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61.
Hirose J Kondo F Nakano T Kobayashi T Hiro N Ando Y Takenaka H Sano K 《Chemosphere》2005,60(8):1018-1024
Wastewater from clinical institutions contains a considerable amount of toxic substances. Among the toxic substances, antineoplastics may induce carcinogenesis, teratogenesis, and the emergence of mutant microorganisms in the environment. Although the incineration or chemical treatments of disposed antineoplastics are recommended, a high energy during incineration and a careful quality control during chemical treatment are required. In this study, we determined the conditions for the electrolytic treatment of an antineoplastic, epirubicin hydrochloride (EH), using two platinum electrodes with a constant current of 100 mA. We analyzed the cytotoxicity, mutagenicity and antibacterial activity of electrolyzed EH and compared them with those of unelectrolyzed EH. Nearly 100% cytotoxicity, mutagenicity and antibacterial activity were eliminated and HPLC did not detect an EH molecule, in the case of electrolysis for 6 h. We also examined the biological cytotoxicities of electrolyzed irinotecan hydrochloride, vincristine sulfate, mitomycin C, paclitaxel, methotrexate and cisplatin, and found that 72.1-99.999% toxicity was eliminated by electrolysis under the same conditions. The biological toxicity of a mixture of these drugs was determined to be decreased by approximately 99% by electrolysis under the same conditions. 相似文献
62.
Yasunori Ohtsu Ryuzo Yamada Hiroshi Urasaki Tatsuya Misawa Sebastian Popescu Hiroharu Fujita 《Journal of Material Cycles and Waste Management》2010,12(1):25-29
It is necessary to develop a medical waste management system featuring nonburning treatment and safety functions for small
medical institutions. In this article, the development of a waste management system without oxygen injection was achieved
by means of hybrid heating using microwave energy and an electric heater. The shape of the microwave reactor was a rectangular
parallelepiped with a volume of about 0.1 m3. In the experimental setup, microwave energy (2.45 GHz, about 800 W) was injected from the top of the reactor, while the
heater (about 1 kW) was located at the bottom. Heat insulators were set into all the walls of the reactor. The gases generated
in the system were vented through water and activated carbon. Five paper-based diapers with absorbed water were used as the
waste sample. For the evaluation of performance, the reduction rate was defined as the ratio (in percent) of the weight before
and after treatment. The reduction rate as a function of treatment time and the effect of the position of the waste in the
reactor on the reduction rate and the uniformity of treatment were examined for about 3 kg of waste. It was found that the
reduction rate reached as low as 4.2% at 3 h and then 3% after 8 h. The treated profile strongly depended on the position
of the waste in the reactor. In particular, it was clarified that a metal cylindrical enclosure and a needle electrode played
an important role in attaining uniform treatment of the waste. 相似文献
63.
Improvement of permeability of waste sludge by mixing with slag or construction and demolition waste
Hiroshi Asakura Kazuto Endo Masato Yamada Yuzo Inoue Yusaku Ono 《Waste management (New York, N.Y.)》2009,29(6):1877-1884
To determine the allowable ratio of waste sludge required to ensure an aerobic zone in the landfill, we investigated sludge permeability, which involved mixing sludge, the major landfill waste in Japan, at different mixing ratios with other wastes (slag and construction and demolition waste (C&D)). We measured parameters of sample permeability and analyzed parameters that exert a large influence on oxygen penetration depth with a simulation model accounting for both diffusion and convection driven by temperature gradients. We also determined the critical volumetric contents in which gas and/or water permeability change significantly when sludge is mixed with sand or gravel. From the results of the simulations, gas permeability of the layer, the difference between inside and outside temperatures and the oxygen consumption rate exert a large influence on the resulting oxygen penetration depth. The allowable ratio of sludge required to ensure an aerobic zone in the landfill was determined by considering the balance of the above three parameters. By keeping volumetric sludge content to below 25%, air convection and oxygen penetration depth of several meters were achieved in the modeling. 相似文献
64.
An experimental study of the behavior of endocrine-disrupting chemicals (EDCs) in leachate treatment processes (aeration, coagulation and sedimentation, activated carbon adsorption, and advanced oxidation) was conducted and removal efficiencies were evaluated. Among target EDCs, concentrations of BPA (1800 times), DBP (10 times), BBP (40 times), and DEHP (30 times) in leachate are more than ten times higher than those in surface water. BPA, DBP, and BBP can be treated by aeration and DEHP, by advanced oxidation processes. BPA could not be effectively removed by coagulation and sedimentation because most of BPA partitioned in the supernatant. DEHP could hardly be treated by aeration. The removal ratios of DEHP were approximately 50–70% if the generated sediment was removed completely. The removal ratios of DEHP in leachate of 100 m3/d with 100 kg of activated carbon were 50–70%, assuming a complete mixing model. The concentration of DEHP was decreased to below one-tenth in 120 min by advanced oxidation processes. 相似文献
65.
Takayoshi Ueno Toru Shiino Hiroshi Onishi 《Journal of Material Cycles and Waste Management》1999,1(1):25-32
Life cycle assessment (LCA), a quantitative method for evaluating the total environmental impact of a product, from the materials
in its manufacture to its final disposal, is playing an increasingly important role in manufacturing. When the LCA method
is applied to a product containing many kinds of electronic components, there is a need for life cycle inventory (LCI) data
on the components. This paper provides an original calculation of the LCI data for each electronic components industry. These
data show the amount of input energy and emissions into the atmosphere per yen of production yield. It is demonstrated that
the magnitude of the LCI data for each industry is essentially equal to that of the other industries. Furthermore, we conclude
that the LCI data for all electronic components are roughly equivalent, making it possible to calculate the LCI data of any
electronic component by simply multiplying the LCI data for the industry by the price of the component. Furthermore, after
comparing the materials production stages with the component manufacturing stage in the calculation, it became clear that
for several component industries the materials production stage could not be omitted from the calculation.
Received: April 10, 1998 / Accepted: February 8, 1999 相似文献
66.
Athit Phetrak Jenyuk Lohwacharin Hiroshi Sakai Michio Murakami Kumiko Ogum Satoshi Takizawa 《环境科学学报(英文版)》2014,26(6):1294-1300
Anion exchange resins (AERs) with different properties were evaluated for their ability to remove dissolved organic matter (DOM) and bromide, and to reduce disinfection by-product (DBP) formation potentials of water collected from a eutrophic surface water source in Japan. DOM and bromide were simultaneously removed by all selected AERs in batch adsorption experiments. A polyacrylic magnetic ion exchange resin (MIEX) showed faster dissolved organic carbon (DOC) removal than other AERs because it had the smallest resin bead size. Aromatic DOM fractions with molecular weight larger than 1600 Da and fluorescent organic fractions of fulvic acid- and humic acid-like compounds were efficiently removed by all AERs. Polystyrene AERs were more effective in bromide removal than polyacrylic AERs. This result implied that the properties of AERs, i.e. material and resin size, influenced not only DOM removal but also bromide removal efficiency, MIEX showed significant chlorinated DBP removal because it had the highest DOC removal within 30 rain, whereas polystyrene AERs efficiently removed brominated DBPs, especially brominated trihalomethane species. The results suggested that, depending on source water DOM and bromide concentration, selecting a suitable AER is a key factor in effective control of chlorinated and brominated DBPs in drinking water. 相似文献
67.
Ogino A Hirooka H Ikeguchi A Tanaka Y Waki M Yokoyama H Kawashima T 《Journal of environmental quality》2007,36(4):1061-1068
There is increasing concern about feeds prepared from food residues (FFR) from an environmental viewpoint; however, various forms of energy are consumed in the production of FFR. Environmental impacts of three scenarios were therefore investigated and compared using life cycle assessment (LCA): production of liquid FFR by sterilization with heat (LQ), production of dehydrated FFR by dehydration (DH), and disposal of food residues by incineration (IC). The functional unit was defined as 1 kg dry matter of produced feed standardized to a fixed energy content. The system boundaries included collection of food residues and production of feed from food residues. In IC, food residues are incinerated as waste, and thus the impacts of production and transportation of commercial concentrate feeds equivalent to the FFR in the other scenarios are included in the analysis. Our results suggested that the average amounts of greenhouse gas (GHG) emissions from LQ, DH, and IC were 268, 1073, and 1066 g of CO(2) equivalent, respectively. The amount of GHG emissions from LQ was remarkably small, indicating that LQ was effective for reducing the environmental impact of animal production. Although the average amount of GHG emissions from DH was nearly equal to that from IC, a large variation of GHG emissions was observed among the DH units. The energy consumption of the three scenarios followed a pattern similar to that of GHG emissions. The water consumption of the FFR-producing units was remarkably smaller than that of IC due to the large volumes of water consumed in forage crop production. 相似文献
68.
Seven compounds with different lipophilicities and structures—1,3,5-trichlorobenzene, pentachlorobenzene, acenaphthylene, 1,4-dimethyl-2-(1-methylphenyl)benzene, 4-ethylbiphenyl, 4,4′-dibromobiphenyl, and 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane—were subjected to bioconcentration tests in carp at concentrations below the water solubilities of the compounds in the presence or absence of a dispersant (either an organic solvent or a surfactant). The bioconcentration factors (BCFs) of the compounds were on the order of 102–104. The BCF values remained in the range of 15–49% for all the compounds, whether or not a dispersant was present, i.e., the BCF values in the presence of an organic solvent or a surfactant at a concentration below the critical micelle concentration were not significantly smaller than the BCF values in the absence of the solvent or surfactant. This result indicates that the dispersants had no influence on the evaluation of the bioconcentration potential of these test substances. 相似文献
69.
70.