Effects of Roadway Crossings on Leaf Litter Processing and Invertebrate Assemblages in Small Streams

The effects of the Maine Turnpike (Interstate 95) on leaf litter processing were examined in five first- and second-order coastal plain streams in southern Maine, U.S.A. Invertebrate assemblages and red maple leaf softening and loss rates were compared at 53 stations arrayed upstream and downstream of the turnpike. Litter softening rate was not affected by the roadway. Litter loss rate was significantly faster at downstream stations (-0.0024 degree-day(-1)) than at upstream stations or at stations nearest the roadway, which were not different from each other (-0.0022 degree-day(-1)). Litter softening and loss rates were more strongly related to physical and chemical habitat variables than to shredder assemblage characteristics. Significant among-stream differences were observed in most community structural metrics and in biomass of important shredder taxa, but effects of the roadway were rarely consistent among streams. This is attributed in part to habitat variation, which was greater among streams than within streams. This study suggests that while the presence of the Maine Turnpike may influence stream water quality and habitat structure, the relatively subtle effects of roadway runoff and associated habitat modifications on stream ecosystem processes are masked by within- and among-stream variability in litter processing and leaf pack invertebrate assemblage structure.     

Chromium speciation and fractionation in ground and surface waters in the vicinity of chromite ore processing residue disposal sites

Chromium concentrations of up to 91 mg l(-1) were found by ICP-OES for ground water from nine boreholes at four landfill sites in an area of S.E. Glasgow/S. Lanarkshire where high-lime chromite ore processing residue (COPR) from a local chemical works had been deposited from 1830 to 1968. Surface water concentrations of up to 6.7 mg l(-1) in a local tributary stream fell to 0.11 mg l(-1) in the River Clyde. Two independent techniques of complexation/colorimetry and speciated isotope dilution mass spectrometry (SIDMS) showed that Cr was predominantly (>90%) in hexavalent form (CrVI) as CrO4(2-), as anticipated at the high pH (7.5-12.5) of the sites. Some differences between the implied and directly determined concentrations of dissolved CrIII, however, appeared related to the total organic carbon (TOC) content. This was most significant for the ground water from one borehole that had the highest TOC concentration of 300 mg l(-1) and at which < 3% of Cr was in the form of CrVI. Subsequent ultrafiltration produced significant decreases in Cr concentration with decreasing size fractions, e.g. <0.45 microm, < 100 kDa, <30 kDa and < 1 kDa by the tangential-flow method. As this appeared related more to concentrations of humic substances than of TOC per se, horizontal bed gel electrophoresis of freeze-dried ultrafilter retentates was carried out to further characterise the CrIII-organic complex. This showed for the main Cr-containing fraction, 100 kDa-0.45 microm, that the Cr was associated with a dark brown band characteristic of organic (humic) matter. Comparison of gel electrophoresis and FTIR results for ultrafilter retentates of ground water from this borehole with those for a borehole at another site where CrVI predominated suggested the influence of carboxylate groups, both in reducing CrVI and in forming soluble CrIII-humic complexes. The implications of this for remediation strategies (especially those based on the addition of organic matter) designed to reduce highly mobile and carcinogenic Cr(VI)O4(2-) to the much less harmful CrIII as insoluble Cr(OH)3 are discussed.     

Anishnaabe Aki: an indigenous perspective on the global threat of invasive species

Conservation discourses tend to portray invasive species as biological entities temporally connected to colonial timelines, using terms such as “alien”, “colonizing”, “colonial”, and “native”. This focus on a colonial timeline emerges from scientific publications within conservation biology and invasion ecology and is enacted through invasive species management by state and NGO actors. Colonialism is influential for indigenous nations in myriad ways, but in what ways do indigenous understandings of invasive species engage with colonialism? We conducted ethnographic research with indigenous Anishnaabe communities to learn about the ways Anishnaabe people conceptualize invasive species as a phenomenon in the world and were gifted with three primary insights. First, Anishnaabe regard plants, like all beings, as persons that assemble into nations more so than “species”. The arrival of new plant nations is viewed by some Anishnaabe as a natural form of migration. The second insight highlights the importance of actively discovering the purpose of new species, sometimes with the assistance of animal teachers. Lastly, while Anishnaabe describe invasive species as phenomenologically entangled with colonialism, the multiple ways Anishnaabe people think about invasive species provide alternatives to native–non-native binaries that dominate much of the scientific discourse.     

Increasing the sustainability of a resource development: Aboriginal engagement and negotiated agreements

While the role Aboriginal people play in environmental governance programs are often underpinned by the Crown, Aboriginal peoples are ratifying negotiated agreements with mining proponents to ensure their issues and concerns are addressed. This paper examines Aboriginal participation in mine development to show how more inclusive social and environmental development models can support a more sustainable development. Through two complementary processes, negotiated agreements and environmental impact assessment, Aboriginal peoples are maximizing their benefits and minimizing the adverse impacts of a project to create a more sustainable resource development. Case study analysis of the Galore Creek Project in northwestern British Columbia, Canada, illustrates how environmental impact assessment and negotiated agreements can co-exist to positively contribute to a successful mineral development, and hence operationalize sustainability within this context.     

Evaluating the difference between the normalized difference vegetation index and net primary productivity as the indicators of vegetation vigor assessment at landscape scale

Both the net primary productivity (NPP) and the normalized difference vegetation index (NDVI) are commonly used as indicators to characterize vegetation vigor, and NDVI has been used as a surrogate estimator of NPP in some cases. To evaluate the reliability of such surrogation, here we examined the quantitative difference between NPP and NDVI in their outcomes of vegetation vigor assessment at a landscape scale. Using Landsat ETM+ data and a process model, the Boreal Ecosystem Productivity Simulator, NPP distribution was mapped at a resolution of 90 m, and total NDVI during the growing season was calculated in Heihe River Basin, Northwest China in 2002. The results from a comparison between the NPP and NDVI classification maps show that there existed a substantial difference in terms of both area and spatial distribution between the assessment outcomes of these two indicators, despite that they are strongly correlated. The degree of difference can be influenced by assessment schemes, as well as the type of vegetation and ecozone. Overall, NDVI is not a good surrogate of NPP as the indicators of vegetation vigor assessment in the study area. Nonetheless, NDVI could serve as a fairish surrogate indicator under the condition that the target region has low vegetation cover and the assessment has relatively coarse classification schemes (i.e., the class number is small). It is suggested that the use of NPP and NDVI should be carefully selected in landscape assessment. Their differences need to be further evaluated across geographic areas and biomes.     

Floral scent variation in two <Emphasis Type="Italic">Antirrhinum majus</Emphasis> subspecies influences the choice of naïve bumblebees

Two wild subspecies of snapdragon, Antirrhinum majus, subspecies pseudomajus and striatum, differ in floral color and can be visually discriminated by insect visitors. The extent to which olfactory cues derived from floral scents contribute to discrimination between snapdragon subspecies is however unknown. We tested whether these two subspecies differ in floral scent and whether these olfactory differences are used by bumblebees (Bombus terrestris) to discriminate between them. We grew individuals of both subspecies, collected from a total of seven wild populations, under controlled conditions. We quantified the volatile organic compounds (VOCs) emitted by the flowers using gas-chromatography/mass-spectrometry/flame-ionization-detection. We studied antennal detection of VOCs by bumblebees, by means of electroantennogram study (EAG). We also performed behavioral experiments in a Y-maze to determine the innate response of bumblebees to the main floral VOCs emitted by our snapdragon subspecies. The floral scent of Antirrhinum majus pseudomajus contained three volatile benzenoids absent in the floral scent of Antirrhinum majus striatum. One of them, acetophenone, contributed over 69% of the absolute emissions of A. majus pseudomajus. These benzenoids elicited a significantly higher EAG response compared with other VOCs. In the Y-maze, bumblebees were significantly less attracted by acetophenone, suggesting an aversive effect of this VOC. Our findings indicate that bumblebees are able to discriminate between the two Antirrhinum majus subspecies. Differences in flower scent between these subspecies and olfactory bumblebee preferences are discussed in the light of biochemical constraints on VOCs synthesis and of the role of flower scent in the evolutionary ecology of A. majus.     

Modelling hydraulic jump using the bubbly two-phase flow method

Hydraulic jumps have complex flow structures, characterised by strong turbulence and large air contents. It is difficult to numerically predict the flows. It is necessary to bolster the existing computer models to emphasise the gas phase in hydraulic jumps, and avoid the pitfall of treating the phenomenon as a single-phase water flow. This paper aims to improve predictions of hydraulic jumps as bubbly two-phase flow. We allow for airflow above the free surface and air mass entrained across it. We use the Reynolds-averaged Navier–Stokes equations to describe fluid motion, the volume of fluid method to track the interface, and the k–ε model for turbulence closure. A shear layer is shown to form between the bottom jet flow and the upper recirculation flow. The key to success in predicting the jet flow lies in formulating appropriate bottom boundary conditions. The majority of entrained air bubbles are advected downstream through the shear layer. Predictions of the recirculation region’s length and air volume fraction within the layer are validated by available measurements. The predictions show a linear growth of the shear layer. There is strong turbulence at the impingement, and the bulk of the turbulence kinetic energy is advected to the recirculation region via the shear layer. The predicted bottom-shear-stress distribution, with a peak value upstream of the toe of the jump and a decaying trend downstream, is realistic. This paper reveals a significant transient bottom shear stress associated with temporal fluctuations of mainly flow velocity in the jump. The prediction method discussed is useful for modelling hydraulic jumps and advancing the understanding of the complex flow phenomenon.     

Assessing agricultural systems vulnerability to climate change to inform adaptation planning: an application in Khorezm,Uzbekistan

Agriculture is one of the most vulnerable sectors to climate change. The current vulnerability assessments through traditional fragmented sectoral methods are insufficient to capture the effects on complex agricultural systems. Therefore, the traditional methods need to be replaced by integrated approaches. The objective of this study is to propose a holistic vulnerability assessment method for agricultural systems. By aggregating both agro-ecological and socio-economic information, we develop an agricultural systems vulnerability index (ASVI) which allows for (i) a classification of geographical units according to their vulnerability level, (ii) an identification of key determinants of vulnerability for each unit and (iii) an assessment of adaptation policy scenarios considering their effects on the sustainability of the analysed systems. The proposed method is applied in the Khorezm region of Uzbekistan—a representative irrigated agricultural region in the lower Amu Darya river basin. A decision support tool is used to facilitate multi-criteria decision analysis, including the computation of the index and performing sensitivity analysis of the results. The assessment for Khorezm reveals significant spatial differences of vulnerability levels due to a variation of contributing factors, e.g. natural resources, water productivity, rural-urban ratio. It reveals also that feasible land and water management policies could reduce the vulnerability in Khorezm, particularly in the districts with the poorest agro-ecological conditions. Overall, the proposed method could support national and local authorities in the identification of sustainable adaptation policies for the agriculture sector.     

Impact of Massanjore Dam on hydro-geomorphological modification of Mayurakshi River,Eastern India

Massanjore reservoir (area ~67 km²) located 84 km downstream from the most distant upstream source capacitates 620,000,000 m³ of water, and regulated flow characters are highly responsible for dam downstream alteration of hydrological, sedimentological and geomorphological characteristics of Mayurakshi River. In dam after condition, monsoon water level (mean water level during monsoon months) and pre-monsoon water level (mean water level during pre-monsoon months, i.e., March–May) have attenuated about 0.56 and 0.32 m, respectively. Maximum duration of high flow period during monsoon has reduced up to 16.5 %; coefficient of variation of diurnal fluctuation of water level during monsoon has increased from 31 to 47 %. Suspended sediment load in Mayurakshi River is reduced to 34 % in dam after period as recorded at Narayanpur gauge station. Average suspended sediment load has decreased even after Tilpara barrage construction from 4.960 to 4.350 mg/L. Average suspended sediment load is 7.875 mg/L in the sites of dam upstream course, and this average is only 4.46 mg/L in different sites of dam downstream course. Volume of discharge has decreased up to 11.3 % during monsoon time in dam after condition. Such reduction in discharge volume in turn has reduced about 24.6 % bed load-carrying capacity. As a result, huge deposition within channel invigorated channel bed aggradations (average 73.6 cm up to Saspara, site 14 at Fig. 1) in dam after condition. Narrowing of active channel, coarsening of channel bed materials, lowering of lateral stability, accelerating rise of braiding index, mixed response of the channel adjustment of the tributaries to local scale positive or negative base level change due to river bed aggradations and degradation, etc. signify the morphological alteration of dam downstream course.

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Fig. 1 Mayurakshi River basin indicating Massanjore Dam, Tilpara barrage and sample working sites

     

Electro-dissolution of metal scrap anodes for nickel ion removal from metal finishing effluent

This contribution reports a novel and cost efficient strategy for nickel ion removal from metal finishing effluents by electro-dissolution of scrap aluminium and iron sacrificial anodes. Electro-coagulation of effluent was carried out at 30 mA/cm² current density for 60 min. The nickel ion concentration of electroplating effluent was analysed by Atomic Absorption Spectroscopy. SEM images of iron and aluminium scrap anodes were critically analysed. Parameters such as heavy metal removal, anode dissolution rate with respect to heavy metal removal, reaction kinetics and cost estimation have been elaborately studied. Electro-coagulation at 30 mA/cm² for 60 min using iron and aluminium scrap anodes resulted in 95.9 and 94.1 % nickel ion reduction, respectively, with 0.0094 and 0.0053 g/ppm dissolution rates. The energy consumption for scrap aluminium and iron anodes was 0.0547 kWh/L. Loose internal bonding and spongy surface morphology of used metal scrap render high porosity and active surface area, enhancing reaction rate. Low cost and ready availability of waste scrap makes the process of electro-coagulation economically viable. Thus, the findings from this contribution point decisively at the superiority of waste metal scrap-based anodes for economic and environmentally sustainable heavy metal ion removal from metal finishing effluent.