西安市高新区采暖期大气颗粒物污染状况分析

为了解西安市高新区采暖期大气颗粒物(包括PM1 0和PM2.5)污染状况,于2013年1月1日到2013年3月15日在高新区进行了为期74 d的连续自动采样。结果表明:采样期间高新区PM1 0的小时浓度范围28~1744μg/m3,平均浓度为332μg/m3;PM2.5的小时浓度范围13~946μg/m3,平均浓度为207μg/m3。PM2.5占PM1 0的平均比例为63.8%。颗粒物浓度日变化呈现弱双峰特征,分别在凌晨2:00和上午7:00~8:00左右达到浓度最高值,但是上午的峰值并不明显。颗粒物在15:00~1 6:00之间浓度达到最低值,由于受采暖影响,18:00之后颗粒物浓度明显上升。     

工作流技术在水质自动站第三方运营中的应用研究

随着越来越多的水质自动站委托给第三方运营维护,环境监测部门在外包管理中面临着无法跟踪任务进展、无法对运维人员在现场工作进行监督、无法及时检查工作成果等问题。借用信息化手段,将工作流技术引入水质自动站的外包管理,使得每当新发起一个运维任务时,及时建立起一个工作流,监测部门通过对工作流的监控可以实现对运维过程的监督管理,从而解决了这些问题。通过应用工作流技术,提升了环境监测部门对水质自动站第三方运营的管理效率,为水质自动监测数据的获取和利用奠定了更坚实的基础。     

北京市2000年-2012年水环境质量及污染规律研究

环境质量和污染结构演化与城市社会经济发展之间存在内在联系,抓住三者间的关系可以更好地规划指导环境保护,甚至影响城市规划。本文分析了2000年以来首都水环境质量及水环境污染演变规律,研究了环境质量和污染结构演化与城市社会经济发展之间的内在联系,在此基础上识别并分析了北京市主要水环境问题和成因,提出了水环境保护的综合对策和建议。研究将为解决北京市水环境问题提供有力支撑。     

项目管理在大型环境整治工程建设中的重要性研究

随着现代工程专业化水平和复杂程度的日益增长,高质量的项目管理已经成为目前大型工程顺利建成的重要保障之一。本文以苏州河环境整治工程项目管理工作为基础,通过对现代工程项目管理特点和重要性进行梳理、分析,论述了项目管理对大型工程的重要性,并根据实际工作经验,从项目信息管理、工作量统计、文明施工管理、工程档案管理等方面入手,成功完成该项目建设任务。结合所得工作成果,提出下一阶段项目管理工作的改进建议,所得成果极具现实意义。     

Empirical corroboration of an earlier theoretical resolution to the UV paradox of insect polarized skylight orientation

It is surprising that many insect species use only the ultraviolet (UV) component of the polarized skylight for orientation and navigation purposes, while both the intensity and the degree of polarization of light from the clear sky are lower in the UV than at longer (blue, green, red) wavelengths. Why have these insects chosen the UV part of the polarized skylight? This strange phenomenon is called the "UV-sky-pol paradox". Although earlier several speculations tried to resolve this paradox, they did this without any quantitative data. A theoretical and computational model has convincingly explained why it is advantageous for certain animals to detect celestial polarization in the UV. We performed a sky-polarimetric approach and built a polarized skylight sensor that models the processing of polarization signals by insect photoreceptors. Using this model sensor, we carried out measurements under clear and cloudy sky conditions. Our results showed that light from the cloudy sky has maximal degree of polarization in the UV. Furthermore, under both clear and cloudy skies the angle of polarization of skylight can be detected with a higher accuracy. By this, we corroborated empirically the soundness of the earlier computational resolution of the UV-sky-pol paradox.     

Combination of heterogeneous Fenton-like reaction and photocatalysis using Co-TiO2 nanocatalyst for activation of KHSO5 with visible light irradiation at ambient conditions

A novel coupled system using Co–Ti O2 was successfully designed which combined two different heterogeneous advanced oxidation processes, sulfate radical based Fenton-like reaction（SR-Fenton） and visible light photocatalysis（Vis-Photo）, for degradation of organic contaminants. The synergistic effect of SR-Fenton and Vis-Photo was observed through comparative tests of 50 mg/L Rhodamine B（Rh B） degradation and TOC removal. The Rhodamine B degradation rate and TOC removal were 100% and 68.1% using the SR-Fenton/Vis-Photo combined process under ambient conditions, respectively. Moreover, based on XRD, XPS and UV-DRS characterization, it can be deduced that tricobalt tetroxide located on the surface of the catalyst is the SR-Fenton active site, and cobalt ion implanted in the Ti O2 lattice is the reason for the visible light photocatalytic activity of Co–Ti O2. Finally, the effects of the calcination temperature and cobalt concentration on the synergistic performance were also investigated and a possible mechanism for the synergistic system was proposed. This coupled system exhibited excellent catalytic stability and reusability,and almost no dissolution of Co2＋was found.     

纳污海域水环境容量计算与总量分配方法研究——以钦州湾为例

经过比较,明确了选用多源线性迭加的方法来计算纳污海域环境容量更加便利和有效,确定了纳污海域水环境容量计算中的几个重要条件,在对“背景浓度”的处理上引入了最大日均值的概念,使得计算结果更加安全可靠。在此基础上,以广西钦州湾为例,用多元线性迭加法计算出纳污海域两个规划排污口联合排放的无机氮、COD、石油类的最大允许排放量。优化了污染物排放方法,为钦州湾污染物排放提供了科学依据。     

浅议建立清洁生产审核内审员制度

阐述了建立内审员制度的必要性与意义.探讨了内审员的工作职能和管理与培训方法,为建立内审员制度提供了参考模式.     

Study on fractions of adsorbed Pb and Cd onto natural surface coatings

The speciation and extent of migration of adsorbed Pb and Cd in natural surface coatings (NSCs) were investigated using sequential extraction procedure to provide an understanding of distribution of the adsorbed Pb and Cd. Extractions were conducted on NSCs before and after Pb and Cd adsorption treatment under controlled laboratory conditions with initial Pb and Cd concentrations ranging from 0.2-2.5 mol/l. The Langmuir adsorption isotherms were applied to estimate equilibrium coefficients of Pb and Cd adsorption to NSCs components. The results showed that 58.50% of adsorbed Pb in average existed in tightly adsorbed form, and the remaining Pb was mostly present as solid oxides/hydroxides (34.00%) and exchangeable and soluble form (7.50%) in NSCs, respectively. Large amount of adsorbed Cd (70.51% in average) was present in exchangeable and soluble form, following a decreasing order in tightly adsorbed form (18.61%), solid oxides/hydroxides (9.87%), and easily oxidizable solids/compounds (1.01%), respectively. No Cd was found in strongly held oxides and precipitates. Compared to the distribution of adsorbed Pb in NSCs, Cd distribution showed that less migration of Cd from exchangeable and soluble form to solid oxides/hydroxides after adsorbed to NSCs, indicating fewer sites for Cd to adsorb to NSCs and less affinity of Cd to the NSCs. These percent distributions of metals provided an additional interpretation to that Pb adsorption to the NSCs greater than that of Cd, less retention of Cd than that of Pb and less roles attributed for Pb/Cd adsorption by organic materials in NSCs, which were observed based on the selective extraction techniques in the independent investigations.