全文获取类型
收费全文 | 12542篇 |
免费 | 79篇 |
国内免费 | 33篇 |
专业分类
安全科学 | 159篇 |
废物处理 | 887篇 |
环保管理 | 1988篇 |
综合类 | 1200篇 |
基础理论 | 3802篇 |
环境理论 | 2篇 |
污染及防治 | 2431篇 |
评价与监测 | 1177篇 |
社会与环境 | 987篇 |
灾害及防治 | 21篇 |
出版年
2023年 | 19篇 |
2022年 | 21篇 |
2021年 | 34篇 |
2020年 | 38篇 |
2019年 | 42篇 |
2018年 | 1514篇 |
2017年 | 1414篇 |
2016年 | 1280篇 |
2015年 | 191篇 |
2014年 | 91篇 |
2013年 | 327篇 |
2012年 | 561篇 |
2011年 | 1484篇 |
2010年 | 809篇 |
2009年 | 715篇 |
2008年 | 1011篇 |
2007年 | 1353篇 |
2006年 | 145篇 |
2005年 | 104篇 |
2004年 | 152篇 |
2003年 | 171篇 |
2002年 | 188篇 |
2001年 | 74篇 |
2000年 | 63篇 |
1999年 | 52篇 |
1998年 | 51篇 |
1997年 | 46篇 |
1996年 | 50篇 |
1995年 | 63篇 |
1994年 | 42篇 |
1993年 | 42篇 |
1992年 | 26篇 |
1991年 | 32篇 |
1990年 | 37篇 |
1989年 | 26篇 |
1988年 | 30篇 |
1987年 | 28篇 |
1986年 | 38篇 |
1985年 | 21篇 |
1984年 | 46篇 |
1983年 | 39篇 |
1982年 | 31篇 |
1981年 | 32篇 |
1980年 | 20篇 |
1979年 | 18篇 |
1978年 | 12篇 |
1977年 | 11篇 |
1976年 | 10篇 |
1974年 | 9篇 |
1972年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 359 毫秒
881.
Jason A. Dittman James B. Shanley George R. Aiken Janet E. Towse 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from all sites, we found a strong positive correlation of THgd to DOC (r2 = 0.87), but progressively stronger correlations of THgd with the hydrophobic acid fraction (HPOA) of DOC (r2 = 0.91) and with UV254 absorbance (r2 = 0.92). The strength of the UV254 absorbance-THgd relationship suggests that optical properties associated with dissolved organic matter may be excellent proxies for THgd concentration in these streams. Ease of sample collection and analysis, the potential application of in-situ optical sensors, and the possibility for intensive monitoring over the hydrograph make this an effective, inexpensive approach to estimate THgd flux in drainage waters. 相似文献
882.
Marc Soutter Maria Alexandrescu Colin Schenk Radu Drobot 《Environmental science and pollution research international》2009,16(1):33-41
Background, aim, and scope
The need for global and integrated approaches to water resources management, both from the quantitative and the qualitative point of view, has long been recognized. Water quality management is a major issue for sustainable development and a mandatory task with respect to the implementation of the European Water Framework Directive as well as the Swiss legislation. However, data modelling to develop relational databases and subsequent geographic information system (GIS)-based water management instruments are a rather recent and not that widespread trend. The publication of overall guidelines for data modelling along with the EU Water Framework Directive is an important milestone in this area. Improving overall water quality requires better and more easily accessible data, but also the possibility to link data to simulation models. Models are to be used to derive indicators that will in turn support decision-making processes. For this whole chain to become effective at a river basin scale, all its components have to become part of the current daily practice of the local water administration. Any system, tool, or instrument that is not designed to meet, first of all, the fundamental needs of its primary end-users has almost no chance to be successful in the longer term.Materials and methods
Although based on a pre-existing water resources management system developed in Switzerland, the methodological approach applied to develop a GIS-based water quality management system adapted to the Romanian context followed a set of well-defined steps: the first and very important step is the assessment of needs (on the basis of a careful analysis of the various activities and missions of the water administration and other relevant stakeholders in water management related issues). On that basis, a conceptual data model (CDM) can be developed, to be later on turned into a physical database. Finally, the specifically requested additional functionalities (i.e. functionalities not provided by classical commercial GIS software), also identified during the assessment of needs, are developed. This methodology was applied, on an experimental basin, in the Ialomita River basin.Results
The results obtained from this action-research project consist of a set of tangible elements, among which (1) a conceptual data model adapted to the Romanian specificities regarding water resources management (needs, data availability, etc.), (2) a related spatial relational database (objects and attributes in tables, links, etc.), that can be used to store the data collected, among others, by the water administration, and later on exploited with geographical information systems, (3) a toolbar (in the ESRI environment) offering the requested data processing and visualizing functionalities. Lessons learned from this whole process can be considered as additional, although less tangible, results.Discussion
The applied methodology is fairly classical and did not come up with revolutionary results. Actually, the interesting aspects of this work are, on the one hand, and obviously, the fact that it produced tools matching the needs of the local (if not national) water administration (i.e. with a good chance of being effectively used in the day-to-day practice), and, on the other hand, the adaptations and adjustments that were needed both at the staff level and in technical terms.Conclusions
This research showed that a GIS-based water management system needs to be backed by some basic data management tools that form the necessary support upon which a GIS can be deployed. The main lesson gained is that technology transfer has to pay much attention to the differences in existing situations and backgrounds in general, and therefore must be able to show much flexibility. The fact that the original objectives could be adapted to meet the real needs of the local end-users is considered as a major aspect in achieving a successful adaptation and development of water resources management tools. Time needed to setup things in real life was probably the most underestimated aspect in this technology transfer process.Recommendations and perspectives
The whole material produced (conceptual data model, database and GIS tools) was disseminated among all river basin authorities in Romania on the behalf of the national water administration (ANAR). The fact that further developments, for example, to address water quantity issues more precisely, as envisaged by ANAR, can be seen as an indication that this project succeeded in providing an appropriate input to improve water quality in Romania on the long term.883.
Claire L. Martin Ian D. Longley James R. Dorsey Rick M. Thomas Martin W. Gallagher Eiko Nemitz 《Atmospheric environment (Oxford, England : 1994)》2009,43(31):4714-4721
Little information is known about the behaviour of ultrafine particles (UFP) on a citywide scale. Total particle number flux, dominated by UFP, and other meteorological parameters were collected from tower sites in Manchester, London, Edinburgh and Gothenburg between 1999 and 2006 using the eddy covariance technique. Averaged diurnal cycles were produced for particle number flux, concentration, sensible heat flux, emission velocity, friction velocity, wind speed and temperature. UFP flux cycles showed clear diurnal trends which were linked to traffic activity and local sources. Wind sector analysis showed contributions to flux from local heavily urbanised areas. A simple parameterised model linking UFP flux to traffic activity, sensible heat and friction velocity above the city was produced. 相似文献
884.
Elizabeth A. Stone Curtis J. Hedman Rebecca J. Sheesley Martin M. Shafer James J. Schauer 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4205-4213
The high-molecular weight water-soluble organic compounds present in atmospheric aerosols underwent functional-group characterization using liquid chromatography tandem mass spectrometry (LC-MS/MS), with a focus on understanding the chemical structure and origins of humic-like substances (HULIS) in the atmosphere. Aerosol samples were obtained from several locations in North America at times when primary sources contributing to organic aerosol were well-characterized: Riverside, CA, Fresno, CA, urban and peripheral Mexico City, Atlanta, GA, and Bondville, IL. Chemical analysis targeted identification and quantification of functional groups, such as aliphatic, aromatic, and bulk carboxylic acids, organosulfates, and carbohydrate-like substances that comprise species with molecular weights (MW) 200–600 amu. Measured high-MW functional groups were compared to modeled primary sources with the purpose of identifying associations between aerosol sources, high-MW aerosol species, and HULIS. Mobile source emissions were linked to high-molecular weight carboxylic acids, especially aromatic acids, biomass burning was associated with carboxylic acids and carbohydrate-like substances, and secondary organic aerosol (SOA) correlated well with the total amount of HULIS measured, whereas organosulfates showed no correlation with aerosol sources and exhibited unique spatial trends. These results suggested the importance of motor vehicles, biomass burning, and SOA as important sources of precursors to HULIS. Structural characteristics of atmospheric HULIS were compared to terrestrial humic and fulvic acids and revealed striking similarities in chemical structure, with the exception of organosulfates which were unique to atmospheric HULIS. 相似文献
885.
Zheng Li Erin N. Porter Andreas Sjödin Larry L. Needham Sangil Lee Armistead G. Russell James A. Mulholland 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4187-4193
Twenty-eight polycyclic aromatic hydrocarbons (PAH) and methylated PAHs (Me-PAH) were measured in daily PM2.5 samples collected at an urban site, a suburban site, and a rural site in and near Atlanta during 2004 (5 samples/month/site). The suburban site, located near a major highway, had higher PM2.5-bound PAH concentrations than did the urban site, and the rural site had the lowest PAH levels. Monthly variations are described for concentrations of total PAHs (∑PAHs) and individual PAHs. PAH concentrations were much higher in cold months than in warm months, with average monthly ∑PAH concentrations at the urban and suburban-highway monitoring sites ranging from 2.12 to 6.85 ng m?3 during January–February and November–December 2004, compared to 0.38–0.98 ng m?3 during May–September 2004. ∑PAH concentrations were found to be well correlated with PM2.5 and organic carbon (OC) within seasons, and the fractions of PAHs in PM2.5 and OC were higher in winter than in summer. Methyl phenanthrenes were present at higher levels than their un-substituted homologue (phenanthrene), suggesting a petrogenic (unburned petroleum products) input. Retene, a proposed tracer for biomass burning, peaked in March, the month with the highest acreage and frequency of prescribed burning and unplanned fires, and in December, during the high residential wood-burning season, indicating that retene might be a good marker for burning of all biomass materials. In contrast, potassium peaked only in December, indicating that it might be a more specific tracer for wood-burning. 相似文献
886.
Lynn M. Russell Ranjit Bahadur Lelia N. Hawkins James Allan Darrel Baumgardner Patricia K. Quinn Timothy S. Bates 《Atmospheric environment (Oxford, England : 1994)》2009,43(38):6100-6105
Organic aerosol chemical markers from normalized concentrations of independent measurements of mass fragments (using Aerosol Mass Spectrometry, AMS) are compared to bond-based functional groups (from Fourier Transform Infrared spectroscopy, FTIR) during eight field projects in the western hemisphere. Several field projects show weak correlations between alcohol group fractions and m/z 60 fractions, consistent with the organic hydroxyl groups and the fragmentation of saccharides, but the weakness of the correlations indicate chemical differences among the relationships for ambient aerosols in different regions. Carboxylic acid group fractions and m/z 44 fractions are correlated weakly for three projects, with correlations expected for aerosols dominated by di-acid compounds since their fragmentation is typically dominated by m/z 44. Despite differences for three projects with ratios of m/z 44 to m/z 57 fragments less than 10, five projects showed a linear trend between the project-average m/z 44 to m/z 57 ratio and the ratio of acid and alkane functional groups. While this correlation explains only a fraction of the fragment and bond variability measured, the consistency of this relationship at multiple sites indicates a general agreement with the interpretation of the relative amount of m/z 44 as a carboxylic acid group marker and m/z 57 as an alkane group marker. 相似文献
887.
On experimental setup in bioelectromagnetics 总被引:1,自引:1,他引:0
Bioeffects created by electromagnetic field (EMF) are the subject of intensive studies. This paper critically considers estimations
of exposure to EMF in bioelectromagnetic experiments. Results of calculations presented herein show the significant role of
the presence of conducting bodies (the exposure system) near an object under test on EMF energy absorption as well as mutual
interactions between simultaneously exposed objects. Our aims herein are twofold: firstly to find a way to refer measurement
results to free-space conditions in order to enable comparison of results obtained in different laboratories, and secondly
to show that EMF energy absorption in any exposed object is different and that this difference is a function of the size of
the exposure system, the number of exposed objects, and the particular properties (i.e., the electromagnetic structure) of
the objects. In the authors’ opinion the existence of interactions caused by the presence of the exposure system and other
exposed objects is a reason why remarkable differences are observed between experiments performed even under supposedly identical
conditions. The presented considerations and conclusion suggest wider participation of physicists and engineers in bioelectromagnetic
experiments in order to ensure the correctness of metrological aspects of these experiments. 相似文献
888.
889.
Epidemiological studies suggesting the possibility of harmful effects on human (specifically children’s leukaemia) due to
long-term exposure to magnetic fields of extremely low frequency (e.g. 50/60 Hz) and relatively low values (i.e. over the
microtesla range) have stirred high activity in the topic of magnetic field mitigation. To reduce these fields, it is common
to use passive metal screens (e.g. plates made of aluminium or steel). To design them, effective and fast numerical computations
are highly desirable. In this article, a method is presented, which computes various parameters of screens in a given shielding
problem and yields magnetic field distribution and shielding factors. The method takes into consideration the 3D field distribution
and is able to solve systems with large aspect ratios (thin thickness in comparison with its other dimensions); this is a
common problem where other methods such as finite elements often experience difficulties. The presented method computes separately
the field inside and outside the screens. Afterwards, the solutions are “stitched” together along the border of the subregions.
Two practical examples are given of the developed numerical method. 相似文献
890.
Urbanization and its impact on groundwater: a remote sensing and GIS-based assessment approach 总被引:1,自引:0,他引:1
The perils of unplanned urbanization and increasing pressure of human activities on hydro-geomorphologic system often result
in modification of the existing recharge mechanism, which leads to many environmental consequences. In the present research,
an attempt has been made to investigate the applicability of remote sensing and geographical information system (GIS) in dealing
with spatial and temporal variability of dynamic phenomena, like urbanization and its impact on groundwater. This paper covers
primarily, quantitative and qualitative impacts of urban growth on the behavior of aquifer in Ajmer city (India). Urban growth
of the Ajmer city in last 17 years has been estimated from the satellite images. Database related to urbanization and groundwater
has been created in GIS. Groundwater recharge has been computed using a water balance approach known as Water Level Fluctuation
Methodology. Recharge estimation methodology has been implemented in GIS to introduce the spatial variability of hydro-geological
characteristics. Further, temporal and spatial variations in groundwater quality and quantity have been correlated with urban
growth using overlay analysis in GIS. The study reveals a general decline in water table and quality with urbanization. Further,
remote sensing and GIS technologies have been found useful in assessment of spatial and temporal phenomena of urbanization
and its impact on groundwater system. 相似文献