Degradation of pet copolyesters under real and laboratory composting conditions

Journal of Material Cycles and Waste Management - The present work is aimed on the study of degradation of poly(ethylene terephthalate-co-lactate) copolyesters, prepared by chemical modification of...     

Valorization of titanium metal wastes as tanning agent used in leather industry

The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromium salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77 °C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning.     

Increasing the effectiveness of environmental decision support systems: lessons from climate change adaptation projects in Canada and Australia

Regional Environmental Change - There is a need to increase regional and community level action towards adaptation to climate change. Natural resource managers and planners have to make challenging...     

Evolving human landscapes: a virtual laboratory approach

ABSTRACT

Different human societies shape landscapes differently. Anthroecology theory explains this long-term differential shaping of landscapes as the product of sociocultural niche construction (SNC): an evolutionary theory coupling social change with ecosystem engineering. The evolutionary mechanisms underpinning this theory cannot be tested without experimental approaches capable of reproducing emergent selection processes acting on the combined suite of cultural, material, and ecological inheritances that determine the adaptive fitness of human individuals, groups, and societies. Agent-based modeling, as a ‘generative social science’ tool, appears ideal for this. Here we propose an agent-based virtual laboratory (ABVL) approach to generating and testing basic hypotheses on SNC as a general mechanism capable of producing the broadly varied anthroecological forms and dynamics of human landscapes from prehistory to present. While major challenges must still be overcome, a prospective modeling framework specification, guiding questions, and illustrative examples demonstrate clear potential for an ABVL to test predictions of anthroecology theory through generative social simulation.     

Chemical contamination of soils in the New York City area following Hurricane Sandy

This paper presents a unique data set of lead, arsenic, polychlorinated biphenyl (PCB), and polycyclic aromatic hydrocarbon (PAH) concentrations in soil samples collected from the metropolitan New York City area in the aftermath of Hurricane Sandy. Initial samples were collected by citizen scientists recruited via social media, a relatively unusual approach for a sample collection project. Participants in the affected areas collected 63 usable samples from basements, gardens, roads, and beaches. Results indicate high levels of arsenic, lead, PCBs, and PAHs in an area approximately 800 feet south of the United States Environmental Protection Agency (US EPA) Superfund site at Newtown Creek. A location adjacent to the Gowanus Canal, another Superfund site, was found to have high PCB concentrations. Areas of high PAH contamination tended to be near high traffic areas or next to sites of known contamination. While contamination as a direct result of Hurricane Sandy cannot be demonstrated conclusively, the presence of high levels of contamination close to known contamination sites, evidence for co-contamination, and decrease in number of samples containing measureable amounts of semi-volatile compounds from samples collected at similar locations 9 months after the storm suggest that contaminated particles may have migrated to residential areas as a result of flooding.     

Regional analysis of climate, primary production, and livestock density in inner Mongolia

Overstocking is believed to be one of the principal causes for grassland degradation in northern China. For this reason, quantification of overstocking and spatiotemporal analysis are needed for this area. In this study, the relationship between annual rainfall and grassland aboveground net primary production (ANPP) was analyzed using data from 1982 to 1991 in the Inner Mongolia Autonomous Region (IMAR), China. Subsequently, rainfall-based livestock carrying capacity was estimated and combined with livestock density calculated from county-level livestock data from 1982 to 1991 to determine spatial and temporal patterns of a stocking rate index and its relationship with climatic factors. The results indicate the following. First, there was a significant linear relationship between annual rainfall and ANPP in IMAR and the slope of ANPP versus rainfall was greater than those found in South America and Africa, indicating higher rain-use efficiency. Second, temporally averaged livestock density showed overstocking in most of the rural counties except for those in the cold north, where human populations are low and transportation systems are poor. Third, the stocking rate index increased with temperature, from less than 1.0 in the north, to greater than 2.0 in most of the southern IMAR. Within the central IMAR, the index increased from west to east, along the gradient of increasing rainfall. Fourth, long-term dynamics of livestock density depicted continuous overstocking, more than 20%, from 1982 to 1991 along the western part of the NorthEast China Transect (NECT) within IMAR. Spatial planning of livestock densities according to carrying capacities and improved pastoral management are needed in this area.     

An ecosystem approach to population management of ungulates

Harvest objectives for wild ungulates have traditionally been based on population models that do not consider ecosystem effects of ungulate herbivory, nor interactions between native and domestic ungulate species. There is a need for ecosystem models to allow wildlife managers to evaluate potential ecosystem effects of management scenarios. The utility of the SAVANNA simulation model for estimating elk population objectives within an ecosystem context was demonstrated for North Park, Colorado, USA. Effects of different elk population levels were evaluated for range condition, elk and cattle forage, elk and cattle condition, forage and condition of mule deer and moose, plant production, and plant community composition. Analyses were based on 30-year simulation runs using variable, historical weather. Another set of analyses utilized stochastic weather patterns. For management scenarios using the historical climate pattern, increasing elk populations caused biomass reductions of palatable plant species, particularly on areas of high winter density, where mean leaf biomass of palatable shrubs declined from 26.97 g/m2 at 0 elk to 20.82 g/m2 at 4000 elk (3.73 elk/km2), a 23% decline. At population levels of 5000 elk (4.68 elk/km2) or greater, elk body condition declined sharply following a severe winter. The availability of palatable browse on critical winter range was likely the limiting factor. However, when random climate patterns were simulated for the same scenarios, the threshold level for density-dependent effects varied with climate, ranging from 2000 to 10,000 elk. We suggest that elk population levels from 4000 to 5000 animals represent a conservative population objective for the North Park elk herd. Also, increasing elk population levels appears to intensify intraspecific competition among elk, far more than interspecific competition with cattle. Resolution of elk-cattle conflicts is likely to be facilitated by managing elk distribution, rather than overall elk population levels.     

HERBICIDES AND DEGRADATES IN SHALLOW AQUIFERS OF ILLINOIS: SPATIAL AND TEMPORAL TRENDS1

ABSTRACT: During the fall of 2000, the occurrence was examined of 16 herbicides and 13 herbicide degradates in samples from 55 wells in shallow aquifers underlying grain producing regions of Illinois. Herbicide compounds with concentrations above 0.05 μg/L were detected in 56 percent of the samples. No concentrations exceeded regulatory drinking water standards. The six most frequently detected compounds were degradates. Water age was an important factor in determining vulnerability of ground water to transport of herbicide compounds. Unconsolidated aquifers, which were indicated to generally contain younger ground water than bedrock aquifers, had a higher occurrence of herbicides (73 percent of samples) than bedrock aquifers (22 percent). Temporal analysis to determine if changes in concentrations of selected herbicides and degradates could be observed over a near decadal period indicated a decrease in detection frequency (25 to 18 percent) between samplings in 1991 and 2000. Over this period, significant differences in concentrations were observed for atrazine (decrease) and total acetochlor (increase). The increase in acetochlor compound concentrations corresponds to an increase in acetochlor use during the study period, while the decrease in atrazine concentrations corresponds to relatively consistent use of atrazine. Changes in frequency of herbicide detection and concentration do not appear related to changes in land use near sampled wells.     

A method to compare groundwater cleanup technologies

DuPont has developed a method to compare, on a consistent economic basis, in situ remediation technologies. The methodology employs a template site with a perchloroethylene plume 1000 ft long by 400 ft wide, and incorporates various aquifer thicknesses and depths. Variables considered in the methodology include duration of the remediation; estimated engineering and flow/transport modeling costs; equipment costs; and operation, maintenance, and monitoring costs. In this article, substrate-enhanced anaerobic bioremediation, intrinsic bioremediation, in situ permeable reactive barriers, and pump-and-treat systems are evalutated. Cost metrics include present cost, cost per pound of contaminant removed, and cost per 1000 gals treated, using a discounted cash-flow analysis. Costs of the remedial alternatives increase starting from intrinsic bioremediation, to substrate-enhanced anaerobic bioremediation, to a biological substrate-enhanced anaerobic barrier, to in situ permeable reactive barriers, to pump-and-treat systems with air stripping and carbon adsorption.     

Neurophysiological alterations due to diesel exhaust exposure during the neonatal life of the rat

This study was designed to assess the effects of diesel exhaust on the development of the nervous system in rats as measured by somatosensory and visual evoked potentials (SEPs and VEPs, respectively). SEPs, elicited by 1 mamp, 0.5 msec pulses delivered to the tibial nerve at the tibale, were recorded from the skull overlying the somatosensory projection area on days 28, 35, 42, and 49 postconception (pc). Analysis of the data for day 35 pc double pulse SEPs revealed significantly longer latencies for all peaks of the SEP in pups exposed to diesel exhaust. There were also differences indicating that the electrophysiological recoverability of the nervous system had been compromised in the diesel exhaust exposed group. On day 35 pc, the latencies of all VEP peaks occurring before 300 msec were greater in the exposed group. The differences, however, reached statistical significance only for the P2 peak of the response to the first of the paired stimuli. These data support the hypothesis that diesel exhaust influences the development of the nervous system.