Experimental investigation of spark ignition energy in kerosene,hexane, and hydrogen

Quantifying the risk of accidental ignition of flammable mixtures is extremely important in industry and aviation safety. The concept of a minimum ignition energy (MIE), obtained using a capacitive spark discharge ignition source, has traditionally formed the basis for determining the hazard posed by fuels. While extensive tabulations of historical MIE data exist, there has been little work done on ignition of realistic industrial and aviation fuels, such as gasoline or kerosene. In the current work, spark ignition tests are performed in a gaseous kerosene–air mixture with a liquid fuel temperature of 60 °C and a fixed spark gap of 3.3 mm. The required ignition energy was examined, and a range of spark energies over which there is a probability of ignition is identified and compared with previous test results in Jet A (aviation kerosene). The kerosene results are also compared with ignition test results obtained in previous work for traditional hydrogen-based surrogate mixtures used in safety testing as well as two hexane–air mixtures. Additionally, the statistical nature of spark ignition is discussed.     

An approach for domino effect reduction based on optimal layouts

An approach to reduce the probability of producing a domino effect in process industry is developed in this work. It is assumed that optimal layouts should include appropriate analysis to reduce risk during the process design stage. The model developed for this approach combines the estimation of probability of damage due to overpressure, proposed by Mingguang and Juncheng (2008), and escalation threshold values defined by Cozzani, Gubinelli, and Salzano (2006). These equations are combined with other typical layout constraints as well as bounding the probability constraint, which has resulted in a highly non-linear MINLP problem. Solving a case study used by other authors provides evidence for reliability of the developed approach. In this way, layouts are designed to reduce the escalation probability yielding safe distributions.     

Analysis of underlying causes of investigated loss of containment incidents in Dutch Seveso plants using the Storybuilder method

In the Netherlands there are around 400 “Seveso” sites that fall under the Dutch Major Hazards Decree (BRZO) 1999. Between 2006 and 2010 the Dutch Labour Inspectorate's Directorate for Major Hazard Control completed investigations of 118 loss of containment incidents involving hazardous substances from this group. On the basis of investigation reports the incidents were entered in a tailor-made tool called Storybuilder developed for the Dutch Ministry of Social Affairs and Employment for identifying the dominant patterns of technical safety barrier failures, barrier task failures and underlying management causes associated with the resulting loss of control events. The model is a bow-tie structure with six lines of defence, three on either side of the central loss of containment event. In the first line of defence, failures in the safety barriers leading to loss of control events were primarily equipment condition failures, pre start-up and safeguarding failures and process deviations such as pressure and flow failures. These deviations, which should have been recovered while still within the safe envelope of operation, were missed primarily because of inadequate indication signals that the deviations have occurred. Through failures of subsequent lines of defence they are developing into serious incidents. Overall, task failures are principally failures to provide adequate technical safety barriers and failures to operate provided barriers appropriately. Underlying management delivery failures were mainly found in equipment specifications and provisions, procedures and competence. The competence delivery system is especially important for identifying equipment condition, equipment isolation for maintenance, pre-start-up status and process deviations. Human errors associated with operating barriers were identified in fifty per cent of cases, were mostly mistakes and feature primarily in failure to prevent deviations and subsequently recover them. Loss of control associated with loss of containment was primarily due to the containment being bypassed (72% of incidents) and less to material strength failures (28%). Transfer pipework, connections in process plant and relief valves are the most frequent release points and the dominant release material is extremely flammable. It is concluded that the analysis of a large number of incidents in Storybuilder can support the quantification of underlying causes and provide evidence of where the weak points exist in major hazard control in the prevention of major accidents.     

Small-scale physical explosions in shock tubes in comparison with condensed high explosive detonations

A series of small-scale experiments involving physical explosions in a 1.6 l pressure vessel was carried out. Explosions were initiated by spontaneous rupture of an aluminium membrane on one side of the vessel at a pressure in the range 1–1.2 MPa. The pressure waves released were measured at different distances along two separate shock tubes, one 10 m long and 200 mm in diameter (closed at one end by the high pressure vessel) and the other 15 m long and 100 mm in diameter.TNT equivalency was used for predicting the blast wave characteristics after vessel rupture. TNT equivalency was used because equations for prediction of peak pressure and impulse of the blast wave in 1-D geometry after detonations of condensed explosives are known. Some experiments with an equivalent amount of real explosive were carried out for comparison with the theoretical and experimental data obtained. The applicability of the TNT equivalency method presented for calculations of maximum pressure and shock wave impulse generated after rupture of the pressure vessel in 1-D geometry is discussed.     

Media surface properties and the development of nitrifying biofilms in mixed cultures for wastewater treatment

Plastic was tested to select biofilm support media that would enhance nitrification in the presence of heterotrophs. Eight different types (acrylonitrile butadiene styrene, nylon, polycarbonate, polyethylene, polypropylene, polytetrafluoroethylene (PTFE), polyvinyl chloride and tufnol) were immersed in an aerobic fed-batch reactor receiving domestic settled wastewater. Nitrification rates did not correlate with biomass concentrations, nor surface roughness of the plastics as measured by atomic force microscopy (AFM). The maximum nitrification rate of 1.5 g/m² d^?1 was obtained from biofilms growing on PTFE which had the lowest surface adhesion force (8 nN). Nitrification rates for the biofilms were inversely correlated with the attraction forces as measured by AFM.     

Environmental risk mapping of accidental pollution and its zonal prevention in a city

Accidental releases of pollution can have severe environmental, societal, economic, and institutional consequences. This paper considers the use of risk mapping of accidental pollution events, and zonal prevention measures for alleviating the impact on large urban areas. An Environmental Pollution Accident Risk Mapping (EPARM) model is constructed according to a mapping index system supported by quantitative sub-models dedicated to evaluating the risk arising from different sources of potential accidental pollution. The EPARM approach consists of identifying suitable indexes, assessment of environmental risk at regional and national scales based on information on previous pollution accidents and the prevailing environmental and social conditions, and use of GIS to map the overall risk. A case study of pollution accidents in Minghang District, Shanghai, China is used to demonstrate the effectiveness of the model. The paper also proposes a systemic framework for accidental environmental pollution risk prevention, and detailed countermeasures for specific risk zones.     

Experimental and theoretical investigations for mitigating NaAlH4 reactivity risks during postulated accident scenarios involving exposure to air or water

Experimental and theoretical studies were conducted to investigate the pyrophoricity and water-reactivity risks associated with employing sodium alanate (NaAlH₄) complex metal hydride in on-board vehicular hydrogen (H₂) storage systems. The ignition and explosivity of NaAlH₄ upon exposure to oxidizers in air or water were attributed to the spontaneous formation of stable hydroperoxyl intermediates on the NaAlH₄ surface and/or H₂ production, as well as the large driving force for NaAlH₄ conversion to favorable hydroxide products predicted by atomic and thermodynamic modeling. The major products from NaAlH₄ exposure to air: NaAl(OH)₄, gibbsite and bayerite Al(OH)₃, and Na₂CO₃ observed by XRD, were identified to be formed by surface-controlled reactions. The reactivity risks were significantly minimized, without compromising de-/re-hydrogenation cyclability, by compacting NaAlH₄ powder into wafers to reduce the available surface area. These core findings are of significance to risk mitigation and H₂ safety code and standard development for the safe use of NaAlH₄ for on-board H₂ storage in light-duty vehicles.     

Bipolar charged aerosol agglomeration and collection by a two-zone agglomerator

ＩｎｔｒｏｄｕｃｔｉｏｎＢｅｃａｕｓｅｏｆｔｈｅｌｏｗｅｆｆｉｃｉｅｎｃｙｏｆｔｈｅｅｌｅｃｔｒｏｓｔａｔｉｃｐｒｅｃｉｐｉｔａｔｏｒ (ＥＳＰ)ｆｏｒｃｏｌｌｅｃｔｉｎｇｔｈｅｓｕｂｍｉｃｒｏｎｐａｒｔｉｃｌｅｓ ,ｔｈｅｅｌｅｃｔｒｉｃａｌａｇｇｌｏｍｅｒａｔｉｏｎｍｅｔｈｏｄｈａｓｌｅｄｔｏａｎｉｎｃｒｅａｓｉｎｇｉｎｔｅｒｅｓｔｉｎｒｅｄｕｃｉｎｇｔｈｅｅｍｉｓｓｉｏｎｏｆｔｈｅｆｉｎｅｐａｒｔｉｃｌｅｓ .Ｍａｎｙａｕｔｈｏｒｓｈａｖｅｓｔｕｄｉｅｄｅｌｅｃｔｒｉｃａｌａｇｇｌｏｍｅｒａｔｉ…     

Laboratory scale studies on removal of chromium from industrial wastes

Chromium being one of the major toxic pollutants is discharged from electroplating and chrome tanning processes and is also found in the effluents of dyes,paint pigments,manufacturing units etc.Chromium exists in aqueous systems in both trivalent(Cr^3 )and hexavalent (Cr^6 )forms.The hexavalent form is carcinogenic and toxic to aquatic life,whereas Cr^3 is however comparatively less toxic.This study was undertaken to investigate the total chromium removal from industial effluents by chemical means in order to achieve the Pakistan NEQS level of 1 mg/L by the methods of reduction and precipitation.The study was conducted in four phase Ⅰ,the optimum pH and cost effective reducing agent among the four popular commercial chemicals was selected.As a result,pH of 2 was found to be most suitable and sodium meta bisulfate was found to be the most cost effective reducing agent respectively.Phase Ⅱ showed that lower dose of sodium meta hisulfate was sufficient to obtain 100% efficiency in reducing Cr^6 to Cr^3 ,and it was noted that reaction time had no significance in the whole process.A design curve for reduction process was established which can act as a tool for treatment of industrial effluents.Phase Ⅲ studies indicated the best pH was 8.5 for precipitation of Cr^3 to chromium hydroxide by using lime.An efficiency of 100% was achievable and a settling time of 30 minutes produced clear effluent.Finally in Phase Ⅳ actual waste samples from chrome tanning and electroplating industries,when precipitated at pH of 12 gave 100% efficiency at a settling time of 30 minutes and confirmed that chemical means of reduction and precipitation is a feasible and viable solution for treating chromium wastes from industries.     

Survey of polycyclic aromatic hydrocarbons (PAHs) in arterial street air of Hangzhou

ＩｎｔｒｏｄｕｃｔｉｏｎＰｏｌｙｃｙｃｌｉｃａｒｏｍａｔｉｃｈｙｄｒｏｃａｒｂｏｎｓ (ＰＡＨｓ)ａｒｅｗｉｄｅｓｐｒｅａｄｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔａｎｔｓｉｎｔｈｅａｔｍｏｓｐｈｅｒｅ.Ｔｈｅｙａｒｅｇｅｎｅｒａｔｅｄｉｎｔｈｅｃｏｍｂｕｓｔｉｏｎ .Ｔｈｅｍａｊｏｒｓｏｕｒｃｅｓｉｄｅｎｔｉｆｉｅｄｉｎｃｌｕｄｅｆｏｓｓｉｌｆｕｅｌｓ,ｖｅｈｉｃｕｌａｒｔｒａｆｆｉｃ,ｉｎｄｕｓｔｒｉａｌｐｒｏｃｅｓｓｅｓ,ｓｍｏｋｉｎｇａｎｄｄｏｍｅｓｔｉｃｈｅａｔｉｎｇ (Ｐｅｌｔｏｎｅｎ ,1995) .Ｔ…