich方程、Redlich-Peterson方程与Temkin方程能较好地描述等温吸附行为;吸附动力学结果表明,数据符合Elovich方程,吸附行为更倾向于化学吸附;热力学研究表明,吸附吉布斯自由能(ΔG0)0,吸附标准焓变(ΔH0)70 kJ/mol,说明该吸附为自发的吸热反应,且化学反应在吸附过程中发挥了重要作用。 相似文献
155.
156.
中国排污许可证制度执行现状调查 总被引:4,自引:0,他引:4
本研究以广州、石家庄、兰州、哈尔滨和大同5个城市为调研对象,收集各城市20年来许可证相关的法规制度,并与各城市环境保护监管部门负责人及典型企业环保专职人员进行了访谈。研究表明,中国排污许可证制度在提高企业环保守法意识和推动总量减排上起到了明显作用,但也面临着法律体系不完善,行政资源不足、排放量核算方法不明确、处罚力度弱以及公众参与不充分等问题。在此基础上,本研究提出中国排污许可证制度的改进建议,为决策部门制定相应的政策提供科学和技术的支撑。 相似文献
157.
Hussani Mubarak Li-Yuan Chai Nosheen Mirza Zhi-Hui Yang Arshid Pervez Madiha Tariq 《毒物与环境化学》2015,97(10):1296-1318
In view of increasing emissions of antimony (Sb) into the environment due to industrialization and consequent carcinogenicity, it is essential to remove this metal from the ecosystem. Antimony and arsenic (As) are analogs. Although numerous studies examined arsenic removal, few reports are available on Sb removal. In this review, various Sb removal techniques are described to understand how this process occurs and what research gaps are needed to improve efficiency. At present, surface adsorption technique is the most widely used for Sb removal. Biological treatment namely phytoremediation is also a promising method and more investigations are required in this regard. The selection of a suitable technique for a given area depends on the conditions including economic, environmental, and social conditions. 相似文献
158.
159.
160.