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排序方式: 共有10000条查询结果,搜索用时 140 毫秒
911.
Romário J. da Silv Lizeth Carolina Mojica-Sánchez Filipe D.S. Gorz Graciela C. Pedro Bruna G. Maciel Gabriela P. Ratkovski Hérica D. da Roch Kamila T.O. do Nascimento Juan C. Medina-Llamas Alicia E. Chávez-Guajardo José J. Alcaraz-Espinoz Celso P. de Melo 《环境科学学报(英文版)》2021,33(2):62-73
We report the preparation of poly(3,4-ethylene dioxythiophene) (PEDOT)-modified polyvinylidene fluoride electrospun fibers and their use as a novel adsorbent material for the removal of the anionic dye Methyl Orange (MO) from aqueous media. This novel adsorbent material can be used to selectively remove MO on a wide pH range (3.0–10.0), with a maximum capacity of 143.8 mg/g at pH 3.0. When used in a recirculating filtration system, the maximum absorption capacity was reached in a shorter time (20 min) than that observed for batch mode experiments (360 min). Based on the analyses of the kinetics and adsorption isotherm data, one can conclude that the predominant mechanism of interaction between the membrane and the dissolved dye molecules is electrostatic. Besides, considering the estimated values for the Gibbs energy, and entropy and enthalpy changes, it was established that the adsorption process is spontaneous and occurs in an endothermic manner. The good mechanical and environmental stability of these membranes allowed their use in at least 20 consecutive adsorption/desorption cycles, without significant loss of their characteristics. We suggest that the physical-chemical characteristics of PEDOT make these hybrid mats a promising adsorbent material for use in water remediation protocols and effluent treatment systems. 相似文献
912.
A special feature of waste management in Finland has been the emphasis on the source separation of kitchen biowaste (catering waste); more than two-thirds of the Finnish population participates in this separation. Source-separated biowaste is usually treated by composting. The biowaste of about 5% of the population is handled by mechanical-biological treatment. A waste treatment plant at Mustasaari is the only plant in Finland using digestion for kitchen biowaste. For the protection of their employees, the plant owners commissioned a study on environmental factors and occupational hygiene in the plant area. During 1998-2000 the concentrations of dust, microbes and endotoxins and noise levels were investigated to identify possible problems at the plant. Three different work areas were investigated: the pre-processing and crushing hall, the bioreactor hall and the drying hall. Employees were asked about work-related health problems. Some problems with occupational hygiene were identified: concentrations of microbes and endotoxins may increase to levels harmful to health during waste crushing and in the bioreactor hall. Because employees complained of symptoms such as dry cough and rash or itching appearing once or twice a month, it is advisable to use respirator masks (class P3) during dusty working phases. The noise level in the drying hall exceeded the Finnish threshold value of 85 dBA. Qualitatively harmful factors for the health of employees are similar in all closed waste treatment plants in Finland. Quantitatively, however, the situation at the Mustasaari treatment plant is better than at some Finnish dry waste treatment plants. Therefore is reasonable to conclude that mechanical sorting, which produces a dry waste fraction for combustion and a biowaste fraction for anaerobic treatment, is in terms of occupational hygiene better for employees than combined aerobic treatment and dry waste treatment. 相似文献
913.
Qiao WM Song Y Yoon SH Korai Y Mochida I Yoshiga S Fukuda H Yamazaki A 《Waste management (New York, N.Y.)》2006,26(6):592-598
Efficient removal of chlorine from PVC achieved by two-stage heat-treatment (280 and 410 degrees C) provided chlorine-free isotropic pitch containing additive. The pitch was stabilized and carbonized into porous carbons with surface areas of approximately 300 m2/g. Resultant porous carbons showed three pore structures of supermicropore, micropore and mesopore. The generation of CO2 from the decomposition of the CaCO3 additive in waste PVC is responsible for the development of porous structures. The surface area of the carbonized product increased after the removal of CaO. 相似文献
914.
Factors affecting TCLP lead leachability from computer CPUs 总被引:1,自引:0,他引:1
The factors impacting lead leachability from computer central processing units (CPUs) during the toxicity characteristic leaching procedure (TCLP) were investigated. Several CPUs were disassembled and their component materials were decreased in size to meet the requirements of the TCLP. The impact of CPU composition was examined by leaching different combinations of the CPU components. The ferrous metal content of the mixture greatly impacted lead leaching. TCLP lead concentrations of CPUs predicted by leaching the lead-bearing printed wire boards alone were much greater than those measured when the ferrous metal of the CPU was included in the mixture. The leaching of iron and zinc from the galvanized steel components of the CPU created electrochemical conditions where lead was less soluble. Additional size reduction beyond that required by the TCLP did not result in additional lead leaching. As the volume of head space above the leaching solution increased, the concentration of lead measured increased as well. 相似文献
915.
Effects of the forced ventilation on composting of a solid olive-mill by-product ("alperujo") managed by mechanical turning 总被引:1,自引:0,他引:1
Cegarra J Alburquerque JA Gonzálvez J Tortosa G Chaw D 《Waste management (New York, N.Y.)》2006,26(12):1377-1383
The evaluation of the most suitable aeration technology for olive-mill by-product "alperujo" (AL) composting was carried out by using two identical piles prepared by mixing AL with a bulking agent (fresh cow bedding) and a mature compost (as inoculant). Forced ventilation was employed in conjunction with mechanical turning in one of the piles, whereas only mechanical turning was used in the other pile. These two treatment methods were evaluated by assessing process efficiency and end-product quality. The results show that the composting process was completed in less time when forced ventilation was coupled with mechanical turning. A slight delay in the evolution of pH, C/N ratio, and biodegradation of fats and organic matter was observed when only turning was employed. However, the recommended method for composting AL was mechanical turning without forced ventilation since the composition of the end-product in this case was comparable to the composted AL using forced ventilation coupled with mechanical turning. Furthermore, there were substantial economic savings by selecting mechanical turning alone, which included capital costs for equipment. 相似文献
916.
Blenkharn JI 《Waste management (New York, N.Y.)》2006,26(3):315-317
Medical (clinical) wastes are costly in disposal and carry risks of infection, or physical injury, and of exposure to potentially harmful pharmaceuticals, as well as being aesthetically unacceptable. Technological advances in disposal, together with the introduction of rigorous emission standards for incinerators and similarly stringent control standards for non-burn “alternate” disposal technologies, continue to drive improvements in waste management. Are these improvements attainable in developing countries?Where adequate resources and a robust infrastructure are lacking, investment in advanced disposal technologies may be counterproductive. Developments must be appropriate to and manageable by the communities served; sustainable low-technology approaches may be preferable. There remains a need for affordable technical innovation, as well as underlying political support and international financial and technical assistance, to sustain meaningful improvements in waste management in remote and isolated regions and more generally in developing countries. 相似文献
917.
Tinseau E Bartier D Hassouta L Devol-Brown I Stammose D 《Waste management (New York, N.Y.)》2006,26(7):789-800
This study aims to investigate, through mineralogical characterization (SEM, XRD) and mass-balance calculations, the effects of contact time, concrete types and presence of free water on the Tournemire argillite under in situ conditions. Three sampling zones from Excavation Disturbed Zone (EDZ) areas have been chosen: (1) dry contacts, collected at the tunnel masonry/argillite interface (contact time - 125 years), (2) wet contacts, taken close to drained areas below the tunnel roadbed in contact with the canal draining the Cernon fault water (contact time - 15 and 7 years) and at the tunnel masonry/argillite interface over 70 m from the Cernon fault (contact time - 125 years). This study shows that: in the absence of water, no significant modification of argillite is observed after 125 years, except for pyrite dissolution and gypsum precipitation; in the presence of water, precipitation of gypsum, recrystallization of mixed-layer clays, neoformation of zeolites and K-feldspars overgrowths are observed. At the concrete/argillite interface near the Cernon fault, important dolomite neoformation and leaching of chlorite and kaolinite occur. These processes are enhanced with contact time, low flow rate and the nature of the concrete (compound cement Portland CEM II 32.5). Evidence for oxidation processes linked to the EDZ (pyrite oxidation, Fe-oxy-hydroxide and gypsum precipitation) is observed. 相似文献
918.
The regional-scale importance of an aquatic stressor depends both on its regional extent (i.e., how widespread it is) and
on the severity of its effects in ecosystems where it is found. Sample surveys, such as those developed by the U.S. Environmental
Protection Agency’s Environmental Monitoring and Assessment Program (EMAP), are designed to estimate and compare the extents,
throughout a large region, of elevated conditions for various aquatic stressors. In this article, we propose relative risk
as a complementary measure of the severity of each stressor’s effect on a response variable that characterizes aquatic ecological
condition. Specifically, relative risk measures the strength of association between stressor and response variables that can
be classified as either “good” (i.e., reference) or “poor” (i.e., different from reference). We present formulae for estimating
relative risk and its confidence interval, adapted for the unequal sample inclusion probabilities employed in EMAP surveys.
For a recent EMAP survey of streams in five Mid-Atlantic states, we estimated the relative extents of eight stressors as well
as their relative risks to aquatic macroinvertebrate assemblages, with assemblage condition measured by an index of biotic
integrity (IBI). For example, a measure of excess sedimentation had a relative risk of 1.60 for macroinvertebrate IBI, with
the meaning that poor IBI conditions were 1.6 times more likely to be found in streams having poor conditions of sedimentation
than in streams having good sedimentation conditions. We show how stressor extent and relative risk estimates, viewed together,
offer a compact and comprehensive assessment of the relative importances of multiple stressors. 相似文献
919.
TUGAI: An Integrated Simulation Tool for Ecological Assessment of Alternative Water Management Strategies in a Degraded River Delta 总被引:1,自引:0,他引:1
Schlüter M Rüger N Savitsky AG Novikova NM Matthies M Lieth H 《Environmental management》2006,38(4):638-653
The development of ecologically sound water allocation strategies that account for the needs of riverine ecosystems is a pressing
issue, especially in semiarid river basins. In the Aral Sea Basin, a search for strategies to mitigate ecological and socioeconomic
deterioration has been in process since the early 1990s. The Geographic Information System–based simulation tool TUGAI has
been developed to support the policy determination process by providing a simple, problem-oriented method to assess ecological
effects of alternative water management strategies for the Amudarya River. It combines a multiobjective water allocation model
with simple, spatially explicit statistical and rule-based models of landscape dynamics. Changes in environmental conditions
are evaluated by a fuzzy habitat suitability index for Populus euphratica, which is the dominant species of the characteristic riverine Tugai forests. Water management scenarios can be developed
by altering spatiotemporal water distribution in the delta area or the amount of water inflow into the delta. Outcomes of
scenario analysis are qualitative comparisons of the ecological effects of different options for a time period of up to 28
years. The given approach utilizes different types of knowledge, from quantitative hydrological data to qualitative local
expert knowledge. The main purpose of the tool is to integrate the knowledge in a comprehensive way to make it available for
discussions on alternative policies in moderated workshops with stakeholders. In this article, the modules of the tool, their
integration, and three hypothetical scenarios are presented. Based on the experience gained when developing the TUGAI tool,
we propose that the general framework can be transferred to other areas where tradeoffs in water allocation between the environment
and other water users are of major concern. The potential for a simulation tool to structure and inform a complex resource
management situation by involving local experts and stakeholders in the development of possible future scenarios will become
increasingly valuable for transparent and participatory resource management. 相似文献
920.
Dimitrakopoulos PG Siamantziouras AS Galanidis A Mprezetou I Troumbis AY 《Environmental management》2006,37(6):826-839
We conducted a field experiment using constructed communities to test whether species richness contributed to the maintenance
of ecosystem processes under fire disturbance. We studied the effects of diversity components (i.e., species richness and
species composition) upon productivity, structural traits of vegetation, decomposition rates, and soil nutrients between burnt
and unburnt experimental Mediterranean grassland communities. Our results demonstrated that fire and species richness had
interactive effects on aboveground biomass production and canopy structure components. Fire increased biomass production of
the highest-richness communities. The effects of fire on aboveground biomass production at different levels of species richness
were derived from changes in both vertical and horizontal canopy structure of the communities. The most species-rich communities
appeared to be more resistant to fire in relation to species-poor ones, due to both compositional and richness effects. Interactive
effects of fire and species richness were not important for belowground processes. Decomposition rates increased with species
richness, related in part to increased levels of canopy structure traits. Fire increased soil nutrients and long-term decomposition
rate. Our results provide evidence that composition within richness levels had often larger effects on the stability of aboveground
ecosystem processes in the face of fire disturbance than species richness per se. 相似文献