Degradation of ethylene glycol using Fenton's reagent and UV

Oxidation of ethylene glycol in aqueous solutions was found to occur with the addition of Fenton's reagent with further conversion observed upon UV irradiation. The pH range studied was 2.5-9.0 with initial H2O2 concentrations ranging from 100 to 1000 mg/l. Application of this method to airport storm-water could potentially result in reduction of chemical oxygen demand by conversion of ethylene glycol to oxalic and formic acids. Although the amount of H2O2 added follows the amount of ethylene glycol degraded, smaller H2O2 doses were associated with increases in the ratio of ethylene glycol removed per unit H2O2 added indicating the potential of pulsed doses or constant H2O2 feed systems. Ethylene glycol removal was enhanced by exposure to UV light after treatment with Fenton's reagent, with rates dependent on initial H2O2 concentration. In addition to ethylene glycol, the principle products of this reaction, oxalic and formic acids, have been shown to be mineralized in other HO generating systems presenting the potential for ethylene glycol mineralization in this system with increased HO* production.     

A model and design equations for the intermittent sand filter

Design parameters based upon influent suspended (SS) and volatile suspended solids (VSS) concentrations and hydraulic loading rates were evaluated. Functional relationships and coefficients describing the efficiency of the ISF process were developed based upon laboratory data from filter units containing 0.17 mm effective sand size (ε′) media. Adequate SS and VSS removals were observed for the 0.17 mm ε′ sand filters. Field data from other studies using filter units containing 0.17, 0.40, and 0.68 mm ε′ sand were also evaluated using the model. Sand sizes larger than 0.17 mm ε′ did not produce effluents satisfying a federal secondary standard of 30 mg/1 of SS when the filter influent suspended solids were predominantly algae.