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881.
do A Kehrig H Seixas TG Palermo EA Baêta AP Castelo-Branco CW Malm O Moreira I 《Environmental science and pollution research international》2009,16(1):10-24
Background, aim, and scope Selenium (Se) has been shown to reduce mercury (Hg) bioavailability and trophic transfer in aquatic ecosystems. The study
of methylmercury (MeHg) and Se bioaccumulation by plankton is therefore of great significance in order to obtain a better
understanding of the estuarine processes concerning Hg and Se accumulation and biomagnification throughout the food web. In
the western South Atlantic, few studies have documented trace element and MeHg in fish tissues. No previous study about trace
elements and MeHg in plankton has been conducted concerning tropical marine food webs. Se, Hg, and MeHg were determined in
two size classes of plankton, microplankton (70–290 μm) and mesoplankton (≥290 μm), and also in muscle tissues and livers
of four fish species of different trophic levels (Mugil liza, a planktivorous fish; Bagre spp., an omnivorous fish; Micropogonias furnieri, a benthic carnivorous fish; and Centropomus undecimalis, a pelagic carnivorous fish) from a polluted estuary in the Brazilian Southeast coast, Guanabara Bay. Biological and ecological
factors such as body length, feeding habits, and trophic transfer were considered in order to outline the relationships between
these two elements. The differences in trace element levels among the different trophic levels were investigated.
Materials and methods Fish were collected from July 2004 to August 2005 at Guanabara Bay. Plankton was collected from six locations within the bay
in August 2005. Total mercury (THg) was determined by cold vapor atomic absorption spectrometry (CV-AAS) with sodium borohydride
as a reducing agent. MeHg analysis was conducted by digesting samples with an alcoholic potassium hydroxide solution followed
by dithizone-toluene extraction. MeHg was then identified and quantified in the toluene layer by gas chromatography with an
electron capture detector (GC-ECD). Se was determined by AAS using graphite tube with Pin platform and Zeeman background correction.
Results and discussion Total mercury, MeHg, and Se increased with plankton size class. THg and Se values were below 2.0 and 4.8 μg g−1 dry wt in microplankton and mesoplankton, respectively. A large excess of molar concentrations of Se in relation to THg was
observed in both plankton size class and both fish tissues. Plankton presented the lowest concentrations of this element.
In fish, the liver showed the highest THg and Se concentrations. THg and Se in muscle were higher in Centropomus undecimalis (3.4 and 25.5 nmol g−1) than in Micropogonias furnieri (2.9 and 15.3 nmol g−1), Bagre spp (1.3 and 3.4 nmol g−1) and Mugil liza (0.3 and 5.1 nmol g−1), respectively. The trophic transfer of THg and Se was observed between trophic levels from prey (considering microplankton
and mesoplankton) to top predator (fish). The top predators in this ecosystem, Centropomus undecimalis and Micropogonias furnieri, presented similar MeHg concentrations in muscles and liver. Microplankton presented lower ratios of methylmercury to total
mercury concentration (MeHg/THg) (34%) than those found in mesoplankton (69%) and in the muscle of planktivorous fish, Mugil liza (56%). The other fish species presented similar MeHg/THg in muscle tissue (of around 100%). M. liza showed lower MeHg/THg in the liver than C. undecimalis (35%), M. furnieri (31%) and Bagre spp. (22%). Significant positive linear relationships were observed between the molar concentrations of THg and Se in the
muscle tissue of M. furnieri and M. liza. These fish species also showed significant inverse linear relationships between hepatic MeHg and Se, suggesting a strong
antagonistic effect of Se on MeHg assimilation and accumulation.
Conclusions Differences found among the concentrations THg, MeHg, and Se in microplankton, mesozooplankton, and fishes were probably related
to the preferred prey and bioavailability of these elements in the marine environment. The increasing concentration of MeHg
and Se at successively higher trophic levels of the food web of Guanabara Bay corresponds to a transfer between trophic levels
from the lower trophic level to the top-level predator, suggesting that MeHg and Se were biomagnified throughout the food
web. Hg and Se were positively correlated with the fish standard length, suggesting that larger and older fish bioaccumulated
more of these trace elements. THg, MeHg, and Se were a function of the plankton size.
Recommendations and perspectives There is a need to assess the role of selenium in mercury accumulation in tropical ecosystems. Without further studies of
the speciation of selenium in livers of fishes from this region, the precise role of this element, if any, cannot be verified
in positively affecting mercury accumulation. Further studies of this element in the study of marine species should include
liver samples containing relatively high concentrations of mercury. A basin-wide survey of selenium in fishes is also recommended. 相似文献
882.
Mechanistic effect models for ecological risk assessment of chemicals (MEMoRisk)—a new SETAC-Europe Advisory Group 总被引:1,自引:1,他引:0
883.
Heinz Rüdel Winfried Schröder Karl Theo von der Trenck Gerhard Andreas Wiesmüller 《Environmental science and pollution research international》2009,16(5):486-498
Background Due to the requirements of the EU Water Framework Directive and other legal regulations (e.g., national laws like the German
Federal Soil Protection Act), but also due to the implementation of the new EU chemicals management system REACH, environmental
monitoring will gain increasing importance for the surveillance of environmental quality as well as for the assessment of
chemicals. Against this background, the Work Group on ‘Environmental Monitoring’ of the Division of ‘Environmental Chemistry
and Ecotoxicology’ within the German Chemical Society has compiled a position paper on substance-related environmental monitoring.
Scope Core elements of this position paper are the definitions of important terms like monitoring, exposure monitoring, effect monitoring,
and integrated monitoring. Moreover, temporal and spatial aspects (monitoring of spatial distributions, trend monitoring,
and retrospective monitoring) and their applications are discussed. The main focus of this position paper is the coverage
of aspects which have to be observed for the preparation and implementation of a monitoring program. Essential is the clear
specification of the targets of the monitoring which determine the development of the monitoring concept and its realization,
e.g., if environmental media (compartments) or organisms are most appropriate as samples for the aim of the study. Of course,
also the properties of the target substances are important (e.g., lipophilicity/bioaccumulation as pre-requisite for an exposure
monitoring with organisms). Finally, the monitoring phases of sample planning, sampling, storage and transport of samples,
selection of analytical methods, quality assurance measures as well as reporting are discussed.
Perspectives An important issue for the future is to link the quantification of chemicals in environmental compartments (exposure and pollution
monitoring) more closely to the study of biological effects (effect monitoring) than has been the case up to now. Furthermore,
by inclusion of a spatial differentiation, a comprehensive evaluation of the state of an ecosystem can be obtained and the
relevance of the results improved. Practical examples of monitoring studies which illustrate various aspects covered in this
position paper will be presented in a series of publications by members of the Work Group in the following issues of this
journal.
相似文献
Gerhard Andreas WiesmüllerEmail: |
884.
W.J.F. Standring J.E. Brown M. Dowdall E.M. Korobova V.G. Linnik A.G. Volosov 《Journal of environmental radioactivity》2009,100(12):1109
The Mining and Chemical Industrial Combine, Zheleznogorsk (MCIC, previously known as Krasnoyarsk-26) on the River Yenisey has contaminated the surrounding environment with anthropogenic radionuclides as a result of discharges of radioactive wastes. The purpose of this study was to investigate the vertical distribution of anthropogenic contamination (137Cs and plutonium) within floodplain areas at different distances from the discharge point. Sites were chosen that display different characteristics with respect to periodic inundation with river water. Cs-137 activity concentrations were in the range 23–3770 Bq/kg (dry weight, d.w.); Pu-239,240 activity concentrations were in the range <0.01–14.2 Bq/kg (d.w.). Numerous sample cores exhibited sub-surface maxima which may be related to the historical discharges from the MCIC. Possible evidence indicating the deposition of earlier discharges at MCIC in deeper core layers was observed in the 238Pu:239,240Pu activity ratio data: a Pu signal discernible from global fallout could be observed in numerous samples. Cs-137 and Pu-239,240 activity concentrations were correlated with the silt fraction (% by mass <63 μm) though no significant correlation was observed between (grain-size) normalised 137Cs activity concentrations and distance downstream from the MCIC. 相似文献
885.
S. Fesenko N. Isamov B.J. Howard N.A. Beresford C.L. Barnett N. Sanzharova G. Voigt 《Journal of environmental radioactivity》2009
Over 150 publications reporting studies conducted in the former USSR were reviewed to provide transfer coefficients (Ff) to the muscle of domestic animals from experiments using chronic administration, often for long timescales in large scale experiments. Only a few of these studies were made available in the English language literature or taken into account in international reviews. The values derived have been compared with expected values reported by the IAEA's Handbook of parameter values for the prediction of radionuclide transfer in temperate environments (TRS 364) where possible. The information presented here has been used in the current updating of parameters recommended for environmental assessments by the IAEA. Many of the reported values are for Sr due to the Mayak accident and Cs due to the Chernobyl accident. Nevertheless, the reported data for a wide range of radionuclides, in particular for Ru, Sb, and Zn markedly improve the extent of available data. 相似文献
886.
Effects of acute γ-irradiation on the aquatic microbial microcosm in comparison with chemicals 总被引:1,自引:1,他引:0
Shoichi Fuma Nobuyoshi Ishii Hiroshi Takeda Kiriko Miyamoto Kei Yanagisawa Kazutaka Doi Isao Kawaguchi Nobuyuki Tanaka Yuhei Inamori Gennady G. Polikarpov 《Journal of environmental radioactivity》2009,100(12):1027-1033
Effects of acute γ-irradiation were investigated in the aquatic microcosm consisting of green algae (Chlorella sp. and Scenedesmus sp.) and a blue–green alga (Tolypothrix sp.) as producers; an oligochaete (Aeolosoma hemprichi), rotifers (Lecane sp. and Philodina sp.) and a ciliate protozoan (Cyclidium glaucoma) as consumers; and more than four species of bacteria as decomposers. At 100 Gy, populations were not affected in any taxa. At 500–5000 Gy, one or three taxa died out and populations of two or three taxa decreased over time, while that of Tolypothrix sp. increased. This Tolypothrix sp. increase was likely an indirect effect due to interspecies interactions. The principal response curve analysis revealed that the main trend of the effects was a dose-dependent population decrease. For a better understanding of radiation risks in aquatic microbial communities, effect doses of γ-rays compared with copper, herbicides and detergents were evaluated using the radiochemoecological conceptual model and the effect index for microcosm. 相似文献
887.
F. Monna F. van Oort P. Hubert J. Dominik J. Bolte J.-L. Loizeau J. Labanowski J. Lamri C. Petit G. Le Roux C. Chateau 《Journal of environmental radioactivity》2009
An 80-year soil archive, the 42-plot experimental design at the INRA in Versailles (France), is used here to study long-term contamination by 137Cs atmospheric deposition and the fate of this radioisotope when associated with various agricultural practices: fallow land, KCl, NH4(NO3), superphosphate fertilizers, horse manure and lime amendments. The pertinence of a simple box model, where radiocaesium is supposed to move downward by convectional mechanisms, is checked using samples from control plots which had been neither amended, nor cultivated since 1928. This simple model presents the advantage of depending on only two parameters: α, a proportional factor allowing the historical atmospheric 137Cs fluxes to be reconstructed locally, and k, an annual loss coefficient from the plow horizon. Another pseudo-unknown is however necessary to run the model: the shape of historical 137Cs deposition, but this function can be easily computed by merging several curves previously established by other surveys. A loss of ∼1.5% per year from the plow horizon, combined with appropriate fluxes, provides good concordance between simulated and measured values. In the 0–25 cm horizon, the residence half time is found to be ∼18 yr (including both migration and radioactive decay). Migration rate constants are also calculated for some plots receiving continuous long-term agricultural treatments. Comparison with the control plots reveals significant influence of amendments on 137Cs mobility in these soils developed from a unique genoform. 相似文献
888.
S. Fesenko B.J. Howard N. Isamov N.A. Beresford C.L. Barnett N. Sanzharova G. Voigt 《Journal of environmental radioactivity》2009,100(10):815-822
Data on radionuclide transfer to domestic chickens and ducks obtained from research performed in the former Soviet Union were reviewed to provide transfer coefficient values (Ff) to poultry and edible egg contents. The majority of the data are from experiments with 90Sr and 137Cs, reflecting the importance of these radionuclides after global fallout and major radiation accidents. Data for 3H, 54Mn, 59Fe, 60Co, 22Na 65Zn, 131I and U are also given. The values derived have been compared with those in the current IAEA Handbook of parameter values for the prediction of radionuclide transfer in temperate environments (TRS 364) and the recent revision which incorporates the values from this paper. The Russian-language data give improved estimates for many radionuclides and the revised handbook is now based on the better quality data given for chronic administration. 相似文献
889.
Environmental sociology and the sociology of natural resources are two key subdisciplines of the sociological study on the interactions between nature and human society. Previous discussion on the relationships of these two fields has largely focused on their distinctions and synthesis in western (particularly American) academia. Environmental sociology emerged as an important sociological subdiscipline in China in the early 1990s and is under vigorous disciplinary construction at present. By contrast, the sociology of natural resources is still a novel term for most Chinese researchers. This article provides a systematic review of recent literature on the relationships between environmental and natural resource sociologies, which should provide important implications for the further development of environmental sociology in China. 相似文献
890.