Enhanced removal of high-As(Ⅲ) from Cl(-Ⅰ)-diluted SO4(-Ⅱ)-rich wastewater at pH 2.3 via mixed tooeleite and(Cl(-Ⅰ)-free) ferric arsenite hydroxychloride formation

An advanced cost-saving method of removal of high-As(Ⅲ) from SO₄(-Ⅱ)-rich metallurgi cal wastewater has been developed by diluting the SO₄(-Ⅱ) content with As(Ⅲ)-Cl(-Ⅰ)-rich metallurgical wastewater and then by the direct precipitation of As(Ⅲ) with Fe(Ⅲ) at pH2.3.As(Ⅲ) removal at various SO₄(-Ⅱ)/Cl(-Ⅰ) molar ratios and temperatures was investigated The results showed that 65.2–98.2%of As(III) immobilization into solids occurred at the SO₄(Ⅱ)/Cl(-Ⅰ) mo...     

Decomplexation of Cu-1-hydroxyethylidene-1,1-diphosphonic acid by a three-dimensional electrolysis system with activated biochar as particle electrodes

The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10⁻³ and 1.94 × 10⁻⁵ min⁻¹respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H₂O₂ and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed.     

事故出流时河流综合水质的计算机预测方法研究

河流上游的污水排放口或倒虹管等污水构筑因有可能发生事故出流而对下游的取水口存在着潜在的威胁，常规的单参数模型不能就事故出流对下游的影响作出公正评价。本文以QUAL－Ⅱ模型为骨架，以生动形象的动画形式演示出在整个排污过程中多个水质参数沿河道分布的变化全过程，并且，在模型中融入隶属度BP神经网络综合评价水质的模块，用它来对发生事故出流时下游取水口水域的水质变化进行综合评价，最后通过一个例子说明了该方法的优越性和合理性。     

于桥水库流域暴雨径流中锰的输送特征及其对水库水质的影响

对于桥水库流域内暴雨径流中锰含量形态的研究表明,锰主要以悬浮状态存在,其中易释放的、潜在释放的和非释放形态的锰所占比例分别为10％、60％和30％.以溶解态迁移的锰极少.流域内的锰矿-含锰页岩带提高了暴雨径流中总锰的浓度,对于桥水库水质造成了一定的影响.