Dissipation of cypermethrin,chlorpyriphos, and profenofos in tomato fruits and soil following application of pre-mix formulations

In this study, changes in heavy metal accumulation in U. rigida J. Agardh taxon and seawater have been investigated with respect to different stations and seasons. For this purpose, the severity of heavy metal pollution in the Dardanelles has been presented through the determination of Cu, Pb, Zn, and Cd concentrations in U. rigida macroalgae and seawater taken seasonally from the stations located on six different regions on the strait. While the metal concentrations in alga specimens were found to be high in spring and winter in all stations; the metal concentrations in the seawater, particularly the Pb concentration, were found to be high in all seasons.     

Sustainable approaches for steroid synthesis

Environmental Chemistry Letters - Steroids are important scaffolds for the synthesis of molecules of pharmaceutical interest and constitute a distinct family of natural products. The demand for...     

Development of Noise Simulation Model for Stationary and Mobile Sources: A GIS-Based Approach

In the rapidly urbanizing country like India, the transportation sector is growing rapidly, which lead to overcrowded roads producing air and noise pollution. Noise of a particular region is influenced by the volume of traffic on the highway, in addition to other causative factors like existing infrastructure and industrial setup etc. In the present paper, a geographical information system (GIS)-based noise simulation model has been developed to generate noise levels in Versova region of Mumbai, India. The study area comprises effect of infrastructure, road network, traffic volume, and various mechanical components like sewage pumping station and wastewater treatment facility. Various meteorological parameters and effect of land use and land cover on noise attenuation are also considered in the model. In this way, commutative noise prediction for point as well as mobile sources has been presented in the study. GIS-based noise simulation has been calibrated with observed noise levels during day and night time with correlation of 0.84 and 0.74, respectively.     

Effect of wastewater irrigation on vegetables in relation to bioaccumulation of heavy metals and biochemical changes

The present study was conducted to determine the heavy metal contamination in soil with accumulation in edible parts of plants and their subsequent changes in biochemical constituents due to wastewater irrigation. Though the wastewater contains low levels of the heavy metals (Fe, Mn, Pb, Cd, and Cr), the soil and plant samples show higher values due to accumulation. The trend of metal accumulation in wastewater-irrigated soil is in the order: Fe > Pb > Mn > Cr > Cd. Of the three species Colocasia esculentum, Brassica nigra, and Raphanus sativus that are grown, the order of total heavy metal accumulation in roots is Raphanus sativus > Colocasia esculentum, while in shoots the order is Brassica nigra > Colocasia esculentum > Raphanus sativus. The enrichment factor (EF) of the heavy metals in contaminated soil is in the sequence of Cd (3) > Mn (2.7) > Cr (1.62) > Pb (1.46) > Fe (1.44), while in plants EF varies depending upon the species and plant part. C. esculentum and R. sativus show a higher EF for Cr and Cd. All plants show a high transfer factor (TF > 1) for Cd signifying a high mobility of Cd from soil to plant whereas the TF values for Pb are very low as it is not bioavailable. Results of the biochemical parameters show decrease in total chlorophyll and total amino acid levels in plants and an increase in amounts of soluble sugars, total protein, ascorbic acid, and phenol except B. nigra for protein in plants grown in soil irrigated with wastewater as compared to control site.     

Study of temporal variation in ambient air quality during Diwali festival in India

The variation in air quality was assessed from the ambient concentrations of various air pollutants [total suspended particle (TSP), particulate matter ≤10 μm (PM₁₀), SO₂, and NO₂] for pre-Diwali, Diwali festival, post-Diwali, and foggy day (October, November, and December), Delhi (India), from 2002 to 2007. The extensive use of fireworks was found to be related to short-term variation in air quality. During the festival, TSP is almost of the same order as compared to the concentration at an industrial site in Delhi in all the years. However, the concentrations of PM₁₀, SO₂, and NO₂ increased two to six times during the Diwali period when compared to the data reported for an industrial site. Similar trend was observed when the concentrations of pollutants were compared with values obtained for a typical foggy day each year in December. The levels of these pollutants observed during Diwali were found to be higher due to adverse meteorological conditions, i.e., decrease in 24 h average mixing height, temperature, and wind speed. The trend analysis shows that TSP, PM₁₀, NO₂, and SO₂ concentration increased just before Diwali and reached to a maximum concentration on the day of the festival. The values gradually decreased after the festival. On Diwali day, 24-h values for TSP and PM₁₀ in all the years from 2002 to 2007 and for NO₂ in 2004 and 2007 were found to be higher than prescribed limits of National Ambient Air Quality Standards and exceptionally high (3.6 times) for PM₁₀ in 2007. These results indicate that fireworks during the Diwali festival affected the ambient air quality adversely due to emission and accumulation of TSP, PM₁₀, SO₂, and NO_2.     

Past climate, future perspective: an exploratory analysis using climate proxies and drought risk assessment to inform water resources management and policy in Maine, USA

In recent decades, significant progress has been made toward reconstructing the past climate record based on environmental proxies, such as tree rings and ice core records. However, limited examples of research that utilizes such data for water resources decision-making and policy exist. Here, we use the reconstructed record of Palmer Drought Severity Index (PDSI), dating back to 1138AD to understand the nature of drought occurrence (severity and duration) in the state of Maine. This work is motivated by the need to augment the scientific basis to support the water resources management and the emerging water allocation framework in Maine (Maine Department of Environmental Protection, Chapter 587). Through a joint analysis of the reconstructed PDSI and historical streamflow record for twelve streams in the state of Maine, we find that: (a) the uncertainties around the current definition of natural drought in the Chapter 587 (based on the 20th century instrumental record) can be better understood within the context of the nature and severity of past droughts in this region, and (b) a drought index provides limited information regarding at-site hydrologic variations. To fill this knowledge gap, a drought index-based risk assessment methodology for streams across the state is developed. Based on these results, the opportunities for learning and challenges facing water policies in a changing hydroclimate are discussed.     

Exergy analysis of the transcritical N2O refrigeration cycle with a vortex tube

In this article, a comparative study is presented for the transcritical cycle with expansion valve (TCEV) and transcritical cycle with vortex tube (TCVT) mainly based on the second law of thermodynamics. Natural refrigerant nitrous oxide (N₂O) is used in both the cycles for analysis. The evaporator and gas cooler temperatures are varied from ?55°C to 5°C and 35°C to 60°C, respectively. The effects of various operating and design parameters on the optimum heat rejection pressure, coefficient of performance (COP), exergy loss (irreversibility), and the exergetic efficiency are studied. Exergy analysis of each component in TCEV and TCVT is performed to identify the amount and locations of irreversibility. It is observed that the use of the vortex tube in place of the expansion valve reduces the total exergy losses and increases the exergetic efficiency as well as COP. The exergetic efficiency and COP of the TCVT are on average 10–12% higher compared to TCEV for the considered operating conditions. The computed values of the exergetic efficiency for TCVT using refrigerant N₂O are the highest at an evaporator temperature of ?55°C, and the corresponding values of exergetic efficiency and exergy losses varies between 25.35% and 15.67% and between 74.65% and 84.33%, respectively. However, COP at the same evaporator temperature of ?55°C varies between 0.83 and 0.51. Furthermore, the optimum heat rejection pressure in TCVT is lower compared to that in TCEV. The results offer significant help for the optimum design and operating conditions of TCVT with refrigerant N₂O.     

Seismic detection of CO2 leakage along monitoring wellbores

A pilot carbon dioxide (CO₂) sequestration experiment was carried out in the Michigan Basin in which ～10,000 tonnes of supercritical CO₂ was injected into the Bass Island Dolomite (BILD) at 1050 m depth. A passive seismic monitoring (PSM) network was operated before, during and after the ～17-day injection period. The seismic monitoring network consisted of two arrays of eight, three-component sensors, deployed in two monitoring wells at only a few hundred meters from the injection point. 225 microseismic events were detected by the arrays. Of these, only one event was clearly an injection-induced microearthquake. It occurred during injection, approximately 100 m above the BILD formation. No events, down to the magnitude ?3 detection limit, occurred within the BILD formation during the injection. The observed seismic waveforms associated with the other 224 events were quite unusual in that they appear to contain dominantly compressional (P) but no (or extremely weak) shear (S) waves, indicating that they are not associated with shear slip on faults. The microseismic events were unusual in two other ways. First, almost all of the events occurred prior to the start of injection into the BILD formation. Second, hypocenters of the 94 locatable events cluster around the wells where the sensor arrays were deployed, not the injection well. While the temporal evolution of these events shows no correlation with the BILD injection, they do correlate with CO₂ injection for enhanced oil recovery (EOR) into the 1670 m deep Coral Reef formation that had been going on for ～2.5 years prior to the pilot injection experiment into the BILD formation. We conclude that the unusual microseismic events reflect degassing processes associated with leakage up and around the monitoring wells from the EOR-related CO₂ injection into the Coral Reef formation, ～700 m below the depth of the monitoring arrays. This conclusion is also supported by the observation that as soon as injection into the Coral Reef formation resumed at the conclusion of the BILD demonstration experiment, seismic events (essentially identical to the events associated with the Coral Reef injection prior to the BILD experiment) again started to occur close to a monitoring arrays. Taken together, these observations point to vertical migration around the casings of the monitoring wellbores. Detection of these unusual microseismic events was somewhat fortuitous in that the arrays were deployed at the depth where the CO₂ undergoes a strong volume increase during transition from a supercritical state to a gas. Given the large number of pre-existing wellbores that exist in depleted oil and gas reservoirs that might be considered for CO₂ sequestration projects, passive seismic monitoring systems could be deployed at appropriate depths to systematically detect and monitor leakage along them.     

Environmentally conscious manufacturing and product recovery (ECMPRO): A review of the state of the art

Gungor and Gupta [1999, Issues in environmentally conscious manufacturing and product recovery: a survey. Computers and Industrial Engineering, 36(4), 811–853] presented an important review of the development of research in Environmentally Conscious Manufacturing and Product Recovery (ECMPRO) and provided a state of the art survey of published work. However, that survey covered most papers published through 1998. Since then, a lot of activity has taken place in EMCPRO and several areas have become richer. Many new areas also have emerged. In this paper we primarily discuss the evolution of ECMPRO that has taken place in the last decade and discuss the new areas that have come into focus during this time. After presenting some background information, the paper systematically investigates the literature by classifying over 540 published references into four major categories, viz., environmentally conscious product design, reverse and closed-loop supply chains, remanufacturing, and disassembly. Finally, we conclude by summarizing the evolution of ECMPRO over the past decade together with the avenues for future research.     

A multi-period optimization model for energy planning with CO2 emission consideration

A novel deterministic multi-period mixed-integer linear programming (MILP) model for the power generation planning of electric systems is described and evaluated in this paper. The model is developed with the objective of determining the optimal mix of energy supply sources and pollutant mitigation options that meet a specified electricity demand and CO₂ emission targets at minimum cost. Several time-dependent parameters are included in the model formulation; they include forecasted energy demand, fuel price variability, construction lead time, conservation initiatives, and increase in fixed operational and maintenance costs over time. The developed model is applied to two case studies. The objective of the case studies is to examine the economical, structural, and environmental effects that would result if the electricity sector was required to reduce its CO₂ emissions to a specified limit.