Speciation of organotins in polyvinyl chloride pipe via X-ray absorption spectroscopy and in leachates using GC-PFPD after derivatisation

Three different polyvinyl chloride (PVC) pipe types were subjected to de-ionized water exposures over the course of at least 180 days. Water exposed to the pipe was analyzed for organotin speciation and concentration. Organotin concentrations were the highest during the first 1-5 days. The species and concentrations of organotins leached varied by pipe type. Data were normalized by surface area in order to compare laboratory results with results from a residential pipe system. For one pipe type, the lowest non-zero concentrations from the laboratory tests overestimated organotin concentrations in solution when compared with water samples from the same pipe type in a residence. For organotin exposure estimates, a range of 0.1 ng m(-2) to 10 ng m(-2) could be used for mature pipes (e.g. in use for 1 year). These estimates should be refined with more field study, however, due to the high variation in organotin species and concentrations leached as a function of pipe type, accuracy within an order of magnitude may be optimal as, in many instances, the type of pipe installed or buried may be unknown. X-ray absorption spectroscopy (XAS) was used to identify organic and inorganic tin species in reference materials and the PVC samples. Monobutyl tin was identified as the primary organotin species in the pipes. Results from the XAS analyses also indicate that the technique shows promise for distinguishing between inorganic tin and organotins. Furthermore, organotins may be distinguished between mono-, di-, and tri-ligand species using XAS.     

Ectoparasites of house sparrows (Passer domesticus): an experimental test of the immunocompetence handicap hypothesis and a new model

Conspicuous secondary sexual traits may have evolved as handicap-revealing signals or as badges of status. We present results of an experiment using males of the sexually dimorphic house sparrow (Passer domesticus), that support the idea that the male-specific bib can be both a handicap-revealing signal and a reliable badge indicating the physical condition of the bird. In a test of the immunocompetence handicap hypothesis, wild-caught adult male house sparrows were studied in captivity. Birds implanted with elevated doses of testosterone were more dominant, had higher circulating levels of both testosterone and corticosterone and they also harboured relatively larger ectoparasite loads. Higher parasite loads were also associated with individuals showing lower immunocompetence and larger changes in bib size. A new model for immunocompetence effects in sexual selection is introduced, integrating actions that the hypothalamopituitary axis exerts on gonads, adrenals and the thyroid gland. The ”integrated immunocompetence model” synthesizes both the ”handicap” (i.e. survival-decreasing) and ”badge of status” (i.e. survival- enhancing) models for evolution of secondary sexual traits. Received: 15 May 1999 / Received in revised form: 2 November 1999 / Accepted: 6 November 1999     

Training Captive-Bred or Translocated Animals to Avoid Predators

Abstract: Animal reintroductions and translocations are potentially important interventions to save species from extinction, but most are unsuccessful. Mortality due to predation is a principal cause of failure. Animals that have been isolated from predators, either throughout their lifetime or over evolutionary time, may no longer express appropriate antipredator behavior. For this reason, conservation biologists are beginning to include antipredator training in pre-release preparation procedures. We describe the evolutionary and ontogenetic circumstances under which antipredator behavior may degenerate or be lost, and we use principles from learning theory to predict which elements can be enhanced or recovered by training. The empirical literature demonstrates that training can improve antipredator skills, but the effectiveness of such interventions is influenced by a number of constraints. We predict that it will be easier to teach animals to cope with predators if they have experienced ontogenetic isolation than if they have undergone evolutionary isolation. Similarly, animals should learn more easily if they have been evolutionarily isolated from some rather than all predators. Training to a novel predator may be more successful if a species has effective responses to similar predators. In contrast, it may be difficult to teach proper avoidance behavior, or to introduce specialized predator-specific responses, if appropriate motor patterns are not already present. We conclude that pre-release training has the potential to enhance the expression of preexisting antipredator behavior. Potential training techniques involve classical conditioning procedures in which animals learn that model predators are predictors of aversive events. However, wildlife managers should be aware that problems, such as the emergence of inappropriate responses, may arise during such training.     

How do trade and economic growth impact environmental degradation? New evidence and policy implications from the ARDL approach

Environmental Science and Pollution Research - Due to various environmental degradation and natural resource depletion around the world, researchers’ and policymakers’ attention has...     

A rationale for recycling

The decision as to whether to recycle discarded objects or not has traditionally been made on a simple financial basis. However, over the last few years a popular movement has sprung up which regards recycling as a good in itself, and this movement finds itself at odds with the present financial basis for recycling. In this paper a rationale for recycling is worked out in an attempt to resolve this conflict. It is concluded that the normal market signals do not provide a proper basis for recycling decisions and that this market failure must be corrected by government intervention. However, this intervention should not take the form of uncritical support for recycling. Rather the societal objectives of individual recycling proposals should be identified and the proposal should then be evaluated in terms of whether it would achieve these objectives more effectively than some alternative action.     

Mercury in flounder (Platichthys flesus L.) from estuaries and coastal waters of the north-east Irish Sea

This paper reports concentrations of mercury in muscle tissue of flounder (Platichthys flesus L.) from various estuaries and coastal waters of north Wales and north-west England that encompass the north-east Irish Sea. Mercury concentrations were highest within and offshore the Ribble Estuary (0.476 +/- 0.037 mg kg(-1)) but were also high within the Mersey (0.389+/-0.042 mg kg(-1)) and Dee Estuaries (0.295+/-0.065) and at coastal sites in the vicinity. Values for all three estuaries and their near coastal sites were significantly higher than for sites in the north and central sectors of the study area. Regressions of mercury concentration against fish length showed significant relationships and age accumulation for the majority of sites, particularly within or in close proximity to the Mersey, Dee and Ribble Estuaries.     

The nexus amid foreign direct investment,urbanization, and CO2 emissions: Evidence from energy grouping along the ECOWAS community

Environment, Development and Sustainability - The vision of every country or subregions is to achieve economic growth and sustainable economic growth. Thus, the Economic Community of West African...     

ESTIMATING REFERENCE EVAPORATION IN THE CENTRAL VALLEY OF CALIFORNIA USING THE LINACRE MODEL1

ABSTRACT: The Linacre (1988) model for calculating evaporation from open water or well-watered surfaces only requires inputs of air temperature, latitude and elevation, and windspeed if it is available. The model was developed using data collected at a large number of sites in different climatic regions of the world, while independent tests of the model have shown it to be suitable for estimating evaporation in a variety of locations. This study was intended to contribute to the broad goal of evaluating temperature-based evaporation models for use in California by testing the Linacre model in the agriculturally intensive Central Valley. Observed monthly mean reference evaporation (E_o) and meteorological data for periods ranging up to 72 months were obtained from 25 California Irrigation and Management Information System (CIMIS) stations distributed throughout the Central Valley. Uncalibrated and calibrated Linacre models were used to estimate monthly mean reference evaporation, and the performance of each model was evaluated using indices that quantified the random and systematic errors and overall model performance. The accuracy of the radiation and ventilation components of the model were evaluated separately. The uncalibrated model was found to systematically overestimate E_o with most of the model error being attributed to the ventilation component. Calibration of the radiation and ventilation components removed most of the systematic model errors, and the root mean square error for monthly mean E_o was 0.676 mm day^?1 (16.8 percent of the mean observed value). (KEY TERMS: reference evaporation; Linacre model; irrigation scheduling.)     

The BOR syndrome and renal agenesis-prenatal diagnosis andfurther clinical delineation

This is the first report of prenatal diagnosis of a fetus with brachio-oto-renal dysplasia (BOR) syndrome with right-sided renal agenesis and severe left hypoplasia. The father of this fetus had malformed external ears, a left-sided preauricular pit and branchial cyst, and bilateral mild to moderate deafness without a demonstrable renal anomaly. This family highlights the variable expressivity seen in the autosomal dominant BOR syndrome, the importance of genetic counselling for families with BOR syndrome, and the aetiologic heterogeneity of renal agenesis.