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431.
Julia Menegotto Frick Alan Ambrosi Liliane Damaris Pollo Isabel Cristina Tessaro 《Journal of Polymers and the Environment》2018,26(7):2748-2757
Depending on the modifications proposed, chitosan films present different characteristics, for instance correlated to hydrophilicity, chemical and mechanical properties. The aim of this study was to evaluate the influence of glutaraldehyde crosslinking and an alkaline post-treatment with NaOH on the characteristics of chitosan based films. Films were obtained by casting and characterized by thickness, swelling degree, mechanical and thermal properties and chemical structure. The water vapor permeability (WVP) was also evaluated for food packaging application. It was observed that crosslinking and NaOH post-treatment have great influence on the chitosan films characteristics. Crosslinking reduced the swelling degree of films and increased its fragility, whereas NaOH treatment also reduces the swelling degree and changes mechanical properties, acting in the same way as a crosslinker. The WVP analyses showed that the basic treatment could substitute the glutaraldehyde crosslinking for film water stability, without greatly compromising the barrier properties of chitosan based films. 相似文献
432.
Degradation of phenols in olive oil mill wastewater by biological,enzymatic, and photo-Fenton oxidation 总被引:1,自引:0,他引:1
Celine Justino Ana Gabriela Marques Kátia Reis Duarte Armando Costa Duarte Ruth Pereira Teresa Rocha-Santos Ana Cristina Freitas 《Environmental science and pollution research international》2010,17(3):650-656
Background, aim, and scope
Olive oil mill wastewater (OOMW) environmental impacts minimization have been attempted by developing more effective processes, but no chemical or biological treatments were found to be totally effective to mitigate their impact on receiving systems. This work is the first that reports simultaneously the efficiency of three different approaches: biological treatment by two fungal species (Trametes versicolor or Pleurotus sajor caju), enzymatic treatment by laccase, and chemical treatment by photo-Fenton oxidation on phenols removal. 相似文献433.
Malinowska Izabela Kubica Paweł Madajski Piotr Ostrowski Adam Gómez Polo Cristina Carvera Laura Bednarski Waldemar Zielińska-Jurek Anna 《Environmental science and pollution research international》2023,30(13):35929-35944
Environmental Science and Pollution Research - In this study, we report the potential of 2D/2D TiO2-GO-ZnFe2O4 photocatalyst obtained using the fluorine-free lyophilization technique for the... 相似文献
434.
Costs of the electrochemical oxidation of wastewaters: a comparison with ozonation and Fenton oxidation processes 总被引:2,自引:0,他引:2
In the work described here the technical and economic feasibilities of three Advanced Oxidation Processes (AOPs) have been studied: Conductive-Diamond Electrochemical Oxidation (CDEO), Ozonation and Fenton oxidation. The comparison was made by assessing the three technologies with synthetic wastewaters polluted with different types of organic compounds and also with actual wastes (from olive oil mills and from a fine-chemical manufacturing plant). All three technologies were able to treat the wastes, but very different results were obtained in terms of efficiency and mineralization. Only CDEO could achieve complete mineralization of the pollutants for all the wastes. However, the efficiencies were found to depend on the concentration of pollutant (mass transfer control of the oxidation rate). Results obtained in the oxidation with ozone (at pH 12) or by Fenton's reagent were found to depend on the nature of the pollutants, and significant concentrations of oxidation-refractory compounds were usually accumulated during the treatment. Within the discharge limits that all of the technologies can reach, the economic analysis shows that the operating cost of Fenton oxidation is lower than either CDEO or ozonation, although CD\EO can compete satisfactorily with the Fenton process in the treatment of several kinds of wastes. Likewise, the investment cost for the ozonation process seems to be higher than either CDEO or Fenton oxidation, regardless of the pollutant treated. 相似文献
435.
Influence of support material on the immobilization of biomass for the degradation of linear alkylbenzene sulfonate in anaerobic reactors 总被引:1,自引:0,他引:1
Lima de Oliveira L Silveira Duarte IC Sakamoto IK Amâncio Varesche MB 《Journal of environmental management》2009,90(2):1261-1268
Two horizontal-flow anaerobic immobilized biomass reactors (HAIB) were used to study the degradation of the LAS surfactant: one filled with charcoal (HAIB1) and the other with a mixed bed of expanded clay and polyurethane foam (HAIB2). The reactors were fed with synthetic substrate supplemented with 14 mg l(-1)of LAS, kept at 30+/-2 degrees C and operated with a hydraulic retention time (HRT) of 12h. The surfactant was quantified by HPLC. Spatial variation analyses were done to quantify organic matter and LAS consumption along the reactor length. The presence of the surfactant in the load did not affect the removal of organic matter (COD), which was close to 90% in both reactors for an influent COD of 550 mg l(-1). The results of a mass balance indicated that 28% of all LAS added to HAIB1 was removed by degradation. HAIB2 presented 27% degradation. Molecular biology techniques revealed microorganisms belonging the uncultured Holophaga sp., uncultured delta Proteobacterium, uncultured Verrucomicrobium sp., Bacteroides sp. and uncultured gamma Proteobacterium sp. The reactor with biomass immobilized on charcoal presented lower adsorption and a higher kinetic degradation coefficient. So, it was the most suitable support for LAS anaerobic treatment. 相似文献
436.
A procedure based on solid-phase microextraction (SPME) and gas chromatography coupled with mass spectrometry (GC-MS) was developed and validated in order to analyse 10 phenols in water samples. The optimised conditions were obtained using polyacrylate fibre (PA), 20ml of sample volume, 10% NaCl, pH 4.0 and direct extraction at 35 degrees C and 1000rpm, for 40min. The linear range and quantification limits for these compounds by SPME-GC-MS were defined. An evaluation of the main uncertainty sources of this method is included, which allows expanded uncertainties in the 9.4-35% range for the majority of the compounds. The main source of uncertainty is associated with matrix effects. The validated method is suitable for monitoring the production and distribution of potable water and was used, in field trials, for the analysis of samples from main intakes of water (surface or underground) and from water supply system of a large area (Lisbon and neighbour municipalities). 相似文献
437.
Two Fagus sylvatica L. clones were used to investigate the early responses to acute O3 exposure (150 nL L−1, i.e., 1.35× ambient hourly peak in rural Italy) and whether xeromorphic adaptations affect gas exchange, membrane, and epicuticular
responses. One clone originated in a wet and temperate climate in Central Italy (Tuscany); the other clone originated in a
warmer and drier climate in the southern-most part of the F. sylvatica distribution (Sicily). Because of higher base gas exchange rates, the most negative effects of O3 exposure (gas exchange impairment, uncoupling between net photosynthesis and stomatal conductance, increased membrane lipid
peroxidation) were found in the southern clone. Xeromorphic adaptations (higher epicuticular waxes and stomatal density, lower
leaf wettability and size) were found in this clone. Our results suggest that xeromorphism may increase O3 sensitivity in species not adapted to face water stress, like the mesophilic F. sylvatica, when experiments are carried out with full irrigation. We present evidence describing the relationship between gas exchange
and number and status of stomata. Stomatal density and the structural damage to stomata resulting from O3 exposure did not affect gas exchange: In fact, non-stomatal limitations to photosynthesis prevailed over stomatal limitations. 相似文献
438.
An educational project on biological monitoring of air quality was launched in 2004 to involve about 650 young students (age
6 to 16) from 21 schools of nine municipalities in Tuscany (Central Italy) in active detection of the crucial pollutant ozone
with indicator sensitive tobacco seedlings. Results implied the reading of 9,300 raw biological figures and were fortified
by the data captured by six photometric analysers. Under the guidance of their teachers, the students had several opportunities
to practice with many basic and applied study areas and were initiated into the scientific method in a simple and absorbing
manner. Curiosity and involvement were widespread; a sort of emotional and responsible relationship was developed by several
pupils. Though primarily an educational exercise, the survey introduced a research element and the regional picture of air
pollution that emerged has increased our knowledge of the air quality situation in the area. Biological monitoring of air
quality is a powerful tool to improve the awareness and involvement in key topics of environmental education. In addition,
it represents a crucial element for improving the awareness of problems and implies the active participation of citizens in
the assessment of several indicators of the state of the environment. Its potential as a robust implement in landscape and
urban planning is noteworthy. 相似文献
439.
Köhler HR Sandu C Scheil V Nagy-Petrică EM Segner H Telcean I Stan G Triebskorn R 《Environmental monitoring and assessment》2007,127(1-3):47-54
Along a downstream stretch of River Mureş, Romania, adult males of two feral fish species, European chub (Leuciscus cephalus) and sneep (Chondrostoma nasus) were sampled at four sites with different levels of contamination. Fish were analysed for the biochemical markers hsp70
(in liver and gills) and hepatic EROD activity, as well as several biometrical parameters (age, length, wet weight, condition
factor). None of the biochemical markers correlated with any biometrical parameter, thus biomarker reactions were related
to site-specific criteria. While the hepatic hsp70 level did not differ among the sites, significant elevation of the hsp70
level in the gills revealed proteotoxic damage in chub at the most upstream site, where we recorded the highest heavy metal
contamination of the investigated stretch, and in both chub and sneep at the site right downstream of the city of Arad. In
both species, significantly elevated hepatic EROD activity downstream of Arad indicated that fish from these sites are also
exposed to organic chemicals. The results were indicative of impaired fish health at least at three of the four investigated
sites. The approach to relate biomarker responses to analytical data on pollution was shown to fit well the recent EU demands
on further enhanced efforts in the monitoring of Romanian water quality. 相似文献
440.