全文获取类型
收费全文 | 29050篇 |
免费 | 278篇 |
国内免费 | 184篇 |
专业分类
安全科学 | 633篇 |
废物处理 | 1549篇 |
环保管理 | 4078篇 |
综合类 | 3889篇 |
基础理论 | 8395篇 |
环境理论 | 12篇 |
污染及防治 | 6562篇 |
评价与监测 | 2281篇 |
社会与环境 | 1966篇 |
灾害及防治 | 147篇 |
出版年
2023年 | 106篇 |
2022年 | 176篇 |
2021年 | 156篇 |
2020年 | 157篇 |
2019年 | 171篇 |
2018年 | 1687篇 |
2017年 | 1641篇 |
2016年 | 1600篇 |
2015年 | 487篇 |
2014年 | 612篇 |
2013年 | 1573篇 |
2012年 | 1123篇 |
2011年 | 2183篇 |
2010年 | 1426篇 |
2009年 | 1341篇 |
2008年 | 1705篇 |
2007年 | 2063篇 |
2006年 | 806篇 |
2005年 | 719篇 |
2004年 | 725篇 |
2003年 | 709篇 |
2002年 | 716篇 |
2001年 | 743篇 |
2000年 | 575篇 |
1999年 | 328篇 |
1998年 | 248篇 |
1997年 | 262篇 |
1996年 | 267篇 |
1995年 | 307篇 |
1994年 | 304篇 |
1993年 | 247篇 |
1992年 | 249篇 |
1991年 | 225篇 |
1990年 | 237篇 |
1989年 | 225篇 |
1988年 | 182篇 |
1987年 | 202篇 |
1986年 | 190篇 |
1985年 | 196篇 |
1984年 | 206篇 |
1983年 | 195篇 |
1982年 | 179篇 |
1981年 | 162篇 |
1980年 | 145篇 |
1979年 | 143篇 |
1978年 | 128篇 |
1977年 | 128篇 |
1976年 | 95篇 |
1974年 | 94篇 |
1973年 | 98篇 |
排序方式: 共有10000条查询结果,搜索用时 234 毫秒
611.
Since 2005, a dramatic decline of the Arctic sea-ice extent is observed which results in an increase of shipping activities. Even though this provides commercial and social development opportunities, the resulting environmental impacts need to be investigated and monitored. In order to understand the impact of shipping in arctic areas, the method described in this paper determines the travel time, fuel consumption and resulting exhaust emissions of ships navigating in arctic waters. The investigated case studies are considering ship particulars as well as environmental conditions with special focus on ice scenarios. Travel time, fuel consumption and exhaust gas emission were investigated for three different vessels, using different passages of the Northern Sea Route (NSR) in different seasons of years 1960, 2000 and 2040. The presented results show the sensitivity of vessel performance and amount of exhaust emissions to optimize arctic traffic with respect to efficiency, safety and environmental impact. 相似文献
612.
Natija Barhoumi Nihal Oturan Salah Ammar Abdellatif Gadri Mehmet A. Oturan Enric Brillas 《Environmental Chemistry Letters》2017,15(4):689-693
There is actually increasing concern about the accumulation of antibiotics, such as tetracycline, in soil and water bodies. There is therefore a need for efficient methods to degrade antibiotics and thus clean waters. Here we tested the degradation of tetracycline using the heterogeneous electro-Fenton-pyrite method and compared the results with the conventional electro-Fenton method. The reaction was performed with a boron-doped diamond or Pt anode and carbon-felt cathode allowing electrogeneration of H2O2 from O2 reduction. Results show an increasing tetracycline mineralization using the following methods: anodic oxidation with electrogenerated H2O2, electro-Fenton and then electro-Fenton-pyrite using boron-doped diamond. Ion-exclusion HPLC revealed the complete removal of malic malonic, succinic, acetic, oxalic and oxamic acids. Nitrogen present in tetracycline was mainly mineralized in NH4 +. The higher efficiency of electro-Fenton-pyrite is explained by self-regulation of soluble Fe2+ and pH to 3.0 from pyrite catalyst favoring larger ·OH generation from Fenton’s reaction. 相似文献
613.
Neslihan Akdeniz Jacek A. Koziel Hee-Kwon Ahn Thomas D. Glanville Benjamin P. Crawford 《Waste management (New York, N.Y.)》2010,30(10):1981-1988
Emergency mortality composting associated with a disease outbreak has special requirements to reduce the risks of pathogen survival and disease transmission. The most important requirements are to cover mortalities with biosecure barriers and avoid turning compost piles until the pathogens are inactivated. Temperature is the most commonly used parameter for assessing success of a biosecure composting process, but a decline in compost core temperature does not necessarily signify completion of the degradation process. In this study, gas concentrations of volatile organic compounds (VOCs) produced inside biosecure swine mortality composting units filled with six different cover/plant materials were monitored to test the state and completion of the process. Among the 55 compounds identified, dimethyl disulfide, dimethyl trisulfide, and pyrimidine were found to be marker compounds of the process. Temperature at the end of eight weeks was not found as an indicator of swine carcass degradation. However, gas concentrations of the marker compounds at the end of eight weeks were found to be related to carcass degradation. The highest gas concentrations of the marker compounds were measured for the test units with the lowest degradation (highest respiration rates). Dimethyl disulfide was found to be the most robust marker compound as it was detected from all composting units in the eighth week of the trial. Concentration of dimethyl disulfide decreased from a range of 290–4340 ppmv to 6–160 ppbv. Dimethyl trisulfide concentrations decreased to a range of below detection limit to 430 ppbv while pyrimidine concentrations decreased to a range of below detection limit to 13 ppbv. 相似文献
614.
Migratory species with a broad geographic range, such as north-east Atlantic mackerel, may be amongst the fauna most able to respond to warming seas, typically with a poleward shift in range. Habitat heterogeneity could, however, produce more complex patterns than a simple polewards translation in distribution. We tested for changes in the central location and spatial spread of mackerel spawning over a 33-year period. Spatial statistics [centre of gravity (CoG) of egg production, spatial variance, and degree of anisotropy] were used to summarise interannual changes in the spawning locations of the western spawning stock of north-east Atlantic mackerel (NEA-WSC) using data from the ICES triennial egg survey. A northwards shift in CoG of egg production estimates was observed, related to both an expansion in the distribution in survey effort and warming waters of the north-east Atlantic. Sea surface temperature (SST) had a significant positive association with the observed northward movement of NEA-WSC mackerel, equivalent to a displacement of 37.7 km °C?1 (based on spring mean SST for the region). The spatial distribution of spawning around the CoG also changed significantly with SST, with a less elongated spatial spread in warm years. An increase in the proportion of spawning over the Porcupine Bank demonstrated how habitat interacts with positional shifts to affect how north-east Atlantic mackerel are distributed around the centre of their spawning range. 相似文献
615.
Tatiana Calvete Eder C. Lima Natali F. Cardoso Júlio C.P. Vaghetti Silvio L.P. Dias Flavio A. Pavan 《Journal of environmental management》2010,91(8):1695-1706
Activated (AC-PW) and non-activated (C-PW) carbonaceous materials were prepared from the Brazilian-pine fruit shell (Araucaria angustifolia) and tested as adsorbents for the removal of reactive orange 16 dye (RO-16) from aqueous effluents. The effects of shaking time, adsorbent dosage and pH on the adsorption capacity were studied. RO-16 uptake was favorable at pH values ranging from 2.0 to 3.0 and from 2.0 to 7.0 for C-PW and AC-PW, respectively. The contact time required to obtain the equilibrium using C-PW and AC-PW as adsorbents was 5 and 4 h at 298 K, respectively. The fractionary-order kinetic model provided the best fit to experimental data compared with other models. Equilibrium data were better fit to the Sips isotherm model using C-PW and AC-PW as adsorbents. The enthalpy and entropy of adsorption of RO-16 were obtained from adsorption experiments ranging from 298 to 323 K. 相似文献
616.
Human impact on wild firewood species in the Rural Andes community of Apillapampa, Bolivia 总被引:1,自引:0,他引:1
Evert Thomas David Douterlungne Ina Vandebroek Frieke Heens Paul Goetghebeur Patrick Van Damme 《Environmental monitoring and assessment》2011,178(1-4):333-347
Firewood is the basic fuel source in rural Bolivia. A study was conducted in an Andean village of subsistence farmers to investigate human impact on wild firewood species. A total of 114 different fuel species was inventoried during fieldtrips and transect sampling. Specific data on abundance and growth height of wild firewood species were collected in thirty-six transects of 50 ×2 m2. Information on fuel uses of plants was obtained from 13 local Quechua key participants. To appraise the impact of fuel harvest, the extraction impact value (EIV) index was developed. This index takes into account local participants?? appreciation of (1) decreasing plant abundance; (2) regeneration capacity of plants; (3) impact of root harvesting; and (4) quality of firewood. Results suggest that several (sub-)woody plant species are negatively affected by firewood harvesting. We found that anthropogenic pressure, expressed as EIV, covaried with density of firewood species, which could entail higher human pressure on more abundant and/or more accessible species. The apparent negative impact of anthropogenic pressure on populations of wild fuel species is corroborated by our finding that, in addition to altitude, several anthropogenic variables (i.e. site accessibility, cultivation of exotics and burning practices) explain part of the variation in height of firewood species in the surroundings of Apillapampa. 相似文献
617.
Alamgir Hossain Jamal Naser Monzur Alam Imteaz 《Environmental Modeling and Assessment》2011,16(4):359-367
This paper presents comprehensive 3D numerical investigations on depositions of particles flowing through a horizontal pipe
loop consisting of four bends. The multiphase mixture model available in FLUENT 6.2 was used in this study. In this numerical
simulation, five different particle sizes have been used as secondary phases to calculate real multiphase effect in which
inter-particle interaction has been considered. The deposition of particles along the periphery of the pipe wall was investigated
as a function of particle size and fluid velocity. The simulations showed that near the upstream of the bends, maximum particle
concentration occurred at the bottom of the pipe. However, downstream the bends, the maximum particle concentration occurred
at an angle of 60° from the bottom. The larger particles clearly showed deposition near the bottom wall except downstream.
As expected, the smaller particles showed less tendency of deposition and lesser at higher velocity. This numerical investigation
showed qualitative agreement with the experiments conducted by Commonwealth Scientific and Industrial Research Organisation,
Melbourne team for similar conditions. 相似文献
618.
The composition and structure of tree stands near the timberline have been studied on different slopes and at different elevations
in the Tylaisko-Konzhakovsko-Serebryanskii Massif, the North Urals. It has been found that the upper limits of tree stands
with different degrees of canopy closure have risen considerably (by about 100 m of elevation) since the mid-19th century,
although the formation of these stands started as early as the late 18th century. Woodless areas in the eastern part of the
massif started to be colonized by Larix sibirica in the late 18th to early 19th centuries; those in the western part, by Picea obovata in the mid-19th century; and in the southern part, by Betula tortuosa in the late 19th century. Analysis of meteorological data provides evidence for warming and increasing humidity of the climate
since the late 19th century. Favorable climatic changes that facilitated the expansion of the forest have taken place both
in the summer (prolongation of the growing period) and in winter seasons (increase of air temperature and precipitation).
The observed differences in the composition and dynamics of tree stands between the studied areas of the mountain range are
most probably explained by different requirements of tree species for the depth of snow cover and the degree of soil freezing. 相似文献
619.
Konstantinos C. Makris Dibyendu Sarkar Jason Salazar Pravin Punamiya Rupali Datta 《Environmental science and pollution research international》2010,17(1):195-202
Background, aim, and scope
Alum (aluminum sulfate) is the currently preferred chemical amendment for phosphorus (P) treatment in poultry litter (PL). Aluminum-based drinking-water treatment residuals (Al-WTRs) are the waste by-product of the drinking-water treatment process and have been effectively used to remove P from aqueous solutions, but their effectiveness in PL water extracts has not been studied in detail. Elevated cost associated with alum could be minimized by using the equally effective WTRs to remove soluble P from PL, and they can be obtained at a minimal cost from drinking-water treatment plants. 相似文献620.