Humic acid in ice: Photo-enhanced conversion of nitrogen dioxide into nitrous acid

Laboratory studies on the heterogeneous conversion of nitrogen dioxide into nitrous acid on irradiated ice films containing humic acid are described. It was found that the presence of light in the visible range of the solar spectrum significantly enhances the rate of nitrous acid release from a humic acid doped ice film. This process might contribute to observed HONO production in snow, where the NO₂ is thought to originate from nitrate photolysis. Analysis of the experimental data based on the Langmuir Hinshelwood model framework allowed quantification of the observed dependencies of the nitrous acid production rate on nitrogen dioxide concentration. The observed dependencies on the humic acid concentration as well as on the irradiation intensity were used to estimate light-driven HONO fluxes for environmental snow covers.     

Characterization of particulate matter concentrations during controlled indoor activities

Indoor sources have been identified as a major contributor to the increase of particle concentration in indoor environments. The work presented here is a study of the characteristics of particulate matter number size distribution and mass concentration under controlled indoor activities in a laboratory room. The objective is to characterize particulate matter concentrations indoors resulted under the influence of specific sources. Measurements were performed in an empty laboratory (period September–October 2006) using a GRIMM SMPS+C system (particle size range between 11.1 and 1083.3 nm), a DustTrak Aerosol Monitor (TSI) and a P-Trak Ultrafine Particle Counter (TSI). The studied indoor activities included candle burning, hot plate heating, water boiling, onion frying, vacuuming, hair drying, hair spraying, smoking and burning of incense stick. The AMANpsd computer algorithm was used to evaluate the modal structure of measured particle number size distribution data. Furthermore, the change of the particle number size distribution shape under the influence of different emission sources was studied versus time. Finally the particle emission rates were computed. High particle number concentrations were observed during smoking, onion frying, candle burning and incense stick burning. The highest particle mass concentrations were measured during smoking and hair spraying. The shift of the particle size distribution to larger diameters suggests the presence of strong coagulation effect during candle burning, incense stick burning, smoking and onion frying. The size distribution was mainly bimodal during onion frying and candle burning, whereas the size distribution remained unimodal during incense stick burning and smoking experiments.     

An experimental study of the influence of biofuel origin on particle-associated PAH emissions

The chemical speciation of the 16 polycyclic aromatic hydrocarbons associated to the particulate matter of conventional diesel fuel, rapeseed methyl esters, waste cooking oil methyl esters, waste cooking oil ethyl esters and their conventional fuel blends has been carried out. The speciation of these individual compounds was made by a combination of thermal extraction, solid phase micro-extraction and GC/MS analysis. This PAH speciation method was applied to a real samples obtained from a diesel engine under two different operating modes, urban and extraurban modes. The purpose of this work was to study the relationship between the amount, type and carcinogenic potency of polycyclic aromatic hydrocarbons in engine emissions and the multi-component biodiesel fuel composition.     

Global sensitivity analysis of a process-based model for ammonia emissions from manure storage and treatment structures

The development of process-based models to estimate ammonia emissions from animal feeding operations (AFOSs) is sought to replace costly and time-consuming direct measurements. Critical to process-based model development is conducting sensitivity analysis to determine the input parameters and their interactions that contribute most to the variance of the model output. Global and relative sensitivity analyses were applied to a process-based model for predicting ammonia emissions from the surface of anaerobic lagoons for treating and storing manure. The objectives were to compare global sensitivity analysis (GSA) to relative (local) sensitivity analysis (RSA) on a process-based model for ammonia emissions. Based on the first-order coefficient, both GSA and RSA showed the model input parameters in order of importance in process model for ammonia emissions from lagoon surfaces were: (i) pH, (ii) lagoon liquid temperature, (iii) wind speed above the lagoon surface, and (iv) the concentration of ammoniacal nitrogen in the lagoon. The GSA revealed that interactions between model parameters accounted for over two-thirds of the model variance, a result that cannot be achieved using traditional RSA. Also, the GSA showed that parameter interactions involving liquid pH had more impact on the model output variance than the single parameters: (i) temperature, (ii) wind speed, or (iii) total ammoniacal nitrogen. This study demonstrates that GSA provides a more complete analysis of model input parameters and their interactions on the model output compared to RSA. A comprehensive tutorial regarding the application of GSA to a process model is presented.     

Non-target effect of organic insecticides: effect of two plant extracts on soil microbial biomass and enzymatic activities in soil

Efficacious botanical derivatives can provide an alternative to synthetic pesticides for organic farming systems. However, there is lack of information regarding the side effects of organic pesticides on key soil ecological processes. In this study, we investigated the effects of aqueous extracts from Urginea maritima and Euphorbia myrsinites exhibiting translaminar and systemic activity against pests on microbial biomass and enzymatic activities in soil. Two grams of plant material was extracted with 100 ml of water and then diluted 1:100, 2:100, and 4:100 with distilled water. Diluted plant extracts were applied around hypocotyl of tomato by soil drench. The effect of both plant extracts on microbial biomass C, amount of total N and organic C, and enzymatic activity in soil was significant. After the last application, the highest microbial biomass C was determined in the lowest U. maritima concentration (U 1:100). Soils treated with the highest concentration of U. maritima (U 4:100) had always lower SMBC content than control soil. All concentrations of E. myrsinites decreased microbial biomass C by 18% to 27% compared to the control. Total nitrogen and organic carbon decreased in soils without (control) and with treated U. maritima extract from first application to last application. Phosphatase, urease, and β-glucosidase activities were monitored in plant extract-treated soils. Except U. maritima 1:100 treatments of second and fourth applications, the other treatments of plant extracts negatively affected enzymatic activity in soil. U. maritima and E. myrsinites plant extracts exhibited different effects on soil microbial biomass and activity, probably because of their different chemical contents.     

Assessment of groundwater pollution in West Delhi, India using geostatistical approach

The exploration, exploitation, and unscientific management of groundwater resources in the National Capital Territory (NCT) of Delhi, India have posed a serious threat of reduction in quantity and deterioration of quality. The objective of the study is to determine the groundwater quality and to assess the risk of groundwater pollution at Najafgarh, NCT of Delhi. The groundwater quality parameters were analyzed from the existing wells of the Najafgarh and the thematic maps were generated using geostatistical concepts. Ordinary kriging and indicator kriging methods were used as geostatistical approach for preparation of thematic maps of the groundwater quality parameters such as bicarbonate, calcium, chloride, electrical conductivity (EC), magnesium, nitrate, sodium, and sulphate with concentrations equal or greater than their respective groundwater pollution cutoff value. Experimental semivariogram values were fitted well in spherical model for the water quality parameters, such as bicarbonate, chloride, EC, magnesium, sodium, and sulphate and in exponential model for calcium and nitrate. The thematic maps of all the groundwater quality parameters exhibited an increasing trend of pollution from the northern and western part of the study area towards the southern and eastern part. The concentration was highest at the southernmost part of the study area but it could not reflect correctly the groundwater pollution status. The indicator kriging method is useful to assess the risk of groundwater pollution by giving the conditional probability of concentrations of different chemical parameters exceeding their cutoff values. Thus, risk assessment of groundwater pollution is useful for proper management of groundwater resources and minimizing the pollution threat.     

Biodiversity of brackish water amphipods (crustacean) in two estuaries, southeast coast of India

The present study about the gammarid amphipods of Vellar and Uppanar estuaries was performed during two seasons (pre-monsoon and post-monsoon, 2005–2006), respectively, in nine habitats: five in the Vellar estuary and four in the Uppanar estuary. Amphipod samples were collected from sediments, oyster beds, seaweeds, sea grass, and mangroves. A total of 29 species of gammarid amphipods were collected in each area. The surface water temperature ranged from 16°C to 26°C, the salinity from 20 to 32 psu, and the pH between 7.5 and 8.3. Dissolved oxygen ranged from 5.3 to 7.8 ml/l. The maximum abundance of amphipods was observed during the pre-monsoon (July to September) in Vellar mangrove, and it was minimum during the pre-monsoon in Uppanar sea grass. It was found that several physicochemical factors, such as salinity, temperature, dissolved oxygen, pH, and the substrate have a marked effect on the distribution and the relative abundance of amphipods. The ranges of species diversity, richness, dominance, and evenness in the Vellar and Uppanar estuaries were 1.58–4.15, 1.82–5.29, 0–0.11, and 0.96–1, respectively. Using multivariate analyses, in each estuary, it was possible to identify different communities of amphipod species according to their habitats.     

Dynamic Games in the Economics and Management of Pollution

The paper provides a survey of the literature which utilizes dynamic state-space games to formulate and analyze intertemporal, many decision-maker problems in the economics and management of pollution.