滇池与红枫湖沉积物中磷的地球化学特征比较研究

对比研究了滇池与红枫湖表层沉积物中磷的形态含量及其生物有效性.结果表明,两湖沉积物总磷含量相当,分别为1373.8～ 4616.3mg·kg-1、1194.4 ～4324.3 mg·kg-1.HCl-P、Res-P为滇池沉积物中主要的磷形态,占总磷的62.9％ ～86.4％;而红枫湖中磷形态顺序为NaOH-P＞ Res-P＞ HCl-P＞ BD-P＞ NH4Cl-P;两湖沉积物中有机磷均以低活性态为主.红枫湖沉积物中NH4Cl-P、BD-P、NaOH-rP及生物有效磷等平均含量明显高于滇池,表明其内源磷释放对上覆水体富营养化的贡献更大.Olsen-P与NH4Cl-P、BD-P、NaOH-rP等活性磷形态呈显著正相关,而与NaOH-nrP、HCl-P、Res-P、TP等相关性不显著,因此,可作为评价两湖沉积物释磷能力及其潜在环境风险的重要指标.     

近52年江西省汛期极端降水事件的时空变化

利用江西省1960～2011年汛期83个台站逐日降水资料,首先定义了不同台站的极端降水阈值,统计各站近52a逐年汛期极端降水事件的发生频次,进而分析其时空分布特征。结果表明：江西省极端降水量阈值的地域分布呈从西到东、从南到北递增的特征。江西汛期极端降水事件发生频次的最主要空间模态是主体一致性,同时存在北部与中南部反位相变化的差异。江西汛期极端降水事件发生频次具有较大的空间差异,可分为具有不同空间特征的5个主要区域。滑动t检验表明,Ⅰ区代表站玉山的极端降水事件在1976年后和1986年后分别发生了由偏多转为偏少和由偏少转为偏多的突变;Ⅱ区代表站永丰在1974年后和1984年后分别发生了由偏少转为偏多和由偏多到偏少的突变。通过最大熵谱分析表明,各分区以2～6 a的年际变化周期最为普遍,其中Ⅴ区还存在13 a的年代际变化周期。从气候因子分析看,前期5～6月和冬季赤道东太平洋海温对江西汛期极端降水事件存在显著影响     

江苏省生态足迹分析与可持续发展研究

生态足迹是定量研究区域可持续发展的一种重要方法。目前将生态足迹用于不同时间序列分析,以描述区域可持续发展状况的研究仅初始于不多的国外研究机构。通过对江苏省10年间生态足迹变化情况进行纵向比较分析,来考虑人类及其发展与生态环境的关系,衡量在人类开发强度较大的江苏省,区域生态供给功能是否能满足开发和消费的需要,量化江苏经济发展对生态环境影响的程度,证实了研究区域江苏省的严峻形势。同时与目前国内外已有的生态足迹研究成果比较,概述江苏省生态足迹赤字产生的原因。     

Enantioselective separation and zebrafish embryo toxicity of insecticide beta-cypermethrin

Enantioselectivity of chiral pollutants is receiving growing concern due to the difference in toxicology and environment fate between enantiomers.In this study,enantiomers of insecticide beta-cypermethrin (beta-CP) were separated on selected chiral column by HPLC,and the toxicity of enantiomers was evaluated using the zebrafish embryo-larval assays.The enantiomers of beta-CP were baseline separated on Chiralcel OD and Chiralpak AD columns and detected by circular dichroism (CD) at 236 nm.Better separation could be achieved at lower temperature (e.g.,20°C) and with lower levels of polar modifiers.Pure enantiomers were obtained on Chiralcel OD.The CD spectra of enantiomers were recorded.By comparing the elution order with a previous similar study,the absolute configuration of beta-CP enantiomers was determined.The individual enantiomers were used in zebrafish embryo test,and the results showed that beta-CP enantioselectively induced yolk sac edema,pericardial edema and crooked body.The 1R-cis-αS and 1R-trans-αS enantiomers showed strong developmental toxicities at concentration of 0.1 mg/L,while the 1S-cis-αR and 1S-trans-αR induced no malformations at higher concentration (e.g.,0.3 mg/L).The results suggest that the enantioselective toxicological effects of beta-CP should be considered when evaluating its ecotoxicological effects.     

Preparation and related properties of geopolymer solidified uranium tailings bodies with various fibers and fiber content

Environmental Science and Pollution Research - Uranium tailing ponds are a potential major source of radioactive pollution. Solidification treatment can control the diffusion and migration of...     

Acute associations between air pollution on premature rupture of membranes in Hefei,China

Numerous studies had focused on the association between air pollution and health outcomes in recent years. However, little evidence is available on associations between air pollutants and premature rupture of membranes (PROM). Therefore, we performed time-series analysis to evaluate the association between PROM and air pollution. The daily average concentrations of PM_2.5, SO₂ and NO₂ were 54.58 μg/m³, 13.06 μg/m³ and 46.09 μg/m³, respectively, and daily maximum 8-h average O₃ concentration was 95.67 μg/m³. The strongest effects of SO₂, NO₂ and O₃ were found in lag4, lag06 and lag09, and an increase of 10 μg/m³ in SO₂, NO₂ and O₃ was corresponding to increase in incidence of PROM of 8.74% (95% CI 2.12–15.79%), 3.09% (95% CI 0.64–5.59%) and 1.68% (95% CI 0.28–3.09%), respectively. There were no significant effects of PM_2.5 on PROM. Season-specific analyses found that the effects of PM_2.5, SO₂ and O₃ on PROM were more obvious in cold season, but the statistically significant effect of NO₂ was observed in warm season. We also found the modifying effects by maternal age on PROM, and we found that the effects of SO₂ and NO₂ on PROM were higher among younger mothers (<?35 years) than advanced age mothers (≥?35 years); however,?≥?35 years group were more vulnerable to O₃ than?<?35 years group. This study indicates that air pollution exposure is an important risk factor for PROM and we wish this study could provide evidence to local government to take rigid approaches to control emissions of air pollutants.

     

石化企业伤亡事故率的系统动力学仿真

针对石化企业伤亡事故率的复杂性和与企业运行的系统相关性,为了科学地预测伤亡事故率,提出了利用系统动力学对石化企业伤亡事故率进行仿真试验的方法.在对石化企业伤亡事故率进行了系统动力学分析之后,建立了石化企业伤亡事故率系统动力学仿真模型,对某石化企业进行了仿真试验,并分析了仿真试验的结果.试验应用表明,利用系统动力学对石化企业伤亡事故率进行仿真是科学有效的.     

即将发布的《坠落防护 挂点装置》国家标准解读

《坠落防护挂点装置》标准是规定高处坠落防护挂点装置的技术要求、检验方法、检验规则及标识的国家标准。本文从标准适用范围、挂点装置分类、技术要求、检验等方面简述该标准的特点及意义,以加深对该标准的理解,促进其在挂点装置生产及检测方面的导向作用。     

国外热防护服装性能测试技术标准研究

热防护服是热环境下人体安全防护的主要装备,其标准的科学性和系统性对热环境下的人体安全防护具有重要的支持作用.国外对热防护服相关的技术标准予以充分重视,以性能测试技术方法为主体,建立了较为科学、完善的标准,并体现出新的发展趋势.通过对国外热防护服技术标准的调研,总结性能测试标准的共性内容,包括主要性能测试方法、实验设备、实验步骤、烧伤评估、人体模型和测试报告等.整套防护服装的性能测试技术及标准是研究的重点,出汗暖体假人将在防护服装性能测试领域被更为广泛的应用.最后,提出我国研制热防护服性能测试技术标准的建议.     

中国石油数字化应急预案系统研究

中国石油高度重视应急预案体系建设工作,集团公司和所属企业均在风险分析的基础上,建立了“横向到边、纵向到底”的应急预案体系,为有效应对各类突发事件提供了重要的支持.旨在对文本应急预案的数字化应用技术进行研究,以进一步提高应急预案的可操作性.首先,探讨了数字化应急预案的概念,分析了国内外数字化应急预案系统技术的研究现状.其次,基于中国石油数字化应急预案系统的需求分析,从业务流程设计、系统部署设计和系统功能设计等三个方面对其进行了研究和分析.最后,立足于中国石油应急信息系统建设实际,提出了中国石油建设数字化预案系统建设的实施步骤.