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851.
Alecos Demetriades Xiangdong Li Michael H. Ramsey Iain Thornton 《Environmental geochemistry and health》2010,32(6):529-552
In the Lavrion urban area study, Hellas, a five-step sequential extraction method was applied on samples of ‘soil’ (n = 224), affected by long-term mining and metallurgical activities, and house dust (n = 127), for the purpose of studying the potential bioaccessibility of lead and other metals to humans. In this paper, the
Pb concentrations in soil and house dust samples are discussed, together with those in rocks and children’s blood. Lead is
mainly associated with the carbonate, Fe–Mn oxides and residual fractions in soil and house dust. Considering the very low
pH of gastric fluids (1–3), a high amount of metals, present in soil (810–152,000 mg/kg Pb) and house dust (418–18,600 mg/kg Pb),
could be potentially bioaccessible. Consequently, children in the neighbourhoods with a large amount of metallurgical processing
wastes have high blood-Pb concentrations (5.98–60.49 μg/100 ml; median 17.83 μg/100 ml; n = 235). It is concluded that the Lavrion urban and sub-urban environment is extremely hazardous to human health, and the
Hellenic State authorities should urgently tackle this health-related hazard in order to improve the living conditions of
local residents. 相似文献
852.
Jiang He Chang-Wei Lü Hong-Xi Xue Ying Liang Saruli Bai Ying Sun Li-Li Shen Na Mi Qing-Yun Fan 《Environmental geochemistry and health》2010,32(1):45-58
This paper analyses the contents and species distributions of rare earth elements (REEs) in the water-suspended particulate-sediment
system of the Baotou section of the Yellow River, China, with known anthropogenic REE input from industrial discharges. The
major forms of REEs were suspended and dissolved in the mainstream and the tributaries of the Baotou section, respectively.
The concentrations of the dissolved and suspended REEs had the same trends in the overlying water along the mainstream, which
increased from the Seqi section (site A) to the mouth of the Sidaosha River (site D), reaching a maximum value at site D,
and tending to decrease thereafter. The contents of REEs in sediment cores showed enrichment with light rare earth elements
(LREEs). The bound to carbonates and to Fe–Mn oxides are the major forms of REE in the secondary phase and the REE exhibited
LREE enrichment pattern and moderate Eu depletion in suspended particulates and surface sediments. The contents and species
distributions of REEs in the water-suspended particulate-sediment system of the Baotou section suggest that the anthropogenic
source of REEs from Baotou city have enhanced REE accumulation to the Baotou section. This information is important for predicting
possible pollution resulting from anthropogenic REE input into rivers. 相似文献
853.
Hydrogeochemical considerations about the origin of groundwater salinization in some coastal plains of Elba Island (Tuscany,Italy) 总被引:1,自引:0,他引:1
Elena Giménez-Forcada Alberto Bencini Giovanni Pranzini 《Environmental geochemistry and health》2010,32(3):243-257
Several coastal plains of the Elba Island (Marina di Campo, Portoferraio, Schiopparello, Mola, Porto Azzurro and Barbarossa
plains) in Tuscany (Italy) were studied to determine the causes of decline in groundwater quality, using major ion chemistry
to establish the causes of groundwater salinization. The study demonstrates that salinization of coastal plain alluvial aquifers
is not simply linked to seawater intrusion but is also intimately related to inflows from adjacent aquifers. Ionic ratios,
correlation graphs and distribution value maps were employed as the means to understand the hydrochemistry of the study areas.
The Mg/Cl ratio in particular can be considered a good tracer to distinguish the main salinization processes that control
groundwater chemistry. Seawater intrusion only partly determines the chemistry of some groundwaters, which generally belong
to a chloride facies where the salinity is derived principally from freshwater–seawater mixing and the participation of cation
exchange. Proceeding inland groundwater quality seems to be principally determined by the inflow of Mg, Ca-HCO3 or Ca, Na-HCO3 waters formed from the weathering of silicate minerals in adjoining aquifers. Hydrolysis of these minerals is of prime importance
in controlling groundwater chemistry in adjacent alluvial plains. The lateral recharge flows introduce water with a different
chemical composition and this variable of freshwater recharge changes the hydrochemistry as a result of mixing between two
or more waters types. This situation is further complicated when seawater and base exchange reactions participate, due to
seawater intrusion. 相似文献
854.
Ryoko Fujiyoshi Yukihide Haraki Takashi Sumiyoshi Hikaru Amano Ivan Kobal Janja Vaupotič 《Environmental geochemistry and health》2010,32(1):73-82
Radon (222Rn) and carbon dioxide were monitored simultaneously in soil air under a cool-temperate deciduous stand on the campus of Hokkaido
University, Sapporo, Japan. Both 222Rn and CO2 concentrations in soil air varied with atmospheric (soil) temperature in three seasons, except for winter when the temperature
in soil air remained constant at 2–3°C at depth of 80 cm. In winter, the gaseous components were influenced by low-pressure
region passing through the observation site when the ground surface was covered with snow of ~1 m thickness. Carbon isotopic
analyses of CO2 suggested that CO2 in soil air may result from mixing of atmospheric air and soil components of different origins, i.e. CO2 from contemporary soil organic matter and old carbon from deeper source, to varying degrees, depending on seasonal meteorological
and thus biological conditions. 相似文献
855.
Arsenic (As) contamination has become a serious environmental problem in many countries. We have performed batch-type leaching
experiments on mine tailing soils collected from three abandoned mine areas in South Korea with the objective of evaluating
the effect of indigenous bacterial activity on As mobilization. The analysis of physicochemical properties and mineralogical
compositions of the samples indicated that the secondary minerals or phases formed as a result of the oxidation or alteration
of primary minerals were associated with the labile and bioleachable fractions of As. Compared to simulated abiotic processes
using sterilization, the indigenous bacteria activated using a carbon source were able to enhance the dissolution of As under
both aerobic and anaerobic conditions. The bacterial dissolution of iron (Fe) and manganese (Mn) was found to occur simultaneously
with the dissolution of As, suggesting that the main bacterial mechanism was via the dissimilatory reduction of Fe(III),
Mn(IV), and As(V). An anaerobic environment was more favorable for the prominent dissolution of As in the tailing soils. These
results indicate that the mobilization of As can be enhanced in the oxygen-depleted part of the tailing dump, particularly
with the infiltration of organic substrates. The difference in the degree of As lixiviation between the three tailing soils
was found to be related to the bioavailability of As as well as the original biomass in the tailing soils. 相似文献
856.
Enver Guler Deniz Ozakdag Muserref Arda Mithat Yuksel Nalan Kabay 《Environmental geochemistry and health》2010,32(4):335-339
The effect of feed seawater temperature on the quality of product water in a reverse osmosis process was investigated using
typical seawater at Urla Bay, Izmir region, Turkey. The tests were carried out at different feed seawater temperatures (11–23°C)
using two RO modules with one membrane element each. A number of variables, including pH, conductivity, total dissolved solids,
salinity, rejection percentage of a number of ions (Na+, K+, Ca2+, Mg2+, Cl−, HCO3
−, and SO4
2−), and the levels of boron and turbidities in collected permeates, were measured. The suitability of these permeates as irrigation
and drinking water was checked by comparison with water quality standards. 相似文献
857.
Anthropogenic influence on surface water quality of the Nhue and Day sub-river systems in Vietnam 总被引:2,自引:0,他引:2
Pham Thi Minh Hanh Suthipong Sthiannopkao Kyoung-Woong Kim Dang The Ba Nguyen Quang Hung 《Environmental geochemistry and health》2010,32(3):227-236
In order to investigate the temporal and spatial variations of 14 physical and chemical surface water parameters in the Nhue
and Day sub-river systems of Vietnam, surface water samples were taken from 43 sampling sites during the dry and rainy seasons
in 2007. The results were statistically examined by Mann–Whitney U-test and hierarchical cluster analysis. The results show that water quality of the Day River was significantly improved during
the rainy season while this was not the case of the Nhue River. However, the river water did not meet the Vietnamese surface
water quality standards for dissolved oxygen (DO), biological oxygen demand (BOD5), chemical oxygen demand (COD), nutrients, total coliform, and fecal coliform. This implies that the health of local communities
using untreated river water for drinking purposes as well as irrigation of vegetables may be at risk. Forty-three sampling
sites were grouped into four main clusters on the basis of water quality characteristics with particular reference to geographic
location and land use and revealed the contamination levels from anthropogenic sources. 相似文献
858.
João Paulo Silva Author Vitae Mário Santos Author Vitae Author Vitae Domingos Leitão Author Vitae Author Vitae Márcia Pinto Author Vitae Author Vitae João Alexandre Cabral Author Vitae 《Ecological modelling》2010,221(16):1954-1963
Collision with conductors and earth cables is a known impact generated by transmission power lines, however there is virtually no information on how these infrastructures might affect bird distribution in a landscape context. With this work we specifically hypothesise that transmission power lines may affect the occurrence of a threatened bird, the little bustard (Tetrax tetrax). To test this hypothesis we used a Stochastic Dynamic Methodology (StDM), analysing the effects of power lines in a landscape perspective and simulating population trends as a response to power line installation and habitat changes induced by agricultural shifts in southern Portugal. The data used in the dynamic model construction included relevant gradients of environmental conditions and was sampled during the breeding seasons of 2003-2006. Transmission power lines were significantly avoided by the little bustard and the developed StDM model showed that the distance to these utility structures is the most important factor determining breeding densities in sites with suitable habitat for the species, which possibly leads to displacement of populations and habitat fragmentation. The model simulations also provided the base to analyse the cumulative effects caused by the habitat degradation that can ultimately lead to the extinction of local populations. Within priority conservation sites, the dismantling of existing transmission lines should be considered whenever possible, in order to ensure adequate breeding habitat. The model is considered useful as an auxiliary tool to be used in environmental impact assessments, management and conservation studies. 相似文献
859.
Increasing polybrominated diphenyl ether (PBDE) contamination in sediment cores from the inner Clyde Estuary,UK 总被引:1,自引:0,他引:1
Christopher H. Vane Yun-Juan Ma She-Jun Chen Bi-Xian Mai 《Environmental geochemistry and health》2010,32(1):13-21
The concentrations of 16 polybrominated diphenyl ether (PBDE) congeners in six short sediment cores from the Clyde Estuary
were determined by gas-chromatography mass-spectrometry. Total PBDE concentrations ranged from 1 to 2,645 μg/kg and the average
concentration was 287 μg/kg. BDE-209 was the main congener and varied from 1 to 2,337 μg/kg. Elevated total PBDE concentrations
were observed close to the sediment surface in the uppermost 10 cm of four of the six sediment cores. Comparison of the down
core PBDE profiles revealed that the increase was driven by the accumulation of deca-BDE. Although the deca-BDE mix was dominant,
the presence of lower molecular weight congeners BDE-47, BDE-99, BDE-183 and BDE-153 at most sediment intervals suggested
additional sources of penta-BDE and octa-BDE pollution. Changing PBDE source input was the major factor in influencing the
proportion of nona-brominated congeners, although other explanations such as post burial photo-debromination of BDE-209 cannot
be entirely discounted. A clear cascading to lower hepta-, hexa-, and penta-homologues was not found. The increase in total
PBDE concentrations and particularly the deca-BDE may possibly be ascribed to the use and subsequent disposal of electrical
appliances such as televisions and computers. In the Clyde sediments, the proportion of nona-brominated congeners was higher
than that reported for commercial mixtures. This might be due to changing sources of PBDEs or post burial photo-debromination
of BDE-209. 相似文献
860.
Karsten Seidelmann Karin Ulbrich Norbert Mielenz 《Behavioral ecology and sociobiology》2010,64(3):337-347
Trivers' and Willard's hypothesis that natural selection favors sex allocation in relation to maternal condition assumes iteropary.
Though this assumption is not met in most solitary Aculeata, the reproductive life span of semelparous females may be divided
into discrete successive cycles by the risk of open-cell parasitism. Females can avoid losing their investment to parasites
attacking the open cell only by limiting the provision time for each cell. The restriction of time available for the investment
in a single progeny irrespective of the condition of the female leads to de facto iteropary. Moreover, in Hymenoptera, there
are no costs for sex allocation due to the haplodiploid mode of sex determination. In sexually size dimorphic species, females
in poor condition are predicted to invest in the smaller sex and vice versa. The resulting prediction of a conditional sex
allocation in solitary Aculeata was tested in the Red Mason bee, Osmia rufa (Osmia bicornis), a stem or hole-nesting, polylectic, univoltine megachilid bee. Body size is a key component of condition in females of
nest-constructing solitary bees. Large females collect the same amount of pollen and nectar in a shorter time than small ones
and should suffer less from parasitism. We found that small females dealt with their handicap of a low provisioning performance
by shifting the sex ratio toward sons (the smaller sex) and by reducing the body size of daughters. Large females, however,
shifted their offspring sex ratio toward daughters, the sex that depends more on body size in its reproductive value. The
sex ratio in the population met the expected Fisherian sex ratio. Although females allocated their investment in the sexes
according to their body mass, the population-level investment was balanced. 相似文献