Aerosol formation yields from the reaction of catechol with ozone

The formation of secondary organic aerosol from the gas-phase reaction of catechol (1,2-dihydroxybenzene) with ozone has been studied in two smog chambers. Aerosol production was monitored using a scanning mobility particle sizer and loss of the precursor was determined by gas chromatography and infrared spectroscopy, whilst ozone concentrations were measured using a UV photometric analyzer. The overall organic aerosol yield (Y) was determined as the ratio of the suspended aerosol mass corrected for wall losses (M_o) to the total reacted catechol concentrations, assuming a particle density of 1.4 g cm^?3. Analysis of the data clearly shows that Y is a strong function of M_o and that secondary organic aerosol formation can be expressed by a one-product gas–particle partitioning absorption model. The aerosol formation is affected by the initial catechol concentration, which leads to aerosol yields ranging from 17% to 86%. The results of this work are compared to similar studies reported in the literature.     

Assessing spatial variability of SO2 field as detected by an air quality network using Self-Organizing Maps,cluster, and Principal Component Analysis

In Bilbao (Spain), an air quality network measures sulphur dioxide levels at 4 locations. The objective of this paper is to develop a practical methodology to identify redundant sensors and evaluate a network's capability to correctly follow and represent SO₂ fields in Bilbao, in the frame of a continuous network optimization process.The methodology is developed and tested at this particular location, but it is general enough to be useable at other places as well, since it is not tied neither to the particular geographical characteristics of the place nor to the phenomenology of the air quality over the area.To assess the spatial variability of SO₂ measured at 4 locations in the area, three different techniques have been used: Self-Organizing Maps (SOMs), cluster analysis (CA) and Principal Component Analysis (PCA). The results show that the three techniques yield the same results, but the information obtained via PCA can be helpful not only for that purpose but also to throw light on the major mechanisms involved. This might be used in future network optimization stages. The main advantage of cluster analysis and SOMs is that they provide readily interpretable results. All the calculations have been carried out using the freely available software R.     

The Effect of Shoreline Recreational Angling Activities on Aquatic and Riparian Habitat Within an Urban Environment: Implications for Conservation and Management

There is growing concern that recreational shoreline angling activity may negatively impact littoral and riparian habitats independent of any direct or indirect influences of fish harvest or fishing mortality through mechanisms such as disturbance (e.g., trampling, erosion) and pollution (e.g., littering). We sampled a suite of aquatic and terrestrial variables (i.e., water quality, aquatic and terrestrial macrophytes, soil compaction, anthropogenic refuse) at 14 high shoreline angling-activity sites (identified by way of interviews with conservation officers and angling clubs) within an urban area (Ottawa, Canada). For each high angling-activity site, a nearby corresponding low angling-activity site was sampled for comparison. We found that the percentage of barren area and soil compaction were greater in areas of high angling activity compared with areas that experienced relatively low angling activity. In addition, terrestrial and aquatic macrophyte density, height, and diversity were lower at high angling-activity sites. Angling- and non-angling-related litter was present in large quantities at each of the high angling-activity sites, and comparatively little litter was found at low angling-activity sites. Collectively, these findings indicate that shoreline angling does alter the riparian environment, contributing to pollution and environmental degradation in areas of high angling intensity. With growing interest in providing urban angling opportunities and in response to increasing interest in developing protected areas and parks, a better understanding of the ecologic impacts of shoreline angling is necessary to address multiuser conflicts, to develop angler outreach and educational materials, and to optimize management of angling effort to maintain ecologic integrity of riparian and aquatic ecosystems.     

Colonized beads as inoculum for marine biodegradability assessment: Application to Linear Alkylbenzene Sulfonate

An innovative biodegradation test system was developed in order to fill the current gap for cost effective and environmentally relevant tools to assess marine biodegradability. Glass beads were colonized by a biofilm in an open flow-through system of seawater with continuous pre-exposure to Linear Alkylbenzene Sulfonate (LAS) (20 μg/L). Thereafter, such colonized beads were added as inoculum in different test systems. [¹⁴C]-LAS (5–100 μg/L) was added and primary and ultimate biodegradation were assessed. The bacterial density collected on the beads (10⁹ bact./mL beads) was ca. 3 orders of magnitude higher than the typical seawater content. The LAS mineralization lag phase duration decreased from 55 to < 1 days and the mineralization extent increased from 53 to 90% as the colonized beads volume increased from 10 to 275 mL. This is the first demonstration of marine bacteria's ability to mineralize LAS. On the opposite, less than 13% LAS was mineralized in seawater only. The colonized beads possibly enhanced the probability to encounter the full degraders' consortium in a low volume of seawater (100 mL).     

Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders

Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors.     

Reproductive parameters and disturbances of embryonic development in the fieldfare (<Emphasis Type="Italic">Turdus pilaris</Emphasis> L.) in the zone of impact from the nuclear fuel industry

The impact of emissions from the Siberian Chemical Plant (Tomsk oblast) on reproduction and embryonic development of the fieldfare was studied. Bird abundance, clutch size, and egg volume in the impact and background (control) zones were similar, but partial brood mortality in the impact zone proved to be significantly higher, and the frequency of embryonic pathologies (including developmental abnormalities) was also several times higher than in the control.     

Remote effect of nuclear polyhedrosis virus on the gypsy moth (<Emphasis Type="Italic">Lymantria dispar</Emphasis> L.) in its natural environment

The remote effect of the nuclear polyhedrosis virus on the gypsy moth was studied for the first time under natural conditions. In the generation that developed from infected eggs, the weight of pupae was reduced, sex ratio was altered, and female fecundity and egg fertility were lower than in control individuals. The F₁ progeny of these moths were characterized by an increased rate of latent virus carriage and high mortality caused by the combined effect of polyhedrosis and insect parasites.     

Composition of pied flycatcher (<Emphasis Type="Italic">Ficedula hypoleuca</Emphasis> Pall.) nestling diet in industrially polluted area

The composition of pied flycatcher (Ficedula hypoleuca Pall.) nestling diet was studied in the zone of strong pollution with emissions from the Middle Ural Copper Smelter (Revda, Sverdlovsk oblast) and in the background area from 2005 to 2007. The results show that diversity of the diet decreases and prevalence in it of one insect taxon (Lepidoptera) increases near the source of emissions. The proportion of uncharacteristic food objects (orthopterans, herpetobiont invertebrates) and variation in the size of invertebrates brought by parents to their nestlings increase, which is explained by degradation of forest habitats in the polluted area. Pied flycatchers provide nestlings with sufficient quantities of food, but its quality in the polluted zone is lower than in the background area.     

Binding of polycyclic aromatic hydrocarbons by humic acids formed during composting

Binding of two model polycyclic aromatic hydrocarbons (PAHs), phenanthrene and pyrene, by humic acids (HAs) isolated from an organic substrate at different stages of composting and a soil was investigated using a batch fluorescence quenching method and the modified Freundlich model. With respect to soil HA, the organic substrate HA fractions were characterized by larger binding affinities for both phenanthrene and pyrene. Further, isotherm deviation from linearity was larger for soil HA than for organic substrate HAs, indicating a larger heterogeneity of binding sites in the former. The composting process decreased the binding affinity and increased the heterogeneity of binding sites of HAs. The changes undergone by the HA fraction during composting may be expected to contribute to facilitate microbial accessibility to PAHs. The results obtained also suggest that bioremediation of PAH-contaminated soils with matured compost, rather than with fresh organic amendments, may result in faster and more effective cleanup.