NUTRIENT CONCENTRATION CRITERIA AND CHARACTERIZATION OF PATTERNS IN TROPHIC STATE FOR RIVERS IN HETEROGENEOUS LANDSCAPES1

ABSTRACT: A method is demonstrated for the development of nutrient concentration criteria and large scale assessment of trophic state in environmentally heterogeneous landscapes. The method uses the River Environment Classification (REC) as a spatial framework to partition rivers according to differences in processes that control the accrual and loss of algae biomass. The method is then applied to gravel bed rivers with natural flow regimes that drain hilly watersheds in New Zealand's South Island. An existing model is used to characterize trophic state (in terms of chlorophyll a as a measure of maximum biomass) using nutrient concentration, which controls the rate of biomass accrual, and flood frequency, which controls biomass loss. Variation in flood frequency was partitioned into three classes, and flow data measured at 68 sites was used to show that the classes differ with respect to flood frequency. Variation in nutrient concentration was partitioned at smaller spatial scales by subdivision of higher level classes into seven classes. The median of flood frequency in each of the three higher level classes was used as a control variable in the model to provide spatially explicit nutrient concentration criteria by setting maximum chlorophyll a to reflect a desired trophic state. The median of mean monthly soluble reactive phosphorus and soluble inorganic nitrogen measured at 68 water quality monitoring sites were then used to characterize the trophic state of each of the seven lower level classes. The method models biomass and therefore allows variation in this response variable to provide options for trophic state and the associated nutrient concentrations to achieve these. Thus it is less deterministic than using reference site water quality. The choice from among these options is a sociopolitical decision, which reflects the management objectives rather than purely technical considerations.     

IMPLICATIONS OF ON‐GROUND NITROGEN LOADING AND SOIL TRANSFORMATIONS ON GROUND WATER QUALITY MANAGEMENT1

ABSTRACT: This paper presents a modeling approach based on a geographic information system (GIS) to estimate the variability of on‐ground nitrogen loading and the corresponding nitrate leaching to ground water. The methodology integrates all point and nonpoint sources of nitrogen, the national land cover database, soil nitrogen transformations, and the uncertainty of key soil and land use‐related parameters to predict the nitrate mass leaching to ground water. The analysis considered 21 different land use classes with information derived from nitrogen sources such as fertilizer and dairy manure applications, dairy lagoons, septic systems, and dry and wet depositions. Simulations were performed at a temporal resolution of one month to capture seasonal trends. The model was applied to a large aquifer of 376 square miles in Washington State that serves more than 100,000 residents with drinking water. The results showed that dairy manure is the main source of nitrogen in the area followed by fertilizers. It was also seen that nitrate leaching is controlled by the recharge rate, and there can be a substantial buildup of soil nitrogen over long periods of time. Uncertainty analysis showed that denitrification rate is the most influential parameter on nitrate leaching. The results showed that combining management alternatives is a successful strategy, especially with the use of nitrification inhibitors. Also, change in the land use pattern has a noticeable impact on nitrate leaching.     

SIMULATING THE IMPACT OF DRAINAGE DESIGN IN A COLD CLIMATE WITH ADAPT1

ABSTRACT: Surface and subsurface drainage make crop production economically viable in much of southern Minnesota because drainage allows timely field operations and protects field crops from extended periods of flooded soil conditions. However, subsurface drainage has been shown to increase nitrate/nitrogen losses to receiving waters. When engaging in drainage activities, farmers are increasingly being asked to consider, apart from the economic profit, the environmental impact of drainage. The Agricultural Drainage and Pesticide Transport model (ADAPT) was used in this study to evaluate the impact of subsurface drainage design on the soil water balance over a two‐year period during which observed drainage discharge data were available. Twelve modeling scenarios incorporated four drainage coefficients (DC), 0.64 cm/d, 0.95 cm/d, 1.27 cm/d, and 1.91 cm/d, and three drain depths, 0.84 m, 1.15 m, and 1.45 m. The baseline condition corresponded to the drainage system specifications at the field site: a drain depth and spacing of 1.45 m and 28 m, respectively (DC of 0.64 cm/d). The results of the two‐year simulation suggested that for a given drainage coefficient, soils with the shallower drains (but equal DC) generally have less subsurface drainage and can produce more runoff (but reduced total discharge) and evapotranspiration. The results also suggested that it may be possible to design for both water/nitrate/nitrogen reduction and crop water needs.     

MODELING SEDIMENT AND PHOSPHORUS LOSSES IN AN AGRICULTURAL WATERSHED TO MEET TMDLs1

ABSTRACT: This paper studies the effectiveness of alternative farm management strategies at improving water quality to meet Total Maximum Daily Loads (TMDLs) in agricultural watersheds. A spatial process model was calibrated using monthly flow, sediment, and phosphorus (P) losses (1994 to 1996) from Sand Creek watershed in south‐central Minnesota. Statistical evaluation of predicted and observed data gave r² coefficients of 0.75, 0.69, and 0.49 for flow (average 4.1 m³/s), sediment load (average 0.44 ton/ha), and phosphorus load (average 0.97 kg/ha), respectively. The calibrated model was used to evaluate the effects of conservation tillage, conversion of crop land to pasture, and changes in phosphorus fertilizer application rate on pollutant loads. TMDLs were developed for sediment and P losses based on existing water quality standards and guidelines. Observed annual sediment and P losses exceeded these TMDLs by 59 percent and 83 percent, respectively. A combination of increased conservation tillage, reduced application rates of phosphorus fertilizer, and conversion of crop land to pasture could reduce sediment and phosphorus loads by 23 percent and 20 percent of existing loads, respectively. These reductions are much less than needed to meet TMDLs, suggesting that control of sediment using buffer strips and control of point sources of phosphorus are needed for the remaining reductions.     

CHEMISTRY OF COALBED METHANE DISCHARGE WATER INTERACTING WITH SEMI‐ARID EPHEMERAL STREAM CHANNELS1

ABSTRACT: The objective of this study was to examine the chemistry of Coalbed Methane (CBM) discharge water reacting with semi‐arid ephemeral stream channels in the Powder River Basin, Wyoming. The study area consisted of two ephemeral streams: Burger Draw and Sue Draw. These streams are tributaries to the perennial Powder River. Samples were collected bimonthly from three CBM discharge points and seven channel locations in Burger Draw and Sue Draw. Samples were also collected bimonthly from the Powder River above and below the confluence of Burger Draw. Before sample collection, the pH and electrical conductivity (EC) were measured in the field. Samples were transported to the laboratory and analyzed for alkalinity, major cations, and anions. From the measurement of sodium (Na), calcium (Ca), and magnesium (Mg), practical sodium adsorption ratio (SARp) and true sodium adsorption ratio (SARt) were calculated. Results suggest pH and EC of CBM discharge water was 7.1 and 4.3 dS/m, respectively. The CBM discharge water consisted of higher concentrations of sodium and alkalinity compared to other components. The pH of CBM discharge water increased significantly (p = 0.000) in the downstream channel of Burger Draw from 7.1 to 8.84 before it joined with the Powder River. Dissolved calcium concentration of CBM discharge water decreased significantly (p = 0.000) in the downstream channel water. Subsequently, SARp increased approximately from 24 to 29. The SARt also increased significantly (p = 0.001) in the downstream channel water. For instance, SARt of CBM discharge water increased from 32.93 to 45.5 downstream channels after the confluence of Sue Draw with the Burger Draw. The only significant difference in water chemistry above and below the confluence of Burger Draw with the Powder River was pH, which increased from 8.36 to 8.52. The significant increase in SAR values of CBM discharge water in Burger Draw and Sue Draw tributaries suggest a careful monitoring of salinity and sodicity is needed if CBM discharge water is used for irrigation in semi‐arid environments. Results discussed in this study will be useful to downstream water users who depend on water for irrigation.     

MODELING THE IMPACTS OF WATER LEVEL CHANGES ON A GREAT LAKES COMMUNITY1

ABSTRACT: Recent research that couples climate change scenarios based on general circulation models (GCM) with Great Lakes hydrologic models has indicated that average water levels are projected to decline in the future. This paper outlines a methodology to assess the potential impact of declining water levels on Great Lakes waterfront communities, using the Lake Huron shoreline at Goderich, Ontario, as an example. The methodology utilizes a geographic information system (GIS) to combine topographic and bathymetric datasets. A digital elevation surface is used to model projected shoreline change for 2050 using water level scenarios. An arbitrary scenario, based on a 1 m decline from February 2001 lake levels, is also modeled. By creating a series of shoreline scenarios, a range of impact and cost scenarios are generated for the Goderich Harbor and adjacent marinas. Additional harbor and marina dredging could cost as much as CDN $7.6 million. Lake freighters may experience a 30 percent loss in vessel capacity. The methodology is used to provide initial estimates of the potential impacts of climate change that can be readily updated as more robust climate change scenarios become available and is adaptable for use in other Great Lakes coastal communities.     

细水雾阻隔火焰热辐射的模拟研究

从热辐射传递方程出发，根据Mie散射理论,考虑雾滴对热辐射的散射和吸收特性，建立细水雾阻隔火焰热辐射的两通量模型，并给出简化算法；同时建立小尺度模拟实验系统，对理论模型进行验证。结果表明，两通量模型较为合理地预测了细水雾对火焰热辐射的衰减作用。在此基础上，应用上述理论模型进一步探讨火焰温度、细水雾特性参数、雾场厚度对阻隔热辐射效率的影响，为细水雾系统的实际工程应用提供了理论和依据。     

Political will,political skill,and political behavior

The current study used Mintzberg's (1983) conceptualization of political will and political skill to evaluate the predictors and consequences of political behavior at work. As elements of political will, we hypothesized that need for achievement and intrinsic motivation would predict the use of political behavior at work. Furthermore, we argued that political skill would moderate the relationship between political behavior and emotional labor. Data gathered from employees (N = 193) representing a wide array of organizations substantiated the proposed relationships. Specifically, need for achievement and intrinsic motivation were positively associated with political behavior. In turn, those opting to employ political behavior at work experienced a higher degree of emotional labor, but this relationship was found to operate differently at low and high levels of political skill. Specifically, emotional labor was a consequence of political behavior for those low in political skill, but emotional labor reactions from political behavior were neutralized for individuals high in political skill. Implications of these results, strengths and limitations, and directions for future research are discussed. Copyright © 2005 John Wiley & Sons, Ltd.     

Carbon sequestration: Do N inputs and elevated atmospheric CO2 alter soil solution chemistry and respiratory C losses?

Soil respiration is a large C flux which is of primary importance in determining C sequestration. Here we ask how it is altered by atmospheric CO₂ concentration and N additions. Swards of Lolium perenne L. were grown in a Eutric cambisol under controlled conditions with and without the addition of 200 kg NO^? ₃ ?N ha^?1, at either 350 ppm or 700 ppm CO₂, for 3 months. Soil respiration and net canopy photosynthesis were both increased by added N and elevated CO₂, but soil respiration increased proportionately less than fixation by photosynthesis. Thus, both elevated CO₂ and N appeared to increase potential C sequestration, although adding N at elevated CO₂ reduced the C sequestered as a proportion of that fixed relative to elevated CO₂ alone. Across all treatments below-ground respiratory C losses were predicted by root biomass, but not by soil solution C and N concentrations. Specific root-dependent respiration was increased by elevated CO₂, such that below-ground respiration per unit biomass and per unit plant N was increased.     

An automated wet deposition system to compare the effects of reduced and oxidised N on ombrotrophic bog species: Practical considerations

Critical N loads for ombrotrophic bogs, which often contain rare and N-sensitive plants (especially those in lower plant groups: lichens, mosses and liverworts), are based on very few experimental data from measured, low background N deposition areas. Additionally the relative effects of reduced versus oxidised N are largely unknown. This paper describes an automated field exposure system (30 km S. of Edinburgh, Scotland) for treating ombrotrophic bog vegetation with fine droplets of oxidised N (NaNO₃) and reduced N (NH₄Cl). Whim Moss exists in an area of low ambient N deposition (ca. 8 kg N ha^?1 y^?1), the sources and quantification of which are described. The wet N treatment system is run continuously, and is controlled/activated by wind speed and rainfall to provide a unique simulation of “real worl” treatment patterns (no rain=no treatment). Simulated precipitation is supplied at ionic concentrations below 4 mM in rainwater collected on site. Treatments provide a replicated dose response to 16, 32 and 64 kg N ha^?1 y^?1 adjusted for ambient deposition (8 kg N ha^?1 y^?1). The 16 and 64 kg N ha^?1 y^?1 are duplicated with a P+K supplement. Baseline soil chemistry and foliar nutrient status was established for all 44 plots for Calluna vulgaris, Sphagnum capillifolium, Hypnum jutlandicum and Cladonia portentosa.