Primary and secondary organic aerosol in an urban/industrial site: Sources, health implications and the role of plastic enriched waste burning

PM10 samples were collected from an urban/industrial site nearby Athens, where uncontrolled burning activities occur. PAHs, monocarboxylic, dicarboxylic, hydroxycarboxylic and aromatic acids, tracers from BVOC oxidation, biomass burning tracers and bisphenol A were determined. PAH, monocarboxylic acids, biomass burning tracers and bisphenol A were increased during autumn/winter, while BSOA tracers, dicarboxylic- and hydroxycarboxylic acids during summer. Regarding aromatic acids, different sources and formation mechanisms were indicated as benzoic, phthalic and trimellitic acids were peaked during summer whereas p-toluic, isophthalic and terephthalic were more abundant during autumn/winter. The Benzo[a]pyrene-equivalent carcinogenic power, carcinogenic and mutagenic activities were calculated showing significant (p < 0.05) increases during the colder months. Palmitic, succinic and malic acids were the most abundant monocarboxylic, dicarboxylic and hydrocarboxylic acids during the entire sampling period. Isoprene oxidation was the most significant contributor to BSOA as the isoprene-SOA compounds were two times more abundant than the pinene-SOA (13.4 ± 12.3 and 6.1 ± 2.9 ng/m³, respectively). Ozone has significant impact on the formation of many studied compounds showing significant correlations with: isoprene-SOA (r = 0.77), hydrocarboxylic acids (r = 0.69), pinene-SOA (r = 0.63),dicarboxylic acids (r = 0.58), and the sum of phthalic, benzoic and trimellitic acids (r = 0.44). PCA demonstrated five factors that could explain sources including plastic enriched waste burning (30.8%), oxidation of unsaturated fatty acids (23.0%), vehicle missions and cooking (9.2%), biomass burning (7.7%) and oxidation of VOCs (5.8%). The results highlight the significant contribution of plastic waste uncontrolled burning to the overall air quality degradation.     

Effect of first-flush device,roofing material,and antecedent dry days on water quality of harvested rainwater

Environmental Science and Pollution Research - Two rainwater harvesting systems, which included first-flush diversion devices, connected to the roofs of two adjacent buildings, were monitored for...     

INTEGRATING HUMANS IN ECOSYSTEM MANAGEMENT USING MULTI‐CRITERIA DECISION MAKING1

ABSTRACT: The Ecosystem Management (EM) process belongs to the category of Multi‐Criteria Decision Making (MCDM) problems. It requires appropriate decision support systems (DSS) where “all interested people” would be involved in the decision making process. Environmental values critical to EM, such as the biological diversity, health, productivity and sustainability, have to be studied, and play an important role in modeling the ecosystem functions; human values and preferences also influence decision making. Public participation in decision and policy making is one of the elements that differentiate EM from the traditional methods of management. Here, a methodology is presented on how to quantify human preferences in EM decision making. The case study of the National Park of River Nestos Delta and Lakes Vistonida and Ismarida in Greece, presented as an application of this methodology, shows that the direct involvement of the public, the quantification of its preferences and the decision maker's attitude provide a strong tool to the EM decision making process. Public preferences have been given certain weights and three MCDM methods, namely, the Expected Utility Method, Compromise Programming and the Analytic Hierarchy Process, have been used to select alternative management solutions that lead to the best configuration of the ecosystem and are also socially acceptable.     

Towards enhancing tidally-induced water renewal in coastal lagoons

Environmental Fluid Mechanics - In order to address the problem of limited water renewal in restricted lagoons of moderate size having at least two tidal inlets, a method is proposed to enhance...     

Unregulated urban sprawl and spatial distribution of fire events: evidence from Greece

Fire events are an annual phenomenon in Greece with damages and even casualties, making their understanding and management important. In this paper, we present fire events provided by NASA Fire Information for Resource Management System and place them along a number of spatial types defined by relief and land cover classes. Results demonstrate that the occurrence of fire events is related more to some land cover classes than others. The most important in terms of overall frequency in all types of terrain is ‘Agricultural Areas’, as a result of farming practices that involve fire. The second more important type of areas is ‘Artificial Surfaces’, especially in low lying areas. These events are related to urban growth and sprawl and are very often a direct outcome of speculation practices with land properties, encouraged by the absence or poor implementation of spatial planning.     

Spatial and temporal variations in the trace elemental data over the northeastern United States

Time series of trace elemental concentrations (14 species) of atmospheric fine particles measured in the northeastern United States between 1988 and 1998 are analyzed for spatial and temporal variations. The influence of synoptic-scale systems to the transport and accumulation of pollutants can be investigated successfully if the short-term fluctuations (i.e. weather-induced variations) embedded in the time series of pollutant concentrations are separated from the original time series. The spatial short-term correlation coefficients for Al, Br, Fe, Se, and Zn permit good predictions of pollutant concentrations up to distances of about 350 km from a given monitor. The species correlation matrices for individual sites reveal that As, Br, Se, and Zn are highly correlated in New York State, while Fe, Mn, and V show also strong correlations, suggesting the commonality of source regions for these industrial and urban pollutants impacting New York.     

Quantification of the influence of life cycle parameters on the total environmental impact of steel-framed buildings

Due to the increased urgency with which environmental issues are currently being prioritized, business sectors such as construction, that have been identified as one of the largest consumers of raw materials and energy, are actively involved in research aiming to optimize construction processes and products in terms of environmental impact. Although researchers have pointed out various issues and aspects of a construction project’s delivery process that can significantly affect its environmental impact, the extent to which these issues can influence the total environmental impact of the project is unclear. The current research aims to investigate and eventually quantify the influence of a number of such parameters, utilizing an existing steel-framed building as the basis for the necessary calculations. The conclusions drawn illustrate the actual extent of the influence of the examined life cycle parameters, while also offering specific insight in regard to the determination of criteria that can be used as the basis for recommendations for similar projects.     

Measurements of benzene and formaldehyde in a medium sized urban environment. Indoor/outdoor health risk implications on special population groups

In the present study, the results of a measurement campaign aiming to assess cancer risk among two special groups of population: policemen and laboratory technicians exposed to the toxic substances, benzene and formaldehyde are presented. The exposure is compared to general population risk. The results show that policemen working outdoor (traffic regulation, patrol on foot or in vehicles, etc.) are exposed at a significantly higher benzene concentration (3-5 times) than the general population, while the exposure to carbonyls is in general lower. The laboratory technicians appear to be highly exposed to formaldehyde while no significant variation of benzene exposure in comparison to the general population is recorded. The assessment revealed that laboratory technicians and policemen run a 20% and 1% higher cancer risk respectively compared to the general population. Indoor working place air quality is more significant in assessing cancer risk in these two categories of professionals, due to the higher Inhalation Unit Risk (IUR) of formaldehyde compared to benzene. Since the origin of the danger to laboratory technicians is clear (use of chemicals necessary for the experiments), in policemen the presence of carbonyls in indoor air concentrations due to smoking or used materials constitute a danger equal to the exposure to traffic originated air pollutants.     

A Budget Model to Scale Nutrient Biogeochemical Cycles in Two Semienclosed Gulfs

The nutrient dynamics of the Strymonikos and Ierissos Gulfs, two semienclosed coastal water bodies, are studied using a simple steady-state budget model, according to the Land–Ocean Interaction in the Coastal Zone modeling guidelines. Strymon river plume dynamics prevailed in the area of the Inner and Outer Srymonikos Gulfs, comprising two layers, while the Ierissos Gulf was defined as a one-box system. Seasonal and mean annual model input data for river discharge, precipitation, evaporation, and concentrations of salt, phosphorus, and nitrogen were obtained during four field campaigns. Results from the nitrogen and phosphorus cycling revealed the importance of river discharge in the horizontal and vertical transport of these substances within the system. Furthermore, it occurred that the major biogeochemical transformation of nitrogen and phosphorus takes place in the immediate nearshore zone (Inner Strymonikos Gulf), while the outer system sustains its nutrient dependence on oceanic exchanges. Therefore, under the summer low flow conditions, the river-influenced inner system acts as a net source of nitrogen and phosphorus, while under increased Strymon River discharge, phosphorus is transferred to the biological material (and the sediments), and the system moves to an autotrophic state. The outer system showed an opposite behavior being autotrophic throughout the year and heterotrophic in February. The Ierissos Gulf, a system not directly influenced by significant river discharge, experienced a seasonally independent behavior with net heterotrophic and denitrification processes prevailing. Model scenarios demonstrated that phosphate concentration increases, even under low river flow conditions and stimulates primary production in excess of respiration, resulting in nitrogen fixation prevalence in the Inner Strymonikos Gulf.