Assessment and prediction of exposure to benzene of filling station employees

In the present study, the exposure to benzene of employees working in two filling stations (one urban and one rural) was estimated, through the method of passive sampling. Additional data (30′ measurements of benzene exposure through active sampling to employees dealing with different activities, meteorological and traffic data) were collected. The measurements campaign was performed in both summer and wintertime to determine the seasonal variation of the exposure pattern.In addition, a set of artificial neural networks (ANNs) was developed to predict benzene exposure pattern for the filling station employees based on active sampling data and the parameters related to the employees’ exposure. The quantification of the contribution of each parameter to the overall exposure pattern was also attempted.The results showed that although vapour recovery technologies are installed in the refuelling systems and benzene emissions are significantly reduced compared to the past, filling station employees are still highly exposed to benzene (52–15 μg m⁻³). Benzene exposure is strongly correlated to car refuelling (exposure levels up to 85 μg m⁻³), while activities like car washing or working in cash machine inside an office contribute to lower exposure levels (up to 44 and 24 μg m⁻³ respectively). In rural filling station, exposure levels were in general lower compared to the urban ones, due to the smaller amount of gasoline that was traded and the absence of any significant traffic effect or urban background concentration. The developed ANN seemed to be a promising technique in the prediction of the exposure pattern giving very good results, and the quantification of the parameters affirmed the importance of the refueling procedure to the exposure levels.     

Revisiting the elemental composition and the calorific value of the organic fraction of municipal solid wastes

In this work, the elemental content (C, N, H, S, O), the organic matter content and the calorific value of various organic components that are commonly found in the municipal solid waste stream were measured. The objective of this work was to develop an empirical equation to describe the calorific value of the organic fraction of municipal solid waste as a function of its elemental composition. The MSW components were grouped into paper wastes, food wastes, yard wastes and plastics. Sample sizes ranged from 0.2 to 0.5 kg. In addition to the above individual components, commingled municipal solid wastes were sampled from a bio-drying facility located in Crete (sample sizes ranged from 8 to 15 kg) and were analyzed for the same parameters. Based on the results of this work, an improved empirical model was developed that revealed that carbon, hydrogen and oxygen were the only statistically significant predictors of calorific value. Total organic carbon was statistically similar to total carbon for most materials in this work. The carbon to organic matter ratio of 26 municipal solid waste substrates and of 18 organic composts varied from 0.40 to 0.99. An approximate chemical empirical formula calculated for the organic fraction of commingled municipal solid wastes was C₃₂NH₅₅O₁₆.     

Spatial typologies of Greek coastal zones and unregulated Urban growth

Coastal zones attract a large number of people and productive activities. This puts pressure on ecosystems and affects the organization of local economies, having an impact on social cohesion and coherence. The complexity of coastal socio-spatial systems and the fact that coastal zones, and, more particularly, islands that are considered vulnerable areas (that is, parameters: such as sea level rising, desertification, built-up areas excessive expansion etc) and important for the overall operation of the state imply the significance of a further study of the subject. The paper deals with the principal socio-spatial pressures on coastal zones and islands that are caused by unregulated urban growth. The incompetent spatial planning framework, the “loose” political system, related to urban growth, and the socio-economical characteristics are considered as the principal reasons for built-up areas excessive dispersion. Here, delineation of the coastal zone is proposed, using physico-geographical and man-made variables. Soil Sealing dataset is used to illustrate where built-up areas dispersion and basic metrics can be applied. Furthermore, an overview of the planning spatial framework is attempted, so that the particularities of urban growth can be interpreted.     

The Narrative Cycle of Climate Change in the Greek Newspapers, 2001–2008

This paper aims to establish whether the longitudinal framing of climate change (CC) in Greek newspapers exhibits the characteristics of a “narrative cycle,” with different themes becoming prominent at different periods in accordance with the media’s narrative considerations. In order to test this assumption, we formulate a number of hypotheses which we test with data originating from three Greek newspapers over the period 2001–2008. We find that the scientific and ecological/meteorological themes of CC are more often mentioned during the initial phase of media coverage, arguably due to media’s attempt to open the narrative and capture the public’s attention. Public protests and debate feature more prominently during the peaked phase of coverage, in accordance with the narrative need for a climax, while the later period of coverage, when some kind of resolution to the story should be offered, is characterized by the prominence of policy-making and economy-related issues.     

Biogas upgrading to methane and removal of volatile organic compounds in a system of zero-valent iron and anaerobic granular sludge

Environmental Science and Pollution Research - The current study presented a novel process of biogas upgrading to biomethane (higher than 97%) based on anaerobic sludge and zero-valent iron (ZVI)...     

Wastewater substrate disinfection for cyanobacteria cultivation as tertiary treatment

Environmental Science and Pollution Research - Cultivation of microalgae or/and cyanobacteria in nutrient-rich wastewaters offers an opportunity for enhancing sustainability of tertiary wastewater...     

Coastal landscape and the Greek spatial planning: evidence from windpower in the South Aegean islands

This paper discusses issues about the coastal and the insular landscape integration in the Greek spatial planning framework. Case study area is the region of the South Aegean, where the proliferation of wind turbines is one of the principal factors of landscape change. The methodological approach adopted is mainly quantitative and is based on viewshed analysis. This paper is also demonstrates that zones with varying impact on landscape can be identified. It also emerges that the spatial planning framework in Greece promotes an ad hoc project-led instead of a plan-based approach to coastal and insular landscape management.