Multivariate statistical study of heavy metal enrichment in sediments of the Pearl River Estuary

The concentrations and chemical partitioning of heavy metals in the sediment cores of the Pearl River Estuary were studied. Based on Pearson correlation coefficients and principal component analysis results, Al was selected as the concentration normalizer for Pb, while Fe was used as the normalizing element for Co, Cu, Ni and Zn. In each profile, sections with metal concentrations exceeding the upper 95% prediction interval of the linear regression model were regarded as metal enrichment layers. The heavy metal accumulation mainly occurred at sites in the western shallow water areas and east channel, which reflected the hydraulic conditions and influence from riparian anthropogenic activities. Heavy metals in the enrichment sections were evaluated by a sequential extraction method for possible chemical forms in sediments. Since the residual, Fe/Mn oxides and organic/sulfide fractions were dominant geochemical phases in the enriched sections, the bioavailability of heavy metals in sediments was generally low. The 206Pb/207Pb ratios in the metal-enriched sediment sections also revealed the influence of anthropogenic sources. The spatial distribution of cumulative heavy metals in the sediments suggested that the Zn and Cu mainly originated from point sources, while the Pb probably came from non-point sources in the estuary.     

Garbage in garbage out: the contribution of our industrial advancement to wastewater degeneration

Environmental Science and Pollution Research - Natural water sources are habitually marred by insidious anthropogenic practices and municipal wastewater discharges that contain either of xenobiotic...     

Compassionate versus consequentialist conservation

Ethical treatment of wildlife and consideration of animal welfare have become important themes in conservation, but ethical perspectives on how best to protect wild animals and promote their welfare are diverse. There are advantages to the consequentialist harms ethical framework applied in managing wild herbivores for conservation purposes. To minimize harms while achieving conservation goals, we argue that overabundant wild herbivores should in many cases be managed through consumptive in situ killing. Advantages of this policy are that the negative welfare states imposed on animals last only a short time; remaining animals are not deprived of positive welfare states (e.g., linked to rearing offspring); poor welfare states of animals in overabundant populations are avoided (e.g., starvation); negative welfare impacts on heterospecifics through resource depletion (i.e., competition) are prevented; harvesting meat reduces the number of (agricultural) animals raised to supply meat; and minimal costs maximize funding for other wildlife management and conservation priorities. Alternative ethical approaches to our consequentialist framework include deontology (containing animal rights) and virtue ethics, some of which underpin compassionate conservation. These alternative ethical approaches emphasize the importance of avoiding intentional killing of animals but, if no population reduction occurs, are likely to impose considerable unintentional harms on overabundant wildlife and indirectly harm heterospecifics through ineffective population reduction. If nonlethal control is used, it is likely that overabundant animals would be deprived of positive welfare states and economic costs would be prohibitive. We encourage conservation stakeholders to consider animal-welfare consequentialism as an ethical approach to minimize harms to the animals under their care as well as other animals that policies may affect while at the same time pursuing conservation goals.     

Performance of a large-scale greenhouse solar dryer integrated with phase change material thermal storage system for drying of chili

ABSTRACT

Large-scale greenhouse solar dryers have been used for drying various products and this type of dryer is usually equipped with LPG burner as auxiliary heater, which creates more operating cost. To overcome this problem, phase change material (PCM) thermal storage was proposed to substitute for the LPG burner. In this work, the performance of a large-scale greenhouse solar dryer integrated with a PCM as a latent heat storage for drying of chili was investigated. Experimental studies were conducted to compare the performance of this dryer with that of another large-scale greenhouse solar dryer without the PCM thermal storage and open sun drying. Chili with an initial moisture content of 74.7% (w.b.) was dried to a final moisture content of 10.0% (w.b.) in 2.5 days, 3.5 days, and 11 days using the solar dryer integrated with the PCM thermal storage, the solar dryer without the PCM thermal storage and the open sun drying, respectively. The performance of the solar dryer integrated with the PCM thermal storage was also evaluated using exergy analysis. The exergy efficiency of the drying room of the solar dryer integrated with the PCM thermal storage and the solar dryer without the PCM thermal storage for drying of chili was found to be 13.1% and 11.4%, respectively and the thermal storage helps to dry chili during adverse weather conditions. The results of exergy analysis implied that the exergy losses from the dryer with the PCM should be reduced.     

Determination of suitable TPH remediation approach via MANOVA and inferential statistics assessment

Soil contamination resulting from petroleum hydrocarbon contaminants poses a fairly substantial hazard to human health and the environment. Phytoremediation, land farming, and chemico–biological stabilization were used to treat total petroleum hydrocarbons (TPHs) and polycyclic aromatic hydrocarbons (PAHs) at a crude oil polluted soil site in Nigeria. A field pilot study was conducted by preparing nine cells with subcells attached to each serving as a control with an overall area of 1.53 m². A complete block design method was used for the study. The prepared soil sample cells were divided into three groups with each group having approximately 300 kg of soil and delineated as low, medium, and high test plots. The low samples were spiked with 6.1 kg of crude oil, the medium samples were spiked with 12.2 kg of crudeoil, and the high samples were spiked with 18.3 kg of crude oil. Each row containing three cells with low, medium, and high concentrations were treated separately using the three treatment methods. The ratio of the soil sample to the organic amendment for the treatments was 2:1. The results showed over 90% degradation in the initial concentration of TPH and PAHs across different contaminant levels except in the control subcells where only 30% of degradation was recorded. Multivariate analysis of variance was employed to assess the significant difference in each treatment group while inferential statistics using a mean performance plot was used to ascertain the optimum treatment method. Land farming, chemico–biological stabilization, and phytoremediation ranked 1, 2, and 3, respectively. In conclusion, the three treatment methods employed all degraded the contaminants (TPH and PAHs) with land farming emerging as the best method.     

The fate of secondary metabolites in plants growing on Cd-, As-, and Pb-contaminated soils—a comprehensive review

Environmental Science and Pollution Research - The study used scattered literature to summarize the effects of excess Cd, As, and Pb from contaminated soils on plant secondary metabolites/bioactive...     

Process modeling of chemical looping combustion (CLC) of municipal solid waste

Journal of Material Cycles and Waste Management - Chemical Looping Combustion (CLC) of MSW could serve as a potential treatment method for the disposal of MSW and the recovery of energy because it...     

Ecological risks of phenolic endocrine disrupting compounds in an urban tropical river

Environmental Science and Pollution Research - The distribution of emerging organic contaminants in drinking water sources in Africa is a subject with very scanty data and information. In order to...     

Constructing regional scenarios for sustainable agriculture in European Russia and Ukraine for 2000 to 2070

This study estimates the consequences of climate change on cropland with and without implementation of adaptation measures, paying special attention to the maintenance of soil organic carbon (C) stocks. We examine the possibility for regional sustainable agricultural management practice that combines both maintenance and gain in soil carbon level with profit maximization. Future scenarios of Regional Agricultural Production Systems (RAPS) were constructed for 2000–2070 based on linking the effects of global climate change, predicted change in productivity parameters for the main agricultural crops, land-use and soil database parameters. The RAPS were used to examine profitability and feasibility of alternative agricultural scenarios, based on an economic model. A number of recommendations for decision making were proposed based on an assessment of the efficiency of adaptation in animal husbandry and in the crop production sector, after analysis of current percentage of perennial grass in rotation in comparison with future economic scenarios. Figures in color are available at     

Estimating the quantity of solid waste generation in Oyo, Nigeria.

The study established waste multipliers that could be used in conjunction with the population figure of a city to estimate the quantity of solid waste generation in the developing world. Oyo, a traditional city in Nigeria was the focus of the study. Two sets of data were collected. The first was the information on the socio-economic attributes of residents obtained from 648 households through questionnaires administered using a systematic random sampling technique. The second was the measurement of waste generated in 25% of the households for a week in each of the 12 months of the year. The study established that 23.3% of the residents surveyed have educational qualifications beyond secondary school, with 51.2% engaged in occupations requiring very little or no formal education and 50.9% were in the low-income group. The daily per capita solid waste generation was 0.129 kg. The highest (9.8%) and lowest (6.5%) of the annual quantities of waste were produced in October and February, respectively. Similarly, 20.2% of the weekly generation was produced on Saturday and the 10.2% produced on Thursday was the lowest. Animal dung, which accounted for 18.0%, constituted the highest component of the total solid waste generated. The study further established that the organic component of the waste generation was 75.4%. The results of the regression analysis R2 significant at 0.001 showed that income, household size, social status, occupation, education and season of the year explained 88.8% of waste generation in Oyo. It was established that 50.90 tonnes of solid waste was generated per day in the city in 2005, and the daily generation in the year 2008 is estimated to be 55.20 tonnes. The study concluded that with an average annual population growth of 13 000 people for the town, an additional 1.3 acres of land will need to be legally acquired annually, implying that 10.92-19.68 hectares ill be required as dump site(s) over the next 20-30 years.