Solvent-free sampling with di-n-butylamine for monitoring of isocyanates in air

The solvent-free sampler for airborne isocyanates consisted of a polypropylene tube with an inner wall coated with a glass fibre filter, coupled in series with a 13 mm glass fibre filter. The filters were impregnated with reagent solution containing equimolar amounts of di-n-butylamine (DBA) and acetic acid. Air sampling was performed with an air flow of 0.2 l min(-1). The formed isocyanate-DBA derivatives were determined using liquid chromatography and tandem mass spectrometry. The sampler was investigated in regard to collection principle and extraction of the formed derivatives with good results. The possibility to store the sampler before sampling and to perform long-term sampling was demonstrated. Field extraction of the sampler was not necessary, as there was no difference between immediately extracted samples and stored ones (2 days). In comparative studies, the sampler was evaluated against a reference method, impinger-filter sampling with DBA as reagent. The ratios between the results obtained with the sampler and the reference in a test chamber at a relative humidity (RH) of 45% was in the range of 83-109% for isocyanates formed during thermal decomposition of PUR. At RH 95%, the range was 72-101% with the exception of isocyanic acid. In two field evaluations, the ratios for fast curing 2,4'- and 4,4'-methylene bisphenyl diisocyanate (MDI) was in the range 81-113% and for the 3-ring MDI the range was 54-70%. For the slower curing 1,6-hexamethylene diisocyanate (HDI) and HDI isocyanurate, the ratios were in the range 78-145%. In conclusion, the solvent-free sampler is a convenient alternative in most applications to the more cumbersome impinger-filter sampler.     

Soils Characteristics of The Bassendean and Spearwood Sands of the Gnangara Mound (Western Australia) and their Controls On Recharge, Water Level Patterns and Solutes of The Superficial Aquifer

The flow pathways of water in the soils of the Gnangara Mound are highly irregular and depend upon the moisture content, the repellency and preferential wettability potential of the soils. The occurrence of preferential flow is more evident in dry soils. As the soil wets during the rainy season, the water repellence and differential wettability decreases, the fingering and the preferential flow paths disappear. Most of the agricultural sites in the Spearwood Sands which showed more irregular flow than the Bassendean Sands are under continuous irrigation during cultivation season. As the repellency problems are chemically treated, it is therefore expected that the flow will be more uniform all the year round. Landuse is mainly responsible for variation in recharge rates; however, the hydraulic properties control aquifer response and water level pattern to a greater degree. Water levels in the mid 1970s were in a semi steady state. Since that time, a combination of increasing water use by pine plantations, heavy pumping from private boreholes in market gardens and private homes and intensive pumping from the Gnangara Mound for the metropolitan water supply have caused water levels to continually decline in the Superficial aquifer. Nitrate and phosphate concentrations in the regional Superficial aquifer are generally very low. None of the tested pesticides (atrazine, diazinon, dimethoate, endosulfan, fenamiphos, iprodione, malathion and chlorpyrifos) were detected in the groundwater samples collected from the monitoring bores.     

Integration of the Pesticide Impact Rating Index with a Geographic Information System for the Assessment of Pesticide Impact on Water Quality

The pesticide impact rating index (PIRI) has been integrated with a Geographic Information System (GIS) to enable regional assessment of pesticide impact on groundwater and surface water resources. The GIS version of PIRI (PIRI-GIS) was used to assess the impact of pre-planting atrazine use in the pine plantations on the Gnangara Mound, Western Australia. The impact on groundwater was found to be spatially variable, mainly dependent on soil type and depth to groundwater, because land use variables were spatially constant. Areas with the greatest impact on groundwater were those where the soil had a low sorption capacity for atrazine. Knowledge of the spatial distribution of the sorption coefficient based on organic carbon (K _oc) for atrazine was found to significantly improve the results from PIRI-GIS. Average values for K _oc (i.e. based on overseas data) were too low for most of the local soil types, resulting in a general overestimation of pesticide impact on groundwater resources, but an underestimation of impact in areas that should be of greatest concern (i.e. where the soil has a low sorption capacity for atrazine).     

CURVE NUMBER HYDROLOGY IN WATER QUALITY MODELING: USES,ABUSES, AND FUTURE DIRECTIONS1

ABSTRACT: Although the curve number method of the Natural Resources Conservation Service has been used as the foundation of the hydrology algorithms in many nonpoint source water quality models, there are significant problematic issues with the way it has been implemented and interpreted that are not generally recognized. This usage is based on misconceptions about the meaning of the runoff value that the method computes, which is a likely fundamental cause of uncertainty in subsequent erosion and pollutant loading predictions dependent on this value. As a result, there are some major limitations on the conclusions and decisions about the effects of management practices on water quality that can be supported with current nonpoint source water quality models. They also cannot supply the detailed quantitative and spatial information needed to address emerging issues. A key prerequisite for improving model predictions is to improve the hydrologic algorithms contained within them. The use of the curve number method is still appropriate for flood hydrograph engineering applications, but more physically based algorithms that simulate all streamflow generating processes are needed for nonpoint source water quality modeling. Spatially distributed hydrologic modeling has tremendous potential in achieving this goal.     

Manure collection and distribution on Wisconsin dairy farms

Manure management plans require knowing the amount of manure produced, collected, and available for land-spreading. Whereas much information is available to calculate manure production, little is known about the types and amounts of manure actually collected on typical dairy farms. This study of 54 representative Wisconsin dairy farms showed significant regional, housing, and herd size differences in collection of manure from lactating cows (Bos taurus), dry cows, and heifers. Significantly (P < 0.05) less manure is collected in the hilly southwest (56% of total annual herd production) than in the undulating south central (72%) or the flat northeast (68%) regions. Collection of lactating cow manure is significantly (P < 0.05) lower from stanchion (66% of total annual production) than free-stall (89%) housing, and significant (P < 0.05) positive relationships were found between the number of lactating cows a farm keeps and the percentage manure collected. Average annual manure N (range of 116-846 kg N ha(-1)) and P (range of 24-158 kg P ha(-1)) loading rates in areas where manure goes uncollected was highest in unvegetated barnyards followed by vegetated and partially vegetated outside areas. Once uncollected manure was accounted for, average annual loading rates on cereal cropland ranged from 128 to 337 kg ha(-1) of manure N, and from 45 to 139 kg ha(-1) of manure P. Compared with adjacent cropland, the accumulation of uncollected manure has vastly increased soil test P, K, and organic matter levels in outside areas. Manure management on Wisconsin dairy farms with small to medium herds might require assistance in managing manure in outside confinement areas to reduce the risk of impairing surface and ground water quality.     

Workers' involvement--a missing component in the implementation of occupational safety and health management systems in enterprises.

Effective implementation of occupational safety and health (OSH) legislation based on European Union directives requires promotion of OSH management systems (OSH MS). To this end, voluntary Polish standards (PN-N-18000) have been adopted, setting forth OSH MS specifications and guidelines. However, the number of enterprises implementing OSH MS has increased slowly, falling short of expectations, which call for a new national policy on OSH MS promotion. To develop a national policy in this area, a survey was conducted in 40 enterprises with OSH MS in place. The survey was aimed at identifying motivational factors underlying OSH MS implementation decisions. Specifically, workers' and their representatives' involvement in OSH MS implementation was investigated. The results showed that the level of workers' involvement was relatively low, which may result in a low effectiveness of those systems. The same result also applies to the involvement of workers' representatives and that of trade unions.     

FECAL COLIFORM SOURCE ASSESSMENT IN A SMALL,MIXED LAND USE WATERSHED1

ABSTRACT: This study presents the results of fecal coliform (FC) sampling in the Rawls Creek, South Carolina, watershed during 1999 and 2000. The work was undertaken because the watershed is listed on the 303(d) list for South Carolina due to FC excursions. The watershed is 43.8 percent residential, 35 percent forest, 5.7 percent mixed urban, 4.9 percent commercial, and 4.8 percent agriculture. Samples were taken at 15 stations during eight field trips divided into two phases to characterize FC inputs from subbasins and to integrate results from upstream sampling. FC concentrations ranged from 135 to 730 colonies/100 ml. Results suggest that retention ponds in the area are a significant factor in attenuation of FC concentrations. Catchments with the largest contiguous impervious areas are the greatest source of FC. The highest concentrations of FC were observed at stations just downstream from a large detention basin that intercepts storm runoff from a large commercial area. Further analysis of the design and performance of that structure is suggested. The Koon Branch tributary is less than 20 percent of the land area in the watershed but may contribute 40 percent of the fecal loading. The results of this study confirm the importance of site assessments to aid understanding of nonpoint source pollution in complex watersheds.     

INTEGRATING LANDSCAPE ASSESSMENT AND HYDROLOGIC MODELING FOR LAND COVER CHANGE ANALYSIS1

ABSTRACT: Significant land cover changes have occurred in the watersheds that contribute runoff to the upper San Pedro River in Sonora, Mexico, and southeast Arizona. These changes, observed using a series of remotely sensed images taken in the 1970s, 1980s, and 1990s, have been implicated in the alteration of the basin hydrologic response. The Cannonsville subwatershed, located in the Catskill/Delaware watershed complex that delivers water to New York City, provides a contrast in land cover change. In this region, the Cannonsville watershed condition has improved over a comparable time period. A landscape assessment tool using a geographic information system (GIS) has been developed that automates the parameterization of the Soil and Water Assessment Tool (SWAT) and KINEmatic Runoff and EROSion (KINEROS) hydrologic models. The Automated Geospatial Watershed Assessment (AGWA) tool was used to prepare parameter input files for the Upper San Pedro Basin, a subwatershed within the San Pedro undergoing significant changes, and the Cannonsville watershed using historical land cover data. Runoff and sediment yield were simulated using these models. In the Cannonsville watershed, land cover change had a beneficial impact on modeled watershed response due to the transition from agriculture to forest land cover. Simulation results for the San Pedro indicate that increasing urban and agricultural areas and the simultaneous invasion of woody plants and decline of grasslands resulted in increased annual and event runoff volumes, flashier flood response, and decreased water quality due to sediment loading. These results demonstrate the usefulness of integrating remote sensing and distributed hydrologic models through the use of GIS for assessing watershed condition and the relative impacts of land cover transitions on hydrologic response.     

Another look at the locus of control–organizational commitment relationship: it depends on the form of commitment

Previous studies imply that individuals with an external locus of control (LOC) are less likely to be committed to their organizations. More recent work on organizational commitment has suggested that commitment is not a unidimensional construct and can take several forms (e.g., affective and continuance). Using a sample of 232 employees of a Canadian governmental agency, we examined the relations between LOC and two different forms of organizational commitment that have been found to have different antecedents and consequences. We found that internal LOC was associated with affective commitment and external LOC was associated with continuance commitment. Implications for research and practice are discussed. Copyright © 1999 John Wiley & Sons, Ltd.