Occurrence of 1,1′-dimethyl-4,4′-bipyridinium (Paraquat) in irrigated soil of the Lake Chad Basin,Niger

Increased use of agrochemical products to improve yields for irrigated crops in sub-Saharan Africa has been accompanied by a significant increase in the risk of environmental contamination. Detailed examples of the fate of pesticides after initial spreading on crop fields are scarce in tropical regions, where safe practices and related health risks are poorly understood by smallholder farmers. In the semi-arid environment of the Lake Chad Basin, SE Niger, both intrinsic properties of pesticides and extrinsic factors such as soil and climate helped to characterize processes leading to an accumulation of pesticides in soils. Analysis by HPLC-UV of a 6 m deep soil profile showed the presence of Paraquat at concentrations from 953?±?102 μg kg^?1 to 3083?±?175 μg kg^?1 at depths between 0.80 and 2.75 m below the land surface. Soil analysis revealed that up to approximately 15 % of the total soil matrix consists of smectites, a clay mineral capable of retaining cationic pesticides such as Paraquat, and a very low content of organic matter (<0.15 wt.% TOC). Paraquat could be stored and not bioavailable in a clayey barrier at approximately 2-m depth and therefore does not represent an immediate risk for populations or environment in this form. However, if the Paraquat application rate remains constant, the clayey barrier could reach a saturation limit within 150–200 years and 180–220 years if we consider a DT50 in soil of ~1,000 days (FAO). Consequently, it could lead to a deeper infiltration and so a pollution of groundwater. Such a scenario can represent a health risk for drinking water and for the Lake Chad, which is a major resource for this densely populated region of semi-arid Africa. Further analyses should focus on deeper layers and groundwater Paraquat contents to validate or invalidate the hypothesis of storage in this clay-rich layer.     

Injury by Sulfur Dioxide,Hydrogen Fluoride,and Chlorine As Observed and Reflected On Vegetation in the Field

Plants were examined at three different locations in the eastern part of the United States to determine whether damage from air pollution had occurred. This paper discusses sulfur dioxide damage in the metropolitan New York City area; hydrogen fluoride damage near a glass fiber manufacturing plant in the midwest; and hydrochloric acid mist and chlorine damage from a manufacturing operation in an eastern state. The symptoms that developed in vegetation were often found to be similar. Chemical and microscopical analyses were helpful in diagnosing the toxicants.     

Improvement of Physico-Mechanical Properties of Photo-Cured Chitosan Films with Ethylene Glycol Dimethacrylate and (2-Hydroxyethyl) Methacrylate

Chitosan, a natural polymer, was prepared by deacetylation of chitin which was obtained from dried prawn shell and was characterized. Thin chitosan film of chitosan was prepared by casting method from 0.2 % chitosan in 2 % acetic acid solution. Five formulations were developed with ethylene glycol dimethacrylate and (2-hydroxyethyl) methacrylate along with photo-initiator, Darocur-1664 (4 %). The chitosan film was soaked in the formulations at different soaking times and irradiated under UV-radiation at different intensities for the improvement of its physical and mechanical properties. The cured chitosan films were then subjected to various mechano-chemical tests like tensile strength, elongation at break, polymer loading, water absorption and gel content. The formulation containing 30 % ethylene glycol dimethacrylate and 66 % (2-hydroxyethyl) methacrylate showed the best performance at the 30th UV pass of UV-radiation for 3 min soaking time.     

不同草地资源水平牧户对气候变化的感知与偏差途径

人群感知是气候变化适应行为形成的重要信息基础,基于对中国北方草地草甸草原、典型草原、荒漠草原、草原化荒漠、沙地、农牧交错带等地区1292个牧户的问卷访谈,分2轮调查研究了不同草地类型地区牧民对气候变化的感知,与气候实值比较分析,并研究了牧民气候变化感知的偏差途径,结果表明:1980~2009年间研究区温度变化倾向率为0.63℃/10a(P0.05);温度较强的趋势性与牧民对其感知的分歧存在偏差,降水无明显变化与不同地区牧民感知明确的趋势性判断存在偏差;受草场变化等环境信息的传导是气候变化感知偏差形成的重要原因,其中,降水感知与环境感知之间具有较强的关系,存在明显的传导过程,而温度感知的传导性不明显;通过Probit模型分析显示,气候变化传导感知与否主要与牧户距离行政中心距离、户主年龄、教育背景、载畜水平、草畜资源等因素有关.     

Flooding and the interannual variability of hydrologic quantities in the Missouri River basin

The six mainstem reservoirs in the Missouri River basin (MRB) are managed mainly to prevent flooding from snowmelt and heavy rainfall, a goal for which the interannual variabilities of precipitation ($P$), evapotranspiration ($\mathit{ET}$), and surface air temperature ($T_{\mathrm{air}}$) are vitally important. We tested the hypothesis that under the expected higher variability owing to global climate change, the months with the highest contributions to the interannual variability of $P$, $\mathit{ET}$, and $T_{\mathrm{air}}$ in the MRB will remain unchanged and quantified likely temporal trends in these quantities. Using high-resolution, downscaled Coupled Model Intercomparison Project Phase 5 multi-model ensemble data sets, we compared the multi-year ratio of monthly and annual interannual variability and temporal trends in $P$, $\mathit{ET}$, and $T_{\mathrm{air}}$ during 2011–2020 with three future decades. Results showed that the 6 months with the highest interannual variability in $P$ and $\mathit{ET}$ (April–September) are the same in all four decades. However, for $T_{\mathrm{air}}$, only 4 months (December–March) retain their status as highly variable throughout the four decades; September and October variability is exceeded by the variability in other months. This implies that, compared to $P$ and $\mathit{ET}$, the cyclical change in the probabilities of $T_{\mathrm{air}}$ in the MRB is less stable under future global climate change. This finding can be used to consider the need to alter existing strategies for reservoir release while minimizing the likelihood of aggravating flooding below the reservoirs.     

Monitoring of effluent DOM biodegradation using fluorescence, UV and DOC measurements

The potential of effluent DOM to undergo microbial degradation was assessed in batch experiments. Effluent samples from Haifa wastewater treatment plant and Qishon reservoir (Greater Haifa wastewater reclamation complex, Israel) were incubated either with effluent or soil microorganisms for a period of 2-4 months and were characterized by dissolved organic carbon contents (DOC), UV(254) absorbance and by fluorescence excitation-emission matrices. Three main fluorescence peaks were identified that can be attributed to humic/fulvic components and "protein-like" structures. During biodegradation, specific fluorescences (F/DOC) of the three peaks were increased at various extents, suggesting selective degradation of non-fluorescing constituents. In some cases increase in the effluent fluorescence (F) was observed thus proposing (i) the formation of new fluorescing material associated with DOM biodegradation and/or (ii) degradation of certain organic components capable of quenching DOM fluorescence. Based on the ratio between fluorescence intensity and UV(254), different biodegradation dynamics for fluorescent DOM constituents as compared with other UV-absorbing molecules was delineated. Overall, about 50% of the total DOM was found to be readily degradable such that residual resistant DOC levels were between 8 and 10 mg l(-1). Enhanced levels of residual DOM in effluent-irrigated soils may contribute to the DOM pool capable of carrying pollutants to groundwater.     

Assessing the life cycle study of alternative earth-retaining walls from an environmental and economic viewpoint

Environmental Science and Pollution Research - This research aims to assess the sustainability of the most common earth-retaining walls (Gravity Walls and Cantilever Walls) in terms of...     

Cement-based batteries design and performance. A review

Environmental Chemistry Letters - Lithium batteries are increasingly used to store energy, but&nbsp;are limited by high cost, safety concerns, leaking of electrolytes, and low capacity....