Evaluating and reducing a model of radiocaesium soil-plant uptake

An existing model of radiocaesium transfer to grasses was extended to include wheat and barley and parameterised using data from a wide range of soils and contact times. The model structure was revised and evaluated using a subset of the available data which was not used for model parameterisation. The resulting model was then used as a basis for systematic model reduction to test the utility of the model components. This analysis suggested that the use of 4 model variables (relating to radiocaesium adsorption on organic matter and the pH sensitivity of soil solution potassium concentration) and 1 model input (pH) are not required. The results of this analysis were used to develop a reduced model which was further evaluated in terms of comparisons to observations. The reduced model had an improved empirical performance and fewer adjustable parameters and soil characteristic inputs.     

Sorption of selenate on soils and pure phases: kinetic parameters and stabilisation

This study was conducted to identify the principle selenate carrier phases for two selected soils, by comparing their reactivity with selenate to that of pure phases of the solids. Silica, calcium carbonate, aluminium hydroxide, goethite, bentonite and humic acid were selected as the main soil carrier phases. Comparisons were made first on the parameter values obtained with the best fit of a kinetic sorption model which can discriminate instantaneous sorption from kinetically limited sorption. Then comparisons were made of the ability for each solid to stabilise selenate by measuring the ratio of the partition coefficient for sorption (Kd_sorption) over that of the desorption (Kd_desorption). Kinetics and stabilisation were used to help elucidate the nature of interactions with the test solid phases for a large range of selenate concentrations. The experiments were conducted over 165 h in batch reactors, the solid being isolated from the solution by dialysis tubing, at two pH (5.4 and 8) and three selenate concentrations (1 × 10⁻³, 1 × 10⁻⁶ and 1 × 10⁻⁸ mol L⁻¹). The results obtained showed that only aluminium hydroxide can sorb selenate throughout the studied pH range (pH 5.4 to 8.0). The sorption capacity on this mineral was high (Kd_sorption > 100 to 1 × 10⁴ L kg⁻¹) and the selenate was mainly stabilized by the formation of inner sphere complexes. The sorption on goethite occurred at pH 5.4 (Kd_sorption 52 L kg⁻¹), mainly as outer sphere complexes, and was null at pH 8. On silica, a weak sorption was observed only at pH 5.4 and at 165 h (Kd_sorption 4 L kg⁻¹). On bentonite, calcium carbonate and humic acid no significant sorption was observed. Concerning the two soils studied, different behaviours were observed for selenate. For soil Ro (pH 5.4), Kd_sorption was low (8 L kg⁻¹) compared to soil Bu (pH 8) (70 L kg⁻¹). The sorption behaviour of selenate on soil Ro was mainly due to outer sphere complexes, as for goethite, whereas for soil Bu the sorption was mainly attributed to inner sphere complexes followed by reduction mechanisms, probably initiated by microorganisms, in which no steady state was reached at the end of the 165 h experiments. The sorption of selenate decreased when concentrations reached 1 × 10⁻³ mol L⁻¹, due to solid saturation, except for aluminium hydroxide. Reduction of selenate seemed also to occur on goethite and soil Ro, for the same concentration, but without preventing a decrease in sorption. Thus, this work shows that the comparison of selenate behaviour between soil and pure phases helps to elucidate the main carrier phases and sorption mechanisms in soil.     

Growing stock and woody biomass assessment in Asola-Bhatti Wildlife Sanctuary,Delhi, India

Biomass is an important entity to understand the capacity of an ecosystem to sequester and accumulate carbon over time. The present study, done in collaboration with the Delhi Forest Department, focused on the estimation of growing stock and the woody biomass in the so-called lungs of Delhi—the Asola-Bhatti Wildlife Sanctuary in northern Aravalli hills. The satellite-derived vegetation strata were field-inventoried using stratified random sampling procedure. Growing stock was calculated for the individual sample plots using field data and species-specific volume equations. Biomass was estimated from the growing stock and the specific gravity of the wood. Among the four vegetation types, viz. Prosopis juliflora, Anogeissus pendula, forest plantation and the scrub, the P. juliflora was found to be the dominant vegetation in the area, covering 23.43 km² of the total area. The study revealed that P. juliflora forest with moderate density had the highest (10.7 m³/ha) while A. pendula forest with moderate density had the lowest (3.6 m³/ha) mean volume. The mean woody biomass was also found to be maximum in P. juliflora forest with moderate density (10.3 t/ha) and lowest in A. pendula forest with moderate density (3.48 t/ha). The total growing stock was estimated to be 20,772.95 m³ while total biomass worked out to be 19,366.83 t. A strong correlation was noticed between the normalized difference vegetation index (NDVI) and the growing stock (R ²?=?0.84)/biomass (R ²?=?0.88). The study demonstrated that growing stock and the biomass of the woody vegetation in Asola-Bhatti Wildlife Sanctuary could be estimated with high accuracy using optical remote sensing data.     

Direct Effects of Cattle on Grassland Birds in Canada

Effects of grazing on grassland birds are generally thought to be indirect, through alteration of vegetation structure; however, livestock can also affect nest survival directly through trampling and other disturbances (e.g., livestock‐induced abandonment). We extracted data on nest fates from 18 grazing studies conducted in Canada. We used these data to assess rates of nest destruction by cattle among 9 ecoregions and between seasonal and rotational grazing systems. Overall, few nests were destroyed by cattle (average 1.5% of 9132 nests). Nest destruction was positively correlated with grazing pressure (i.e., stocking rate or grazing intensity), but nest survival was higher in more heavily grazed areas for some species. Because rates of destruction of grassland bird nests by cattle are low in Canada, management efforts to reduce such destruction may not be of ecological or economic value in Canada. Efectos Directos del Ganado sobre las Aves de Pastizales en Canadá     

Atmospheric composition change research: Time to go post-normal?

For more than two decades a number of frameworks for scientific knowledge production are being proposed by science and technology researchers. They all advocate an extended involvement of non-specialists, in particular when it comes to knowledge production applicable to practical societal problems. We look to what extent these new frameworks have taken ground within a particular research community: the ACCENT Network of Excellence which coordinates European atmospheric chemistry and physics research applicable to air pollution and climate change. We did so by stimulating a debate through a “blog”, a survey and in-depth interviews with ACCENT scientists about the interaction between science, policy making and civil society, to which a great deal of ACCENT member contributed in writing or verbally. Most of them had interactions with policy makers and/or the general public, and they generally believe that interactions with spheres other than the scientific are needed. While such interactions give personal insight and satisfaction, they seem to have little impact on the goals and the practice of the scientific work itself. Extended frameworks of science production that go beyond the disciplinary mode seem to emerge at the level of individual scientists, yet they still need to find their way to the level of scientific project management. In this paper we discuss the justifications and barriers to implement a higher degree of extended knowledge integration in applied science projects such as ACCENT. It is felt that the community of atmospheric chemists and physicists is mature for such an implementation and recommendations are given to help and make this happen.     

Modeling linkages between sediment resuspension and water quality in a shallow,eutrophic, wind-exposed lake

The interactions between bed sediments and the water column in shallow, eutrophic lakes have tremendous implications for the fate and transport of nutrients in those water bodies. This has resulted in the development of water quality models for lakes incorporating the processes of sediment resuspension. Reliable resuspension models are thus needed to accurately represent this phenomenon. In this paper, three different sediment-resuspension models are combined with a hydrodynamic and water quality model, dynamic lake model-water quality (DLM-WQ), and the resulting models are used to simulate nutrient distributions in the highly eutrophic Salton Sea, California, USA. One of the resuspension formulas is based upon sediment characteristics as well as the bed shear stress exerted by wind-induced waves and currents, while the other two are standard, power-law-type formulas for cohesive sediments with two different exponents. The outputs for water quality variables, such as temperature, chlorophyll a, dissolved oxygen and nutrients, obtained from the three resulting models and from an earlier DLM-WQ run with a simple empirical sediment-resuspension model are compared with measured data. The level of agreement between the simulations and the measured data is assessed by using both statistical and graphical model evaluation methods, including measures of residual errors, sample autocorrelations, t-tests, and box plots. Based on these assessments, DLM-WQ with an extended version of the García and Parker [García, M.H., Parker, G., 1993. Experiments on the entrainment of sediment into suspension by a dense bottom current. J. Geophys. Res.-Oceans 98, 4793–4807] relationship gave the best results for water quality in the Salton Sea, confirming that the use of formulas with more information on the sediment characteristics yields more accurate results. To the best of our knowledge, this is the first effort to combine water quality models for lakes and reservoirs with a sediment-resuspension model which was originally intended for open-channel flows. The simulations confirm that sediment resuspension is the most dominant process in the Salton Sea's nutrient cycling. The effect of proposed physical changes to the Salton Sea on water quality characteristics is also addressed.     

Development of an analytical method for analysis of flubendiamide,des-iodo flubendiamide and study of their residue persistence in tomato and soil

Flubendiamide is a new insecticide that has been found to give excellent control of lepidopterous pests of tomato. This study has been undertaken to develop an improved method for analysis of flubendiamide and its metabolite des-iodo flubendiamide and determine residue retention in tomato and soil. The analytical method developed involved extraction of flubendiamide and its metabolite des-iodo flubendiamide with acetonitrile, liquid-liquid partitioning into hexane-ethyl acetate mixture (6:4, v v^?1) and cleanup with activated neutral alumina. Finally the residues were dissolved in gradient high pressure liquid chromatography (HPLC) grade acetonitrile for analysis by HPLC. The mobile phase, acetonitrile-water at 60:40 (v v^?1) proportion and the wavelength of 235 nm gave maximum peak resolution. Using the above method and HPLC parameters described, nearly 100 % recovery of both insecticides were obtained. There was no matrix interference and the limit of quantification (LOQ) of the method was 0.01 mg kg^?1. Initial residue deposits of flubendiamide on field-treated tomato from treatments @ 48 and 96 g active ingredient hectare^?1 were 0.83 and 1.68 mg kg^?1,respectively. The residues of flubendiamide dissipated at the half-life of 3.9 and 4.4 days from treatments @ 48 and 96 g a.i. ha^?1, respectively and persisted for 15 days from both the treatments. Des-iodo flubendiamide was not detected in tomato fruits at any time during the study period. Residues of flubendiamide and des-iodo flubendiamide in soil from treatment @ 48 and 96 g a.i. ha^?1 were below detectable level (BDL, < 0.01 mg kg^?1) after 20 days. Flubendiamide completely dissipated from tomato within 20 days when the 480 SC formulation was applied at doses recommended for protection against lepidopterous pests.     

Diffusion mechanism of lindane into wood charcoal

Abstract

The wood charcoal treated by 1N HNO₃ (WCT) was used to remove toxic chlorinated pesticide lindane (y‐HCH) residue from water by the sorption process. Using a simple first order reversible kinetics constants and half time equations, the film and pore diffusion coefficients were determined. Film diffusion was found to be rate limiting step in sorbing lindane by WCT. This was further authenticated by kinetics studies at different initial sorbate concentrations, different sorbent sizes, and different agitation speeds besides interruption test. A pore diffusion model was used to fit the data of kinetics in continuously mixed batch reactors (CMBR), and the tortuosity, external resistance, and surface diffusion effects on lindane sorption by WCT were noticed. The tortuosity values of 15 to 28 were obtained for WCT‐lindane system.     

Assessing the toxicity of organophosphorous pesticides to indigenous algae with implication for their ecotoxicological impact to aquatic ecosystems

This study aimed to determine the toxicity of three organophosphorous pesticides, chlorpyrifos, terbufos and methamidophos, to three indigenous algal species isolated from local rivers and algal mixtures. The diatom Nitzschia sp. (0.30–1.68 mg L^?1 of EC₅₀ -the estimated concentration related to a 50% growth reduction) and the cyanobacteria Oscillatoria sp. (EC₅₀ of 0.33–7.99 mg L^?1) were sensitive to single pesticide treatment and the chlorophyta Chlorella sp. was the most tolerant (EC₅₀ of 1.29–41.16 mg L^?1). In treatment with the mixture of three pesticides, Chlorella sp. became the most sensitive alga. The antagonistic joint toxic effects on three indigenous algae and algal mixtures were found for most of the two pesticide mixtures. The results suggested that mixture of pesticides might induce the detoxification mechanisms more easily than the single pesticide. The synergistic interactions between terbufos and methamidophos to algal mixtures and between methamidophos and chlorpyrifos to Nitzschia sp. indicated methamidophos might act as a potential synergist. Differential sensitivity of three families of algae to these pesticides might result in changes in the algal community structures after river water has been contaminated with different pesticides, posing great ecological risk on the structure and functioning of the aquatic ecosystem.     

Impact of “Designated Smoking Area” Policy on Nicotine Vapor and Particle Concentrations in a Modern Office Building

A series of measurements of nicotine vapor and particle concentrations were carried out in a modern office building. The measurement program was designed to document the impact of the new smoking policy (e.g. smoking restricted to two specific areas) on air quality in various parts of the building.

Measurements at over 30 locations examined areas where smoking was restricted, where smoking was permitted, and where an air handler shared the load of a designated smoking area. These measurements were taken at the same locations before and after the policy was Implemented.

The measurement results Indicated that: ? After the policy was implemented, general employee exposure to nicotine vapor (as a surrogate for all environmental tobacco smoke) was reduced by about 98 percent on most floors. Other patterns related to spillover from designated smoking areas and changes in the designated smoking areas themselves are described in the paper.

? Substantial reductions in exposure to nicotine vapor were found even for those general office areas which had the highest concentrations after the policy was implemented.