全文获取类型
收费全文 | 87篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 7篇 |
环保管理 | 2篇 |
综合类 | 11篇 |
基础理论 | 13篇 |
污染及防治 | 40篇 |
评价与监测 | 8篇 |
社会与环境 | 6篇 |
出版年
2023年 | 3篇 |
2022年 | 2篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 5篇 |
2011年 | 9篇 |
2010年 | 2篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 3篇 |
2006年 | 7篇 |
2005年 | 3篇 |
2003年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1970年 | 1篇 |
1965年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有90条查询结果,搜索用时 46 毫秒
31.
The formation and fate of chlorinated organic substances in temperate and boreal forest soils 总被引:1,自引:0,他引:1
Nicholas Clarke Květoslava Fuksová Milan Gryndler Zora Lachmanová Hans-Holger Liste Jana Rohlenová Reiner Schroll Peter Schröder Miroslav Matucha 《Environmental science and pollution research international》2009,16(2):127-143
Background, aim and scope Chlorine is an abundant element, commonly occurring in nature either as chloride ions or as chlorinated organic compounds
(OCls). Chlorinated organic substances were long considered purely anthropogenic products; however, they are, in addition,
a commonly occurring and important part of natural ecosystems. Formation of OCls may affect the degradation of soil organic
matter (SOM) and thus the carbon cycle with implications for the ability of forest soils to sequester carbon, whilst the occurrence
of potentially toxic OCls in groundwater aquifers is of concern with regard to water quality. It is thus important to understand
the biogeochemical cycle of chlorine, both inorganic and organic, to get information about the relevant processes in the forest
ecosystem and the effects on these from human activities, including forestry practices. A survey is given of processes in
the soil of temperate and boreal forests, predominantly in Europe, including the participation of chlorine, and gaps in knowledge
and the need for further work are discussed.
Results Chlorine is present as chloride ion and/or OCls in all compartments of temperate and boreal forest ecosystems. It contributes
to the degradation of SOM, thus also affecting carbon sequestration in the forest soil. The most important source of chloride
to coastal forest ecosystems is sea salt deposition, and volcanoes and coal burning can also be important sources. Locally,
de-icing salt can be an important chloride input near major roads. In addition, anthropogenic sources of OCls are manifold.
However, results also indicate the formation of chlorinated organics by microorganisms as an important source, together with
natural abiotic formation. In fact, the soil pool of OCls seems to be a result of the balance between chlorination and degradation
processes. Ecologically, organochlorines may function as antibiotics, signal substances and energy equivalents, in descending
order of significance. Forest management practices can affect the chlorine cycle, although little is at present known about
how.
Discussion The present data on the apparently considerable size of the pool of OCls indicate its importance for the functioning of the
forest soil system and its stability, but factors controlling their formation, degradation and transport are not clearly understood.
It would be useful to estimate the significance and rates of key processes to be able to judge the importance of OCls in SOM
and litter degradation. Effects of forest management processes affecting SOM and chloride deposition are likely to affect
OCls as well. Further standardisation and harmonisation of sampling and analytical procedures is necessary.
Conclusions and perspectives More work is necessary in order to understand and, if necessary, develop strategies for mitigating the environmental impact
of OCls in temperate and boreal forest soils. This includes both intensified research, especially to understand the key processes
of formation and degradation of chlorinated compounds, and monitoring of the substances in question in forest ecosystems.
It is also important to understand the effect of various forest management techniques on OCls, as management can be used to
produce desired effects. 相似文献
32.
Laturnus F Fahimi I Gryndler M Hartmann A Heal MR Matucha M Schöler HF Schroll R Svensson T 《Environmental science and pollution research international》2005,12(4):233-244
- DOI: http:/dx.doi.org/10.1065/espr2005.06.262
Goal, Scope and Background The anthropogenic environmental emissions of chloroacetic acids and volatile organochlorines have been under scrutiny in
recent years because the two compound groups are suspected to contribute to forest dieback and stratospheric ozone destruction,
respectively. The two organochlorine groups are linked because the atmospheric photochemical oxidation of some volatile organochlorine
compounds is one source of phytotoxic chloroacetic acids in the environment. Moreover, both groups are produced in higher
amounts by natural chlorination of organic matter, e.g. by soil microorganisms, marine macroalgae and salt lake bacteria,
and show similar metabolism pathways. Elucidating the origin and fate of these organohalogens is necessary to implement actions
to counteract environmental problems caused by these compounds.
Main Features While the anthropogenic sources of chloroacetic acids and volatile organochlorines are relatively well-known and within human
control, knowledge of relevant natural processes is scarce and fragmented. This article reviews current knowledge on natural
formation and degradation processes of chloroacetic acids and volatile organochlorines in forest soils, with particular emphasis
on processes in the rhizosphere, and discusses future studies necessary to understand the role of forest soils in the formation
and degradation of these compounds.
Results and Discussion Reviewing the present knowledge of the natural formation and degradation processes of chloroacetic acids and volatile organochlorines
in forest soil has revealed gaps in knowledge regarding the actual mechanisms behind these processes. In particular, there
remains insufficient quantification of reliable budgets and rates of formation and degradation of chloroacetic acids and volatile
organochlorines in forest soil (both biotic and abiotic processes) to evaluate the strength of forest ecosystems regarding
the emission and uptake of chloroacetic acids and volatile organochlorines, both on a regional scale and on a global scale.
Conclusion It is concluded that the overall role of forest soil as a source and/or sink for chloroacetic acids and volatile organochlorines
is still unclear; the available laboratory and field data reveal only bits of the puzzle. Detailed knowledge of the natural
degradation and formation processes in forest soil is important to evaluate the strength of forest ecosystems for the emission
and uptake of chloroacetic acids and volatile organochlorines, both on a regional scale and on a global scale.
Recommendation and Perspective As the natural formation and degradation processes of chloroacetic acids and volatile organochlorines in forest soil can
be influenced by human activities, evaluation of the extent of this influence will help to identify what future actions are
needed to reduce human influences and thus prevent further damage to the environment and to human health caused by these compounds. 相似文献
33.
34.
Matucha M Rohlenová J Forczek ST Uhlírová H Gryndler M Fuksová K Schröder P 《Chemosphere》2006,63(11):1924-1932
Radioisotopes carbon 14 and chlorine 36 were used to elucidate the environmental role of trichloroacetic acid (TCA) formerly taken to be a herbicide and a secondary air pollutant with phytotoxic effects. However, use of 14C-labeling posed again known analytical problems, especially in TCA extraction from the sample matrix. Therefore—after evaluation of available methods—a new procedure using decarboxylation of [1,2-14C]TCA combined with extraction of the resultant 14C-chloroform with a non-polar solvent and its subsequent radiometric measurement was developed. The method solves previous difficulties and permits an easy determination of amounts between 0.4 and 20 kBq (10–500 ng g−1) of carrier-less [1,2-14C]TCA in samples from environmental investigations. The procedure is, however, not suitable for direct [36Cl]TCA determination in chlorination studies with 36Cl. Because TCA might be microbially degraded in soil during extraction and sample storage and its extraction from soil or needles is never complete, the decarboxylation method—i.e. 2 h TCA decomposition to chloroform and CO2 in aqueous solution or suspension in closed vial at 90 °C and pH 4.6 with subsequent CHCl3 extraction—is recommended here, estimated V < 7%. Moreover, the influence of pH and temperature on the decarboxylation of TCA in aqueous solution was studied in a broad range and its environmental relevance is shown in the case of TCA decarboxylation in spruce needles which takes place also at ambient temperatures and might amount more than 10–20% after a growing season. A study of TCA distribution in spruce needles after below-ground uptake shows the highest uptake rate into current needles which have, however, a lower TCA content than older needle-year classes, TCA biodegradation in forest soil leads predominatingly to CO2. 相似文献
35.
Can choice of mutualistic partners and the degree of their utilization determine (1) mutualistic partner coexistence, (2) relative abundance of mutualistic partners, and (3) environment-dependent changes in relative abundance? We investigate these questions in the context of the plant-mycorrhizal fungal mutualism by building a biological market model potentially applicable to other mutualisms as well. We examine the situation where a single plant selectively utilizes member(s) of a group of ectomycorrhizal potential trading partners. Under biologically realistic circumstances, the plant may simultaneously utilize multiple partners, its degree of utilization determining the community structure of the fungi. If utilization of multiple partners is optimal, the marginal cost of acquiring additional nitrogen from every trading partner must be equal while the marginal cost of acquiring it from any unutilized partner must be larger. Because the plant's nitrogen demand is light dependent, the composition of the fungal species among its trading partners changes along light-availability gradients. We discuss the design of an experiment to test the key prediction of our model, the equalization of marginal cost. 相似文献
36.
Antić MP Jovancićević BS Ilić M Vrvić MM Schwarzbauer J 《Environmental science and pollution research international》2006,13(5):320-327
Background, Aims and Scope It is well known that the composition of petroleum or some of its processing products changes in the environment mostly under
the influence of microorganisms. A series of experiments was conducted in order to define the optimum conditions for an efficient
biodegradation of petroleum pollutant, or bioremediation of different segments of the environment. The aim of these investigations
was to show to what extent the hydrocarbons of a petroleum pollutant are degraded by microbial cultures which were isolated
as dominant microorganisms from a surface water of a wastewater canal of an oil refinery and a nitrogen plant. Biodegradation
experiments were conducted on one paraffinic, and one naphthenic type of petroleum during a three month period under aerobic
conditions, varying the following parameters: Inorganic (Kp) or an organic medium (Bh) with or without exposition to light.
Methods Microorganisms were analyzed in a surface water sample from a canal (Pančevo, Serbia), into which wastewater from an oil
refinery and a nitrogen plant is released. The consortia of microorganisms were isolated from the water sample (most abundant
species: Phormidium foveolarum - filamentous Cyanobacteria, blue-green algae and Achanthes minutissima, diatoms, algae). The
simulation experiments of biodegradation were conducted with the biomass suspension and crude oils Sirakovo (Sir, paraffinic
type) and Velebit (Ve, naphthenic type). After a three month period, organic substance was extracted by means of chloroform.
In the extracts, the content of saturated hydrocarbons, aromatic hydrocarbons, alcohols and fatty acids was determined (the
group composition). n-Alkanes and isoprenoid aliphatic alkanes, pristane and phytane, in the aliphatic fractions, were analyzed
using gas chromatography (GC). Total isoprenoid aliphatic alkanes and polycyclic alkanes of sterane and triterpane types were
analyzed by GC-MS.
Results and discussion. Paraffinic type petroleums have a significant loss of saturated hydrocarbons. For naphthenic type petroleum,
such a trend has not been observed. The most intensive degradation of n-alkanes and isoprenoid aliphatic alkanes (in paraffinic
oil) and isoprenoids (in naphthenic oil) was observed using the inorganic medium Kp in the light; the microbial conversion
is somewhat lower with Kp in the dark; with organic medium Bh in the light the degradation is of low intensity; with the same
medium in the dark the degradation is hardly to be seen. Steranes and triterpanes were not affected by microbial degradation
under the conditions used in our experiments. Obviously, the petroleum biodegradation was restricted to the acyclic aliphatics
(n-alkanes and isoprenoids).
Conclusion Phormidium foveolarum (filamentous Cyanobacteria - blue-green algae) and Achanthes minutissima (diatoms, algae), microbial
cultures isolated as dominant algae from a surface water in a wastewater canal of an oil refinery and a nitrogen plant, have
degradable effects dominantly involving petroleum hydocarbons. Petroleum microbiological degradation is more intensive when
inorganic medium (in the light) is applied. Having in mind that the inorganic pollutants have been released into the canal
as well, this medium reflects more the natural environmental conditions. Polycyclic alkanes of sterane and triterpane type,
in spite of the fact that these compounds could be degraded, have remained unchanged regarding abundance and distribution.
Since this is the case even for naphthenic type petroleum (which is depleted in n-alkanes), it can be concluded that the biodegradation
of petroleum type pollutants, under natural conditions, will be restrained to the n-alkane and isoprenoid degradation.
Recommendation and Outlook Performed experiments and simulations of petroleum microbiological degradation may serve for the prediction of the fate of
petroleum type pollutants, as well as for definition of conditions for bioremediation of some environmental segments. 相似文献
37.
Abstract The paper discusses the eutrophication phenomenon as a result of pollution from land-based sources with special reference to the experience gained in the Kas?tela Bay Project. The Bay of Kas?tela is a semi-enclosed bay of a total volume of 1.4 km3. It receives a great amount of untreated waste water, both domestic and industrial. Results of the analyses of long-term data series of dissolved oxygen, nutrients, transparency and phytoplankton have shown a continuous increase of eutrophication in the Bay. While the concentration of oxygen in the euphotic layer increases due to a higher phytoplankton productivity, in the bottom layer it decreases as a result of the activity of heterotrophic bacteria. the nitrogen/phosphorus ratio in sea water has decreased, and today is much lower than in the open sea. From the Secchi-disc data it is clear that transparency has also decreased for the last three decades. Primary production as well as phytoplankton biomass has also increased. the structure of phytoplankton community has been changed and dinoflagellate species have become dominant rather than diatoms. 相似文献
38.
39.
Klara Hilscherova Miroslav Machala Kurunthachalam Kannan Alan L. Blankenship John P. Giesy 《Environmental science and pollution research international》2000,7(3):159-171
In vitro cell bioassays are useful techniques for the determination of receptor-mediated activities in environmental samples containing complex mixtures of contaminants. The cell bioassays determine contamination by pollutants that act through specific modes of action. This article presents strategies for the evaluation of aryl hydrocarbon receptor (AhR)-(hereafter referred as dioxin-like) or estrogen receptor (ER)-mediated activities of potential endocrine disrupting compounds (EDCs) in complex environmental mixtures. Extracts from various types of environmental or food matrices can be tested by this technique to evaluate their 2,3,7,8-tetrachlorodibenzop-dioxin equivalents (TCDD-EQs) or estrogenic equivalents (E2-EQs) and to identify contaminated samples that need further investigation using resource-intensive instrumental analyses. Fractionation of sample extracts exhibiting significant activities, and subsequent reanalysis with the bioassays can identify important classes of contaminants that are responsible for the observed activity. Effect-directed chemical analysis is performed only for the active fractions to determine the responsible compounds. Mass-balance estimates of all major compounds contributing to the observed effects can be calculated to determine if all of the activity has been identified, and to assess the potential for interactions such as synergism or antagonism among contaminants present in the complex mixtures. The bioassay approach is an efficient (fast and cost effective) screening system to identify the samples of interest and to provide basic information for further analysis and risk evaluation. 相似文献
40.
Russo Fabiana Ceci Andrea Maggi Oriana Siciliano Antonietta Guida Marco Petrangeli Papini Marco Černík Miroslav Persiani Anna Maria 《Environmental science and pollution research international》2019,26(24):24445-24461
Environmental Science and Pollution Research - The study of the soil microbial community represents an important step in better understanding the environmental context. Therefore, biological... 相似文献