Carbon isotope fractionation during reductive dechlorination of TCE in batch experiments with iron samples from reactive barriers

Reductive dechlorination of trichloroethene (TCE) by zero-valent iron produces a systematic enrichment of 13C in the remaining substrate that can be described using a Rayleigh model. In this study, fractionation factors for TCE dechlorination with iron samples from two permeable reactive barriers (PRBs) were established in batch experiments. Samples included original unused iron as well as material from a barrier in Belfast after almost 4 years of operation. Despite the variety of samples, carbon isotope fractionations of TCE were remarkably similar and seemed to be independent of iron origin, reaction rate, and formation of precipitates on the iron surfaces. The average enrichment factor for all experiments was -10.1 per thousand (+/- 0.4 per thousand). These results indicate that the enrichment factor provides a powerful tool to monitor the reaction progress, and thus the performance, of an iron-reactive barrier over time. The strong fractionation observed may also serve as a tool to distinguish between insufficient residence time in the wall and a possible bypassing of the wall by the plume, which should result in an unchanged isotopic signature of the TCE. Although further work is necessary to apply this stable isotope method in the field, it has potential to serve as a unique monitoring tool for PRBs based on zero-valent iron.     

Climate change adaptation at different levels of government: Characteristics and conditions of policy change

Climate change adaptation strategies that aim to minimize harm and maximize benefits related to climate change impacts have mushroomed at all levels of government in recent years. While many studies have explored barriers that stand in the way of their implementation, the factors determining their potential to mainstream adaptation into various sectors are less clear. In the present paper, we aim to address this gap for two international, six national, and six local adaptation strategies. Based on document analyses and 35 semi‐structured interviews, the 14 case studies also explore in how far the factors facilitating climate change adaptation are similar across levels of government or level‐specific. Although located at three different levels of government, we find that the 14 adaptation strategies analyzed here represent “one‐size‐fits‐all governance arrangements” that are characterized by voluntariness and a lack institutionalization. Since adaptation strategies are relatively weak coordination hubs that are unable to force adaptation onto sectoral policy agendas, they rely mainly on sectoral self‐interest in adapting to climate change, largely determined by problem pressure. We conclude that one‐size‐fits‐all governance arrangements are rarely adequate responses to complex challenges, such as climate change. Although climate change adaptation depends more on framework conditions such as problem pressure than on administrative or governance features, the findings presented here can help to understand under what circumstances adaptation is likely to make progress.     

Synthesis of the DDT metabolite 2,4-dichloro-1-[2-chloro-1-(4-chlorophenyl)ethenyl]benzene (o-Cl-DDMU) and its detection in abiotic and biotic samples

Environmental Science and Pollution Research - Technical dichlorodiphenyltrichloroethane (DDT) has been used worldwide as a pesticide since the beginning of the 1940s. Due to its persistence, DDT...     

Recalculating GHG emissions saving of palm oil biodiesel

In 2010, the Renewable Energy Directive (RED) came into force in the EU and establishes a framework for achieving legally binding greenhouse gas (GHG) emission reductions. Only sustainable biofuels can be counted towards Member State targets. The aim of this paper is to calculate realistic and transparent scenario-based CO₂-emission values for the GHG emissions savings of palm oil fuel compared with fossil fuel. Using the calculation scheme proposed by the RED, we derive a more realistic overall GHG emissions saving value for palm oil diesel by using current input and output data of biofuel production (e.g. in South-East Asia). We calculate different scenarios in which reliable data on the production conditions (and the regarding emission values during the production chain) of palm oil diesel are used. Our results indicate values for the GHG emissions savings potential of palm oil biodiesel not only above the 19 % default and 36 % typical value published in RED but also above the 35 % sustainable threshold. Our findings conclude the more accurate GHG emissions saving value for palm oil feedstock for electricity generation to be 52 %, and for transportation biodiesel between 38.5 and 41 %, depending on the fossil fuel comparator. Our results confirm the findings by other studies and challenge the official typical and default values published in RED. As a result, the reliability of the Directive to support the EU’s low-carbon ambitions is being undermined, exposing the EU and commission to charges of trade discrimination and limiting the ability of Member States to achieve their legally binding GHG emission reductions.     

Predators have large effects on ecosystem properties by changing plant diversity, not plant biomass

Cascading effects of predators on total plant trophic-level biomass tend to be weaker in terrestrial than in aquatic systems. Accordingly, it is hypothesized that top predator effects on terrestrial plant diversity and on ecosystem function should likewise be weak or unimportant. This report presents a test of this hypothesis using data from a long-term field experiment. The five-year experiment manipulated the trophic structure of an old field ecosystem by excluding either predators or predators and herbivores relative to an unmanipulated, natural control. Long-term manipulations led to systematic treatment effects on community properties (plant trophic-level biomass, plant species biomass, plant species evenness) and on ecosystem properties (supply rate of solar radiation, N mineralization rate). The strengths of top predator effects on community properties were modest compared with nonterrestrial systems. But, predator-caused changes in plant community structure via alteration of plant dominance, and hence plant species evenness, strengthened effects on ecosystem properties. Counter to the hypothesis, weak trophic cascades do not necessarily lead to weak indirect effects of predators on ecosystem properties.     

Isotopic signature of atmospheric xenon released from light water reactors

A global monitoring system for atmospheric xenon radioactivity is being established as part of the International Monitoring System to verify compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The isotopic activity ratios of (135)Xe, (133m)Xe, (133)Xe and (131m)Xe are of interest for distinguishing nuclear explosion sources from civilian releases. Simulations of light water reactor (LWR) fuel burn-up through three operational reactor power cycles are conducted to explore the possible xenon isotopic signature of nuclear reactor releases under different operational conditions. It is studied how ratio changes are related to various parameters including the neutron flux, uranium enrichment and fuel burn-up. Further, the impact of diffusion and mixing on the isotopic activity ratio variability are explored. The simulations are validated with reported reactor emissions. In addition, activity ratios are calculated for xenon isotopes released from nuclear explosions and these are compared to the reactor ratios in order to determine whether the discrimination of explosion releases from reactor effluents is possible based on isotopic activity ratios.